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1.太原理工大学化学与化工学院,山西 太原 030024
2.怀柔实验室山西研究院,山西 太原 030024
Received:22 April 2026,
Revised:2026-07-10,
Accepted:13 July 2026,
移动端阅览
LI Xiaomin, ZHOU Yang, LI Shishuai, et al. Research progress on comprehensive utilization and cascade upgrading of full-concentration coalbed methane[J/OL]. CIESC Journal, 2026.
LI Xiaomin, ZHOU Yang, LI Shishuai, et al. Research progress on comprehensive utilization and cascade upgrading of full-concentration coalbed methane[J/OL]. CIESC Journal, 2026. DOI: 10.11949/0438-1157.20260573.
煤层气是重要的非常规天然气资源,实现其高效利用对于优化能源结构、保障煤矿生产安全、进行温室气体减排有着重要意义。文章系统综述了全浓度煤层气综合利用及梯级提质(富集与提纯)技术的研究进展。依据不同浓度煤层气的组成特点,通过高值化学品转化、燃烧及燃爆发电、氧化供热等不同途径,分析了其在各应用场景中的适用性与发展现状。围绕中低浓度煤层气的梯级提质,介绍了主流工艺的基本原理、研究进展和工业化应用现状。着重论述了变压吸附分离技术的最新成果,包括高性能吸附材料的开发和变压吸附工艺的优化。最后表明,全域煤层气综合利用技术虽然已初步形成,但是还需要进一步提高系统集成与规模化,以此推动煤层气资源的高效利用。
Coalbed methane (CBM)
a significant unconventional natural gas resource
holds strategic importance f
or optimizing energy structure
ensuring the safety of coal mining operations and reducing greenhouse gas emissions through effective utilization. This review systematically examines the comprehensive utilization and cascade upgrading
including enrichment and purification
of CBM across the full concentration range. For comprehensive utilization
differentiated approaches are adopted for CBM with different CH
4
concentrations
encompassing chemical conversion
combustion and knock combustion power generation
and oxidation for heat supply. The applicability and technical bottlenecks of these methods in different application scenarios are analyzed. In addition
more promising high-value conversion pathways and direct energy conversion via solid oxide fuel cells offer new development directions for enhancing the economic viability and utilization efficiency of CBM. For enrichment and purification
with a focus on improving the quality and efficiency of low-to-medium concentration CBM
this review introduces the basic principles
research progress
and industrial application status of mainstream processes. The recent advances in pressure swing adsorption (PSA) separation technology are highlighted
including the design and development of high-performance adsorbents
continuous optimization of PSA processes
exploratory applications of machine learning
and recent progress in novel PSA techniques. Although a comprehensive utilization technology system for CBM across the full concentration range has begun to take shape
numerous challenges remain in safe and efficient utilization
system integration
and large-scale operation across different concentration ranges
particularly for ventilation air methane (VAM). Future research should further strengthen technological research and development to promote the efficient
clean
and large-scale utilization of CBM resources.
Moore T A . Coalbed methane: a review [J ] . International Journal of Coal Geology , 2012 , 101 : 36 - 81 .
中华人民共和国自然资源部 . 中国矿产资源报告 [M ] . 北京 : 地质出版社 , 2019 .
Ministry of Natural Resources of the People’s Republic of China . China mineral resources [M ] . Beijing : Geological Publishing House , 2019 .
Karakurt I , Aydin G , Aydiner K . Mine ventilation air methane as a sustainable energy source [J ] . Renewable and Sustainable Energy Reviews , 2011 , 15 ( 2 ): 1042 - 1049 .
Miller S M , Michalak A M , Detmers R G , et al . China’s coal mine methane regulations have not curbed growing emissions [J ] . Nature Communications , 2019 , 10 : 303 .
Chai X L , Tonjes D J , Mahajan D . Methane emissions as energy reservoir: context, scope, causes and mitigation strategies [J ] . Progress in Energy and Combustion Science , 2016 , 56 : 33 - 70 .
姚成林 . 煤层气梯级利用技术探讨 [J ] . 矿业安全与环保 , 2016 , 43 ( 4 ): 94 - 97 .
Yao C L . Discussion on cascade utilization technology for coal-bed methane [J ] . Mining Safety & Environmental Protection , 2016 , 43 ( 4 ): 94 - 97 .
Kumar S , Kwon H T , Choi K H , et al . LNG: an eco-friendly cryogenic fuel for sustainable development [J ] . Applied Energy , 2011 , 88 ( 12 ): 4264 - 4273 .
He T B , Chong Z R , Zheng J J , et al . LNG cold energy utilization: Prospects and challenges [J ] . Energy , 2019 , 170 : 557 - 568 .
Mehrpooya M , Moftakhari Sharifzadeh M M , Rosen M A . Optimum design and exergy analysis of a novel cryogenic air separation process with LNG (liquefied natural gas) cold energy utilization [J ] . Energy , 2015 , 90 : 2047 - 2069 .
Cao W S , Beggs C , Mujtaba I M . Theoretical approach of freeze seawater desalination on flake ice maker utilizing LNG cold energy [J ] . Desalination , 2015 , 355 : 22 - 32 .
Ribun V , Boichenko S , Kuzhewski H , et al . Analysis of conventional and nonconventional GTL technologies: benefits and drawbacks [M ] // Modern Technologies in Energy and Transport . Cham : Springer Nature Switzerland , 2024 : 273 - 286 .
Fei Q , Guarnieri M T , Tao L , et al . Bioconversion of natural gas to liquid fuel: opportunities and challenges [J ] . Biotechnology Advances , 2014 , 32 ( 3 ): 596 - 614 .
An Y L , Lin T J , Yu F , et al . Advances in direct production of value-added chemicals via syngas conversion [J ] . Science China Chemistry , 2017 , 60 ( 7 ): 887 - 903 .
Velasco J A , Lopez L , Cabrera S , et al . Synthesis gas production for GTL applications: Thermodynamic equilibrium approach and potential for carbon formation in a catalytic partial oxidation pre-reformer [J ] . Journal of Natural Gas Science and Engineering , 2014 , 20 : 175 - 183 .
Wang S Q , Nabavi S A , Clough P T . A review on bi/polymetallic catalysts for steam methane reforming [J ] . International Journal of Hydrogen Energy , 2023 , 48 ( 42 ): 15879 - 15893 .
Wei J M , Iglesia E . Isotopic and kinetic assessment of the mechanism of reactions of CH 4 with CO 2 or H 2 O to form synthesis gas and carbon on nickel catalysts [J ] . Journal of Catalysis , 2004 , 224 ( 2 ): 370 - 383 .
Alli R D , de Souza P A L , Mohamedali M , et al . Tri-reforming of methane for syngas production using Ni catalysts: current status and future outlook [J ] . Catalysis Today , 2023 , 407 : 107 - 124 .
梁立志 . 低浓度瓦斯发电技术研究现状分析 [J ] . 山西化工 , 2022 , 42 ( 3 ): 47 - 48 .
Liang L Z . Analysis on current research situation of low concentration gas power generation technology [J ] . Shanxi Chemical Industry , 2022 , 42 ( 3 ): 47 - 48 .
李国富 , 李超 , 霍春秀 , 等 . 山西重点煤矿区瓦斯梯级利用关键技术与工程示范 [J ] . 煤田地质与勘探 , 2022 , 50 ( 9 ): 42 - 50 .
Li G F , Li C , Huo C X , et al . Key technology and engineering demonstration for cascade utilization of gas in key coal mining areas of Shanxi Province, China [J ] . Coal Geology & Exploration , 2022 , 50 ( 9 ): 42 - 50 .
Zhou F B , Xia T Q , Wang X X , et al . Recent developments in coal mine methane extraction and utilization in China: a review [J ] . Journal of Natural Gas Science and Engineering , 2016 , 31 : 437 - 458 .
陈宜亮 , 牟善祥 , 张启军 . 发动机电子控制装置 : CN200520087726.X [P ] . 2007-05-30 .
Chen Y L , Mou S X , Zhang Q J . Electronic control equipment for engine : CN200520087726.X [P ] . 2007-05-30 .
杨根盛 . 低浓度煤层气发电技术的应用研究 [J ] . 中国煤炭 , 2014 ( S1 ): 277 - 279, 284 .
Yang G S . Application research on low concentration coalbed methane power generation technology [J ] . China Coal , 2014 ( S1 ): 277 - 279, 284 .
Singh M , Zappa D , Comini E . Solid oxide fuel cell: decade of progress, future perspectives and challenges [J ] . International Journal of Hydrogen Energy , 2021 , 46 ( 54 ): 27643 - 27674 .
Wei K W , Wang X X , Zhu H , et al . Clean and stable conversion of oxygen-bearing low-concentration coal mine gas by solid oxide fuel cells with an additional reforming layer [J ] . Journal of Power Sources , 2021 , 506 : 230208 .
Jiao Y , Wang L Y , Zhang L Q , et al . Direct operation of solid oxide fuel cells on low-concentration oxygen-bearing coal-bed methane with high stability [J ] . Energy & Fuels , 2018 , 32 ( 4 ): 4547 - 4558 .
Hibino T , Iwahara H . Simplification of solid oxide fuel cell system using partial oxidation of methane [J ] . Chemistry Letters , 1993 , 22 ( 7 ): 1131 - 1134 .
Hua B , Li M , Pu J , et al . BaZr 0.1 Ce 0.7 Y 0.1 Yb 0.1 O 3– δ enhanced coking-free on-cell reforming for direct-methane solid oxide fuel cells [J ] . Journal of Materials Chemistry A , 2014 , 2 ( 31 ): 12576 .
Setiawan H , Sakamoto M , Shiratori Y . Study on biochar as desulfurizer for SOFC application [J ] . Fuel Cells , 2021 , 21 ( 5 ): 430 - 439 .
Mujeebu M A , Abdullah M Z , Abu Bakar M Z , et al . Combustion in porous media and its applications–a comprehensive survey [J ] . Journal of Environmental Management , 2009 , 90 ( 8 ): 2287 - 2312 .
Liao M J , He Z , Liang X , et al . Effect of the cross-section of a porous burner on the combustion stability limit of premixed oxy-methane flames [J ] . ACS Omega , 2023 , 8 ( 50 ): 48258 - 48268 .
甘海龙 . 低浓度瓦斯焚烧及热能利用技术研究 [J ] . 化工设备与管道 , 2018 , 55 ( 4 ): 47 - 49, 54 .
Gan H L . Research of technologies used in low concentration gas incineration and heat energy utilization [J ] . Process Equipment & Piping , 2018 , 55 ( 4 ): 47 - 49, 54 .
He L , Fan Y L , Bellettre J , et al . A review on catalytic methane combustion at low temperatures: catalysts, mechanisms, reaction conditions and reactor designs [J ] . Renewable and Sustainable Energy Reviews , 2020 , 119 : 109589 .
Chin Y H , Buda C , Neurock M , et al . Reactivity of chemis orbed oxygen atoms and their catalytic consequences during CH 4 –O 2 catalysis on supported Pt clusters [J ] . Journal of the American Chemical Society , 2011 , 133 ( 40 ): 15958 - 15978 .
Tang Z Y , Zhang T , Luo D C , et al . Catalytic combustion of methane: from mechanism and materials properties to catalytic performance [J ] . ACS Catalysis , 2022 , 12 ( 21 ): 13457 - 13474 .
Fan Y Y , Zhou W C , Qiu X Y , et al . Selective photocatalytic oxidation of methane by quantum-sized bismuth vanadate [J ] . Nature Sustainability , 2021 , 4 ( 6 ): 509 - 515 .
Liu Z , Xu B Y , Jiang Y J , et al . Photocatalytic conversion of methane: current state of the art, challenges, and future perspectives [J ] . ACS Environmental Au , 2023 , 3 ( 5 ): 252 - 276 .
Xu Y Y , Shen X F , Guo S , et al . Iron oxide clusters as electron donors under light enhance oxygen reduction kinetics at atomically dispersed Fe for photocatalytic CH 4 partial oxidation [J ] . Angewandte Chemie International Edition , 2025 , 137 ( 7 ): e202419075 .
任俊卿 , 张伟 , 龚文照 . 煤层气利用技术研究进展 [J ] . 山西化工 , 2018 , 38 ( 4 ): 41 - 44 .
Ren J Q , Zhang W , Gong W Z . Research progress of utilization technique in coal bed methane [J ] . Shanxi Chemical Industry , 2018 , 38 ( 4 ): 41 - 44 .
张涛 . 低浓度煤层气蓄热氧化利用关键技术研究与应用 [J ] . 煤炭科学技术 , 2023 , 51 ( S1 ): 173 - 180 .
Zhang T . Research and application of key technology for thermal storage oxidation utilization of low concentration coalbed methane [J ] . Coal Science and Technology , 2023 , 51 ( S1 ): 173 - 180 .
Feng X B , Jiang L , Li D Y , et al . Progress and key challenges in catalytic combustion of lean methane [J ] . Journal of Energy Chemistry , 2022 , 75 : 173 - 215 .
毛明明 , 刘永启 , 郑斌 , 等 . 煤矿乏风预热催化氧化床温度均匀性的研究 [J ] . 煤炭学报 , 2015 , 40 ( 1 ): 109 - 114 .
Mao M M , Liu Y Q , Zheng B , et al . Investigation of temperature distribution uniformity in a preheating catalytic oxidation bed [J ] . Journal of China Coal Society , 2015 , 40 ( 1 ): 109 - 114 .
Ma J , Lou Y , Cai Y F , et al . The relationship between the chemical state of Pd species and the catalytic activity for methane combustion on Pd/CeO 2 [J ] . Catalysis Science & Technology , 2018 , 8 ( 10 ): 2567 - 2577 .
Liu Y X , Hu C H , Bian L C . Highly dispersed Pd species supported on CeO 2 catalyst for lean methane combustion: the effect of the occurrence state of surface Pd species on the catalytic activity [J ] . Catalysts , 2021 , 11 ( 7 ): 772 .
Kim C , Hong E , Shin C H . Improvement of methane combustion activity for Pd/ZrO 2 catalyst by simple reduction/reoxidation treatment [J ] . Catalysts , 2019 , 9 ( 10 ): 838 .
Pu Z Y , Liu Y , Zhou H , et al . Catalytic combustion of lean methane at low temperature over ZrO 2 -modified Co 3 O 4 catalysts [J ] . Applied Surface Science , 2017 , 422 : 85 - 93 .
Gong D , Zeng G F . Low-temperature combustion of methane over graphene templated Co 3 O 4 defective-nanoplates [J ] . Scientific Reports , 2021 , 11 : 12604 .
Ercolino G , Grzybek G , Stelmachowski P , et al . Pd/Co 3 O 4 -based catalysts prepared by solution combustion synthesis for residual methane oxidation in lean conditions [J ] . Catalysis Today , 2015 , 257 : 66 - 71 .
Xiang X P , Zhao L H , Teng B T , et al . Catalytic combustion of methane on La 1– x Ce x FeO 3 oxides [J ] . Applied Surface Science , 2013 , 276 : 328 - 332 .
Zheng Y , Wang C , Li J J , et al . Enhanced methane oxidation over Co 3 O 4 –In 2 O 3- x composite oxide nanoparticles via controllable substitution of Co 3+ /Co 2+ by In 3+ ions [J ] . ACS Applied Nano Materials , 2020 , 3 ( 9 ): 9470 - 9479 .
任晓光 , 郑建东 , 宋永吉 . 不同离子掺杂对镧六铝酸盐催化剂结构及其甲烷燃烧性能的影响 [J ] . 燃料化学学报 , 2011 , 39 ( 9 ): 717 - 720 .
Ren X G , Zheng J D , Song Y J . Effects of different ion dopants on the structure and catalytic performance of lanthanum hexaaluminates in methane combustion [J ] . Journal of Fuel Chemistry and Technology , 2011 , 39 ( 9 ): 717 - 720 .
Li J H , Liang X , Xu S C , et al . Catalytic performance of manganese cobalt oxides on methane combustion at low temperature [J ] . Applied Catalysis B: Environmental , 2009 , 90 ( 1/2 ): 307 - 312 .
You C F , Xu X C . Utilization of ventilation air methane as a supplementary fuel at a circulating fluidized bed combustion boiler [J ] . Environmental Science & Technology , 2008 , 42 ( 7 ): 2590 - 2593 .
李中军 . 低浓度煤层气利用技术研究现状及应用展望 [J ] . 能源与环保 , 2018 , 40 ( 6 ): 152 - 156 .
Li Z J . Research status of low concentration coal mine methane utilization technology and application prospect [J ] . China Energy and Environmental Protection , 2018 , 40 ( 6 ): 152 - 156 .
杨克剑 . 含氧煤层气的分离与液化 [J ] . 中国煤层气 , 2007 , 4 ( 4 ): 20 - 22 .
Yang K J . Separation and liquefaction of oxygen-bearing coal mine methane [J ] . China Coalbed Methane , 2007 , 4 ( 4 ): 20 - 22 .
陶鹏万 , 王晓东 , 黄建彬 . 低温法浓缩煤层气中的甲烷 [J ] . 天然气化工 , 2005 , 30 ( 4 ): 43 - 46 .
Tao P W , Wang X D , Huang J B . Separation of methane from coal seam gas by cryogenic distillation [J ] . Natural Gas Chemical Industry , 2005 , 30 ( 4 ): 43 - 46 .
陶鹏万 . 煤矿区煤层气低温分离液化工艺功耗分析 [J ] . 中国煤层气 , 2009 , 6 ( 1 ): 37 - 41 .
Tao P W . Analysis of power consumption of the liquefaction technology for separation of CMM at low temperature [J ] . China Coalbed Methane , 2009 , 6 ( 1 ): 37 - 41 .
朱菁 . 含氧煤层气直接深冷分离甲烷的安全工艺方法 [J ] . 天然气化工(C1化学与化工) , 2014 ( 3 ): 57 - 62 .
Zhu J . A safe process for purification of oxygen-bearing coal bed methane by direct cryogenic separation [J ] . Natural Gas Chemical Industry , 2014 ( 3 ): 57 - 62 .
Nguyen T V , Rothuizen E D , Markussen W B , et al . Thermodynamic comparison of three small-scale gas liquefaction systems [J ] . Applied Thermal Engineering , 2018 , 128 : 712 - 724 .
Wang Q , Yu Y X , Li Y H , et al . Methane separation and capture from nitrogen rich gases by selective adsorption in microporous materials: a review [J ] . Separation and Purification Technology , 2022 , 283 : 120206 .
Yang J F , Liu J Q , Liu P X , et al . K-chabazite zeolite nanocrystal aggregates for highly efficient methane separation [J ] . Angewandte Chemie International Edition , 2022 , 61 ( 8 ): e202116850 .
Tang X , Bai X W , Wang Y T , et al . In situ synthesis of copper-based mordenite for nitrogen/methane sieving [J ] . Nature Communications , 2025 , 16 : 8065 .
Jing J X , Wang Y G , Yang C C , et al . Green and facile synthesis of cellulose-based porous carbons for effective CH 4 /N 2 adsorption separation [J ] . Chemical Engineering Journal , 2025 , 519 : 164803 .
Liu F , Zhang Y , Zhang P X , et al . Facile preparation of N and O-rich porous carbon from palm sheath for highly selective separation of CO 2 /CH 4 /N 2 gas-mixture [J ] . Chemical Engineering Journal , 2020 , 399 : 125812 .
Yang J F , Zhao Q , Xu H , et al . Adsorption of CO 2 , CH 4 , and N 2 on gas diameter grade ion-exchange small pore zeolites [J ] . Journal of Chemical & Engineering Data , 2012 , 57 ( 12 ): 3701 - 3709 .
Niu Z , Cui X L , Pham T , et al . A metal–organic framework based methane nano-trap for the capture of coal-mine methane [J ] . Angewandte Chemie International Edition , 2019 , 58 ( 30 ): 10138 - 10141 .
Zhang F F , Zhao Z W , Wang Y T , et al . Nitrogen adsorption sites with low polarizability for benchmark N 2 /CH 4 separation [J ] . Angewandte Chemie International Edition , 2025 , 64 ( 36 ): e202510242 .
Wang S M , Wu P C , Fu J W , et al . Heteroatom-doped porous carbon microspheres with ultramicropores for efficient CH 4 /N 2 separation with ultra-high CH 4 uptake [J ] . Separation and Purification Technology , 2021 , 274 : 119121 .
Li Y , Xu R , Wang B B , et al . Enhanced N-doped porous carbon derived from KOH-activated waste wool: a promising material for selective adsorption of CO₂/CH₄ and CH₄/N₂ [J ] . Nanomaterials , 2019 , 9 ( 2 ): 266 .
Zhang C J , Wang Y G , Jing J X , et al . Green synthesis of ultramicroporous carbons by in-situ ionic activation of coal-derived humic acids for efficient CH 4 /N 2 separation [J ] . Chemical Engineering Journal , 2025 , 510 : 161605 .
Wu Y Q , Yuan D H , Zeng S , et al . Significant enhancement in CH 4 /N 2 separation with amine-modified zeolite Y [J ] . Fuel , 2021 , 301 : 121077 .
Shang H , Li Y P , Liu J Q , et al . CH 4 /N 2 separation on methane molecules grade diameter channel molecular sieves with a CHA-type structure [J ] . Chinese Journal of Chemical Engineering , 2019 , 27 ( 5 ): 1044 - 1049 .
Li Y , Zhou Y , Zhang Y Z , et al . Template-free synthesis of intergrown T zeolite with high CH 4 /N 2 selectivity [J ] . Separation and Purification Technology , 2025 , 377 : 134500 .
Chang M , Zhao Y J , Liu D H , et al . Methane-trapping metal–organic frameworks with an aliphatic ligand for efficient CH 4 /N 2 separation [J ] . Sustainable Energy & Fuels , 2020 , 4 ( 1 ): 138 - 142 .
Qing M W , Shen D M , Bülow M , et al . Metallo-organic molecular sieve for gas separation and purification [J ] . Microporous and Mesoporous Materials , 2002 , 55 ( 2 ): 217 - 230 .
Wang S M , Shivanna M , Yang Q Y . Nickel-based metal–organic frameworks for coal-bed methane purification with record CH 4 /N 2 selectivity [J ] . Angewandte Chemie International Edition , 2022 , 61 ( 15 ): e202201017 .
Hu J L , Sun T J , Liu X W , et al . Separation of CH 4 /N 2 mixtures in metal–organic frameworks with 1D micro-channels [J ] . RSC Advances , 2016 , 6 ( 68 ): 64039 - 64046 .
Yoon J W , Chang H , Lee S J , et al . Selective nitrogen capture by porous hybrid materials containing accessible transition metal ion sites [J ] . Nature Materials , 2017 , 16 ( 5 ): 526 - 531 .
Jaramillo D E , Reed D A , Jiang H Z H , et al . Selective nitrogen adsorption via backbonding in a metal–organic framework with exposed vanadium sites [J ] . Nature Materials , 2020 , 19 ( 5 ): 517 - 521 .
Kuznicki S M , Bell V A , Nair S , et al . A titanosilicate molecular sieve with adjustable pores for size-selective adsorption of molecules [J ] . Nature , 2001 , 412 ( 6848 ): 720 - 724 .
Jayaraman A , Hernandez-Maldonado A J , Yang R T , et al . Clinoptilolites for nitrogen/methane separation [J ] . Chemical Engineering Science , 2004 , 59 ( 12 ): 2407 - 2417 .
Zhou S , Shekhah O , Ramírez A , et al . Asymmetric pore windows in MOF membranes for natural gas valorization [J ] . Nature , 2022 , 606 ( 7915 ): 706 - 712 .
Lu B , Shen Y H , Tang Z L , et al . Vacuum pressure swing adsorption process for coalbed methane enrichment [J ] . Chinese Journal of Chemical Engineering , 2021 , 32 : 264 - 280 .
Hu G P , Xiao G K , Guo Y L , et al . Separation of methane and nitrogen using ionic liquidic zeolites by pressure vacuum swing adsorption [J ] . AIChE Journal , 2022 , 68 ( 7 ): e17668 .
Hu G P , Guo Y L , Zhao Q H , et al . Separation of methane and nitrogen using heavy reflux pressure swing adsorption: experiments and modeling [J ] . Industrial & Engineering Chemistry Research , 2023 , 62 ( 18 ): 7114 - 7126 .
Shang H , Bai H H , Li X M , et al . Site trials of methane capture from low-concentration coalbed methane drainage wells using a mobile skid-mounted vacuum pressure swing adsorption system [J ] . Separation and Purification Technology , 2022 , 295 : 121271 .
Yang J F , Bai H H , Shang H , et al . Experimental and simulation study on efficient CH 4 /N 2 separation by pressure swing adsorption on silicalite-1 pellets [J ] . Chemical Engineering Journal , 2020 , 388 : 124222 .
Zhang J H , Qu S J , Li L T , et al . Preparation of carbon molecular sieves used for CH 4 /N 2 separation [J ] . Journal of Chemical & Engineering Data , 2018 , 63 ( 5 ): 1737 - 1744 .
Bhadra S J , Farooq S . Separation of methane–nitrogen mixture by pressure swing adsorption for natural gas upgrading [J ] . Industrial & Engineering Chemistry Research , 2011 , 50 ( 24 ): 14030 - 14045 .
Shang H , Zhang X R , Li X M , et al . Nitrogen replacement strategy to efficiently enhance methane recovery of the methane purification process using nitrogen equilibrium selective sorbent [J ] . Chemical Engineering Journal , 2023 , 452 : 139538 .
Sant Anna H R , Jr Barreto A G , Tavares F W , et al . Machine learning model and optimization of a PSA unit for methane-nitrogen separation [J ] . Computers & Chemical Engineering , 2017 , 104 : 377 - 391 .
Fu Q , Yan H Y , Shen Y H , et al . Optimal design and control of pressure swing adsorption process for N 2 /CH 4 separation [J ] . Journal of Cleaner Production , 2018 , 170 : 704 - 714 .
Wang B X , Bao Q , Chen Z R , et al . K-RHO zeolite with high nitrogen selectivity for N 2 /CH 4 separation by PSA process [J ] . Separation and Purification Technology , 2024 , 338 : 126586 .
Zhang X R , Shang H , Yang J F , et al . Nitrogen rejection from low quality natural gas by pressure swing adsorption experiments and simulation using dynamic adsorption isotherms [J ] . Chinese Journal of Chemical Engineering , 2022 , 42 : 120 - 129 .
Olajossy A . Effective recovery of methane from coal mine methane gas by vacuum pressure swing adsorption: a pilot scale case study [J ] . Chemical Engineering and Science , 2013 , 1 ( 4 ): 46 - 54 .
杨华伟 , 张正旺 , 张东辉 . 真空变压吸附分离氮气甲烷模拟与实验研究 [J ] . 化学工业与工程 , 2013 , 30 ( 5 ): 55 - 60 .
Yang H W , Zhang Z W , Zhang D H . Modeling and experiment of vacuum pressure swing adsorption process for N 2 and CH 4 separation [J ] . Chemical Industry and Engineering , 2013 , 30 ( 5 ): 55 - 60 .
周圆圆 , 杨华伟 , 张东辉 . 甲烷/氮气变压吸附分离的实验与模拟 [J ] . 天然气化工 , 2011 , 36 ( 5 ): 21 - 27 .
Zhou Y Y , Yang H W , Zhang D H . Simulation and experiment for the pressure swing adsorption separation of methane and nitrogen [J ] . Natural Gas Chemical Industry , 2011 , 36 ( 5 ): 21 - 27 .
Zhou Y , Fu Q , Shen Y H , et al . Upgrade of low-concentration oxygen-bearing coal bed methane by a vacuum pressure swing adsorption process: performance study and safety analysis [J ] . Energy & Fuels , 2016 , 30 ( 2 ): 1496 - 1509 .
杨雄 , 刘应书 , 李永玲 , 等 . 基于活性炭的真空变压吸附提浓煤层气甲烷的实验研究 [J ] . 煤炭学报 , 2010 , 35 ( 6 ): 987 - 991 .
Yang X , Liu Y S , Li Y L , et al . The experimental study on upgrade of coal mine gas by vacuum pressure swing adsorption with activated carbon [J ] . Journal of China Coal Society , 2010 , 35 ( 6 ): 987 - 991 .
Qadir S , Li D F , Gu Y M , et al . Experimental and numerical investigations on the separation performance of [Cu(INA) 2 ] adsorbent for CH 4 recovery by VPSA from oxygen-bearing coal mine methane [J ] . Chemical Engineering Journal , 2021 , 408 : 127238 .
崔乐雨 , 张东辉 , 苏伟 , 等 . 变压吸附法回收氮气中的微量甲烷: 实验与模型 [J ] . 天然气化工(C1化学与化工) , 2008 , 33 ( 6 ): 1 - 5, 10 .
Cui L Y , Zhang D H , Su W , et al . Recovery of trace methane from nitrogen by PSA: experiment and model [J ] . Natural Gas Chemical Industry , 2008 , 33 ( 6 ): 1 - 5, 10 .
Li Y L , Meng Y , Liu Y S , et al . A novel VPSA process for ventilation air methane enrichment by active carbon [J ] . Advanced Materials Research , 2012 , 479/ 480 / 481 : 648 - 653 .
Saleman T L , Li G K , Rufford T E , et al . Capture of low grade methane from nitrogen gas using dual-reflux pressure swing adsorption [J ] . Chemical Engineering Journal , 2015 , 281 : 739 - 748 .
Dias R O M , Ferreira A F P , Cho K H , et al . Methane/nitrogen separation by SMB using UiO-66(Zr)_(COOH) 2 [J ] . Brazilian Journal of Chemical Engineering , 2022 , 39 ( 4 ): 973 - 990 .
Liu C M , Zhou Y P , Sun Y , et al . Enrichment of coal-bed methane by PSA complemented with CO 2 displacement [J ] . AIChE Journal , 2011 , 57 ( 3 ): 645 - 654 .
Adil K , Belmabkhout Y , Pillai R S , et al . Gas/vapour separation using ultra-microporous metal–organic frameworks: insights into the structure/separation relationship [J ] . Chemical Society Reviews , 2017 , 46 ( 11 ): 3402 - 3430 .
Lokhandwala K A , Pinnau I , He Z J , et al . Membrane separation of nitrogen from natural gas: a case study from membrane synthesis to commercial deployment [J ] . Journal of Membrane Science , 2010 , 346 ( 2 ): 270 - 279 .
Buonomenna M G , Golemme G , Tone C M , et al . Nanostructured poly(styrene- b -butadiene- b -styrene) (SBS) membranes for the separation of nitrogen from natural gas [J ] . Advanced Functional Materials , 2012 , 22 ( 8 ): 1759 - 1767 .
Carreon M A . Molecular sieve membranes for N 2 /CH 4 separation [J ] . Journal of Materials Research , 2018 , 33 ( 1 ): 32 - 43 .
Li S G , Zong Z W , Zhou S J , et al . SAPO-34 membranes for N 2 /CH 4 separation: preparation, characterization, separation performance and economic evaluation [J ] . Journal of Membrane Science , 2015 , 487 : 141 - 151 .
Ning X , Koros W J . Carbon molecular sieve membranes derived from Matrimid® polyimide for nitrogen/methane separation [J ] . Carbon , 2014 , 66 : 511 - 522 .
Ma C , Li N , Xue W J , et al . Polarization enhanced CH 4 /N 2 separation in bromine functionalized ZIF-62 based mixed-matrix membranes [J ] . Journal of Membrane Science , 2023 , 683 : 121829 .
Ma C , Yang Z B , Guo X Y , et al . Size-reduced low-crystallinity ZIF-62 for the preparation of mixed-matrix membranes for CH 4 /N 2 separation [J ] . Journal of Membrane Science , 2022 , 663 : 121069 .
Happel J , Hnatow M A , Meyer H . The study of separation of nitrogen from methane by hydrate formation using a novel apparatus [J ] . Annals of the New York Academy of Sciences , 1994 , 715 ( 1 ): 412 - 424 .
Li X Y , Ge B B , Yan J , et al . Review on hydrate-based CH 4 separation from low-concentration coalbed methane in China [J ] . Energy & Fuels , 2021 , 35 ( 10 ): 8494 - 8509 .
Zhang B Y , Wu Q . Thermodynamic promotion of tetrahydrofuran on methane separation from low-concentration coal mine methane based on hydrate [J ] . Energy & Fuels , 2010 , 24 ( 4 ): 2530 - 2535 .
Wang Y W , Du M , Guo X Q , et al . Experiments and simulations for continuous recovery of methane from coal seam gas (CSG) utilizing hydrate formation [J ] . Energy , 2017 , 129 : 28 - 41 .
吴强 . 煤矿瓦斯水合化分离试验研究进展 [J ] . 煤炭科学技术 , 2014 , 42 ( 6 ): 81 - 85 .
Wu Q . Research progress of separation experiment of mine gas hydrate [J ] . Coal Science and Technology , 2014 , 42 ( 6 ): 81 - 85 .
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