Research progress on high-performance α-olefin-based surfactants

LIU Tianzi; HUANG Zhiwei; FANG Song; ZHOU Congcong; YIN Xiangxun; ZHANG Hongru; CHENG Haoran

doi:10.11949/0438-1157.20260530

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Research progress on high-performance α-olefin-based surfactants

更新时间：2026-07-09

- Research progress on high-performance α-olefin-based surfactants
- CIESC Journal (2026)
- 作者机构：
  
  青岛科技大学化工学院，高性能有机光学聚合物与先进制造技术全国重点实验室，山东青岛 266042
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20260530
  CLC：
- Received：14 April 2026，
  
  Revised：2026-07-09，
  
  Accepted：09 July 2026，
- 稿件说明：
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LIU Tianzi, HUANG Zhiwei, FANG Song, et al. Research progress on high-performance α-olefin-based surfactants[J/OL]. CIESC Journal, 2026.
DOI：

LIU Tianzi, HUANG Zhiwei, FANG Song, et al. Research progress on high-performance α-olefin-based surfactants[J/OL]. CIESC Journal, 2026. DOI： 10.11949/0438-1157.20260530.

摘要

在全球朝绿色低碳转型、“双碳”战略的推进过程中，α-烯烃凭借其末端双键、直链结构，成为高性能表面活性剂实现绿色化发展的关键原料。本文系统综述了α-烯烃基表面活性剂在全链条过程中实现高值化利用的研究进展，深入剖析了疏水链长、支化度、亲水基类型对于临界胶束浓度、界面张力、液膜流变行为的构效关系，总结了α-烯烃磺酸盐的C-S键稳定性和抗硬水性、α-烯烃乙氧基化物的亲水亲油平衡可调性特性与润湿乳化性能、α-烯烃磺基甜菜碱的内盐结构耐盐机理及复配协同效应，并结合日用化工、高温高盐油藏的应用实例，阐述了其在降低油水界面张力、稳定泡沫封堵、提高洗油效率等方面的作用优势。未来研究应聚焦于分子模拟与人工智能辅助的靶向设计、微通道连续流与生物催化等绿色工艺的强化方面，同时要建立全生命周期评价模式，以此推动α-烯烃基表面活性剂朝着高端绿色功能材料进行升级。

Abstract

Driven by the global transition toward a low-carbon economy and China's "dual carbon" strategy

α-olefins have emerged as key feedstocks for the green development of high-performance surfactants

owing to their terminal double-bond structure and linear alkyl chains. This paper systematically reviews recent advances in the high-value utilization of α-olefin-based surfactants throughout the full chain. The structure–property relationships between hydrophobic chain length

branching degree

and hydrophilic group type are critically analyzed with respect to critical micelle concentration

interfacial tension

and liquid film rheology. The characteristics of representative surfactants are summarized: the C–S bond stability and hard-water resistance of α-olefin sulfonates

the tunable hydrophilic-lipophilic balance and wetting/emulsification performance of α-olefin ethoxylates

and the salt tolerance mechanism of the inner-salt structure of α-olefin sulfobetaines along with their synergistic effects in formulation. Combined with application cases in daily chemicals and high-temperature

high-salinity reservoirs

the mechanisms by which these surfactants reduce oil–water interfacial tension

stabilize foam for plugging

and enhance oil-washing efficiency are elucidated. Future research should focus on targeted molecular design assisted by molecular simulation and artificial intelligence

intensified green processes such as microchannel continuous-flow technology and biocatalysis

and the establishment of a whole-life-cycle assessment model

thereby promoting the upgrade of α-olefin-based surfactants toward high-end green functional materials.

关键词

Keywords

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