CO<sub>2 </sub>capture by metal-organic frameworks: adsorption properties,material design, and practical applications

XIE Mingzhi; MENG Chuang; XU Chengwei; WANG Feng; LI Lirong

doi:10.11949/0438-1157.20260251

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CO₂capture by metal-organic frameworks: adsorption properties,material design, and practical applications

更新时间：2026-08-05

- CO₂capture by metal-organic frameworks: adsorption properties,material design, and practical applications
- CIESC Journal (2026)
- 作者机构：
  
  1.扬州大学电气与能源动力工程学院，江苏扬州 225127
  2.温州理工学院建筑与能源工程学院，浙江温州 325000
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20260251
  CLC： TB383
- Received：24 February 2026，
  
  Revised：2026-07-28，
  
  Accepted：05 August 2026，
- 稿件说明：
移动端阅览
XIE Mingzhi, MENG Chuang, XU Chengwei, et al. CO₂capture by metal-organic frameworks: adsorption properties,material design, and practical applications[J/OL]. CIESC Journal, 2026. DOI: 10.11949/0438-1157.20260251.
DOI：

XIE Mingzhi, MENG Chuang, XU Chengwei, et al. CO₂capture by metal-organic frameworks: adsorption properties,material design, and practical applications[J/OL]. CIESC Journal, 2026. DOI: 10.11949/0438-1157.20260251. DOI：

摘要

在全球绿色能源转型背景下，传统能源在相当长时期内仍承担重要的能源保障功能，因此碳减排问题仍是当前亟需重点关注的核心议题。金属有机框架（Metal-organic frameworks，MOFs）作为一类具有超高比表面积和高度可设计孔结构的多孔材料，近年来在二氧化碳捕集领域展现出不菲的研究价值与应用潜力。本文系统总结了近年来MOFs在CO

捕集方面的研究进展，重点综述了其吸附特性及性能调控规律，归纳了通过孔径调控、有机配体功能化、结构掺杂及缺陷工程等策略实现吸附性能强化的相关研究成果，并分析了提升MOFs结构稳定性的关键方法。本文总结了MOFs在CO

吸附领域的工程化研究进展，包括传统与新兴的成型技术（如挤出成型、造粒、膜制备以及3D打印、静电纺丝和溶胶-凝胶法，以及MOF海绵/泡沫复合材料构筑等），并指出合理的成型策略可在保持MOFs优异吸附性能的同时显著提升材料的结构稳定性。其中，以CALF-20为代表的材料已在中试规模应用中展现出优异的CO

吸附性能与长久的循环工作能力。在此基础上，本文讨论了MOFs在碳捕集应用中的生产成本与经济可行性，指出规模化合成与工艺优化是降低成本、推动其产业化应用的关键途径。最后，对MOFs在碳捕集领域的未来发展方向进行了展望，认为应重点关注绿色低成本合成路线的开发、结构稳定性的持续提升、多尺度研究方法的融合以及生命周期评价（LCA）体系的完善，以推动其在实际碳捕集场景中的规模化应用。

Abstract

In the context of the global transition toward green energy

conventional energy sources will continue to play a critical role in ensuring energy security over a considerable period; accordingly

carbon emission reduction remains a central issue requiring urgent and sustained attention. Metal-organic frameworks (MOFs)

a class of porous materials with high surface areas and tunable pore architectures

have recently demonstrated significant research value and promising potential for carbon dioxide capture.This review systematically summarizes recent advances in MOFs for CO

capture

with emphasis on adsorption behavior and the governing principles of performance modulation. Key enhancement strategies are discussed

including pore size regulation

organic ligand functionalization

structural doping

and defect engineering

together with representative approaches for improving MOF structural stability.In addition

engineering development of MOFs for CO

adsorption is reviewed

covering both conventional and emerging shaping strategies

including extrusion

granulation

membrane fabrication

3D printing

electrospinning

sol–gel processing

and the construction of MOF-based sponge and foam composites. Rational shaping strategies are shown to preserve intrinsic adsorption performance while markedly enhancing mechanical and structural stability. Notably

CALF-20 and related materials have demonstrated high CO

adsorption capacity and long-term cyclic stability in pilot-scale applications.On this basis

the production cost and economic feasibility of MOFs in carbon capture applications are further analyzed

highlighting that scalable synthesis and process optimization are key to cost reduction and industrial deployment. Finally

future research directions are outlined

focusing on green and cost-effective synthesis routes

continued improvement of structural stability

integration of multiscale methodologies

and

development of life cycle assessment (LCA) frameworks

all of which are essential for enabling large-scale deployment of MOFs in practical carbon capture scenarios.

关键词

Keywords

references

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CO2 capture by metal-organic frameworks: adsorption properties,material design, and practical applications

DOI：10.11949/0438-1157.20260251

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CO₂capture by metal-organic frameworks: adsorption properties,material design, and practical applications