Mass transfer characteristics of an atomizing reactor in the preparation of magnesium hydroxide

YU Honglei; LIANG Hui; FANG Xin; WANG Jiahui; FAN Lihua

doi:10.11949/0438-1157.20260207

您当前的位置：

首页 >

文章列表页 >

Mass transfer characteristics of an atomizing reactor in the preparation of magnesium hydroxide

更新时间：2026-06-09

- Mass transfer characteristics of an atomizing reactor in the preparation of magnesium hydroxide
- CIESC Journal (2026)
- 作者机构：
  
  沈阳工业大学化工装备学院，辽宁辽阳 111000
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20260207
  CLC： TQ132.2
- Received：10 February 2026，
  
  Revised：2026-06-04，
  
  Accepted：09 June 2026，
- 稿件说明：
移动端阅览
YU Honglei, LIANG Hui, FANG Xin, et al. Mass transfer characteristics of an atomizing reactor in the preparation of magnesium hydroxide[J/OL]. CIESC Journal, 2026.
DOI：

YU Honglei, LIANG Hui, FANG Xin, et al. Mass transfer characteristics of an atomizing reactor in the preparation of magnesium hydroxide[J/OL]. CIESC Journal, 2026. DOI： 10.11949/0438-1157.20260207.

摘要

通过理论模型与实验验证相结合，探讨了雾化反应器制备氢氧化镁的传质性能。基于表面更新理论建立了传质模型，预测精度较好（误差

10%）。实验结果表明，液气流量比和溶液浓度显著影响传质效率，最佳条件为液体流量60 L/h，氨气流量300 L/h（液气流量比2×10⁻³）、氯化镁溶液浓度25 wt%、温度308 K，此时传质系数（

）达到最大值2.53 kmol·kPa

-1

·m

-3

·s

-1

。雾化反应器在30 min内转化率达77.61%，较鼓泡反应器提升8.2%。反应时间缩短40 min，产物氢氧化镁粒径更小（D

降低74.12%）、分布更窄，晶体结构稳定。延长雾化时间至90分钟可获得规则六角片状氢氧化镁，提高分散性。本研究可为相关工艺优化提供基础理论与数据参考。

Abstract

The mass transfer performance of an atomizing reactor for magnesium hydroxide preparation was investigated through a combination of theoretical modeling and experimental validation. A mass transfer model based on surface renewal theory was developed and exhibited good predictive capability

with an error below 10%. The results demonstrated that the liquid–gas flow ratio and magnesium chloride solution concentration significantly influenced the mass transfer efficiency. Optimal conditions were obtained at a liquid flow rate of 60 L h⁻¹

an ammonia flow rate of 300 L h⁻¹ (liquid–gas flow ratio of 2 × 10⁻³)

a MgCl₂ solution concentration of 25 wt%

and a temperature of 308 K. Under these conditions

the volumetric mass

transfer coefficient (

) reached a maximum value of 2.53 kmol·kPa⁻¹·m⁻³·s⁻¹. The atomizing reactor achieved a conversion of 77.61% within 30 min

representing an 8.2% increase compared with a conventional bubble reactor

while reducing the reaction time by 40 min. Moreover

the obtained Mg(OH)₂ exhibited a significantly smaller particle size (D

reduced by 74.12%)

narrower size distribution

and stable crystal structure. Extending the atomization time to 90 min resulted in well-defined hexagonal plate-like Mg(OH)₂ with improved dispersion. This research can provide fundamental theories and data references for the optimization of related processes.

关键词

Keywords

references

周园 , 李丽娟 , 吴志坚 , 等 . 青海盐湖资源开发及综合利用 [J ] . 化学进展 , 2013 , 25 ( 10 ): 1613 - 1624 .

Zhou Y , Li L J , Wu Z J , et al . Exploitation and comprehensive utilization for Qinghai salt lakes [J ] . Progress in Chemistry , 2013 , 25 ( 10 ): 1613 - 1624 .

Pan X J , Dou Z H , Zhang T A , et al . Separation of metal ions and resource utilization of magnesium from saline lake brine by membrane electrolysis [J ] . Separation and Purification Technology , 2020 , 251 : 117316 .

Xu X Y , Lin Y J , Evans D G , et al . Layered intercalated functional materials based on efficient utilization of magnesium resources in China [J ] . Science China Chemistry , 2010 , 53 ( 7 ): 1461 - 1469 .

宋彭生 , 李武 , 孙柏 , 等 . 盐湖资源开发利用进展 [J ] . 无机化学学报 , 2011 , 27 ( 5 ): 801 - 815 .

Song P S , Li W , Sun B , et al . Recent development on comprehensive utilization of salt lake resources [J ] . Chinese Journal of Inorganic Chemistry , 2011 , 27 ( 5 ): 801 - 815 .

Satoshi Y , Seichiro O , Hiroyuki H , et al . Simultaneous crystallization of phosphate and potassium as magnesium potassium phosphate using bubble column reactor with draught tube [J ] . Journal of Environmental Chemical Engineering , 2013 , 1 ( 4 ): 1154 - 1158 .

Shen H Y , Liu Y Z . In situ synthesis of hydrophobic magnesium hydroxide nanoparticles in a novel impinging stream-rotating packed bed reactor [J ] . Chinese Journal of Chemical Engineering , 2016 , 24 ( 9 ): 1306 - 1312 .

Cheng L , Li T , Keener T C , et al . A mass transfer model of absorption of carbon dioxide in a bubble column reactor by using magnesium hydroxide slurry [J ] . International Journal of Greenhouse Gas Control , 2013 , 17 : 240 - 249 .

蒋仲安 , 许峰 , 王亚朋 , 等 . 空气雾化喷嘴雾化机理及影响因素实验分析 [J ] . 中南大学学报(自然科学版) , 2019 , 50 ( 10 ): 2360 - 2367 .

Jiang Z A , Xu F , Wang Y P , et al . Experimental analysis of atomization mechanism and influencing factors of air atomizing nozzle [J ] . Journal of Central South University (Science and Technology) , 2019 , 50 ( 10 ): 2360 - 2367 .

Wang P F , Shi Y J , Zhang L Y , et al . Effect of structural parameters on atomization characteristics and dust reduction performance of internal-mixing air-assisted atomizer nozzle [J ] . Process Safety and Environmental Protection , 2019 , 128 : 316 - 328 .

程泽宇 , 谢宇 , 郭志辉 . 双旋流气动雾化喷嘴近场区初始雾化特征实验研究 [J ] . 航空动力学报 , 2025 , 40 ( 7 ): 178 - 190 .

Cheng Z Y , Xie Y , Guo Z H . Experimental study on primary atomization characteristics of double swirl air-blast atomizer in near field region [J ] . Journal of Aerospace Power , 2025 , 40 ( 7 ): 178 - 190 .

Trofymenko P E , Khomenko O V , et al . Energy-saving technologies of liquid atomization: theoretical bases and engineering solutions [J ] . Romanian Journal of Physics , 2025 , 70 ( 5/6 ): 907 .

余爱萍 . 盐湖氯化镁连续制备高纯Mg(OH)_2工艺研究 [D ] . 大连 : 大连海事大学 , 2008 .

Yu A P . Study on continuous synthesizing technology of high purity magnesium hydroxide using magnesium chloride from salt lakes [D ] . Dalian : Dalian Maritime University , 2008 .

张婉婷 , 许晓波 , 邓列征 , 等 . 直叶片离心喷雾气液反应器分离性能 [J ] . 大连理工大学学报 , 2020 , 60 ( 4 ): 358 - 364 .

Zhang W T , Xu X B , Deng L Z , et al . Separation performance of straight blade centrifugal atomized gas-liquid reactor [J ] . Journal of Dalian University of Technology , 2020 , 60 ( 4 ): 358 - 364 .

Yu H L , Li Y L , Wang D X , et al . Analysis of atomization characteristics and efficient synthesis of Mg(OH)2 in micron scale atomization reactor [J ] . Physics of Fluids , 2024 , 36 ( 8 ): 083340 .

Yu H L , Fan L H , Wang D X , et al . Enhancing mixing characteristics of MgCl 2 solution within atomization nozzles: a computational fluid dynamics investigation of structural parameter [J ] . Chemical Engineering Research and Design , 2024 , 212 : 378 - 390 .

阙永生 , 杨辉 , 汪海风 , 等 . 采用表面更新模型与微观涡流模型制备MgAl-CO 3 LDHs纳米颗粒 [J ] . 材料科学与工程学报 , 2013 , 31 ( 6 ): 813 - 818 .

Que Y S , Yang H , Wang H F , et al . Synthesis of MgAl-CO 3 LDHs nanoparticles via surface renewal model and eddy cell model [J ] . Journal of Materials Science and Engineering , 2013 , 31 ( 6 ): 813 - 818 .

姜天彪 . 盐湖镁热解炉内六水氯化镁溶液雾化特性研究 [D ] . 沈阳 : 沈阳工业大学 , 2022 .

Jiang T B . Study on atomization characteristics of magnesium chloride hexahydrate solution in salt lake magnesium pyrolysis furnace [D ] . Shenyang : Shenyang University of Technology , 2022 .

范天博 , 姜宇 , 刘露萍 , 等 . 一步水热法合成六方片状氢氧化镁及其生长习性分析的研究 [J ] . 人工晶体学报 , 2017 , 46 ( 12 ): 2319 - 2325 .

Fan T B , Jiang Y , Liu L P , et al . Crystal growth habit of hexagonal flake magnesium hydroxide synthesized by one-stepHydrothermal method [J ] . Journal of Synthetic Crystals , 2017 , 46 ( 12 ): 2319 - 2325 .

刘志启 , 李丽娟 , 张东生 , 等 . 气液接触法制备球形氢氧化镁 [J ] . 无机化学学报 , 2014 , 30 ( 3 ): 705 - 709 .

Liu Z Q , Li L J , Zhang D S , et al . Spherical magnesium hydroxide prepared by gas-liquid contact method [J ] . Chinese Journal of Inorganic Chemistry , 2014 , 30 ( 3 ): 705 - 709 .

姚建平 , 范天博 , 王健 , 等 . 氨状态对氨法制备氢氧化镁颗粒性质的影响 [J ] . 化工学报 , 2012 , 63 ( 1 ): 314 - 319 .

Yao J P , Fan T B , Wang J , et al . Influence of ammonia state on particle characterization of magnesium hydroxide prepared via ammonia method [J ] . CIESC Journa , 2012 , 63 ( 1 ): 314 - 319 .

Tsai C Y , Chen Y S . Effective interfacial area and liquid-side mass transfer coefficients in a rotating bed equipped with baffles [J ] . Separation and Purification Technology , 2015 , 144 : 139 - 145 .

刘知邦 . 多级折流反应器强化CO 2 吸收工艺与机制研究 [D ] . 北京 : 北京化工大学 , 2022 .

Liu Z B . Study on processes and mechanism of CO 2 absorption intensified by a multistage rotating zigzag bed [D ] . Beijing : Beijing University of Chemical Technology , 2022 .

Luo Y , Chu G W , Zou H K , et al . Mass transfer studies in a rotating packed bed with novel rotors: chemisorption of CO 2 [J ] . Industrial & Engineering Chemistry Research , 2012 , 51 ( 26 ): 9164 - 9172 .

Li Y W , Si J M , Arowo M , et al . Experimental investigation of effective gas-liquid specific interfacial area in a rotor-stator reactor [J ] . Chemical Engineering and Processing - Process Intensification , 2020 , 148 : 107801 .

Magnin Y , Dirand E , Orsikowsky A , et al . A step in carbon capture from wet gases: understanding the effect of water on CO 2 adsorption and diffusion in UiO-66 [J ] . The Journal of Physical Chemistry C , 2022 , 126 ( 6 ): 3211 - 3220 .

Castellví F . An advanced method based on surface renewal theory to estimate the friction velocity and the surface heat flux [J ] . Water Resources Research , 2018 , 54 ( 12 ): 10, 134 - 10, 154 .

郭达 , 祁贵生 , 刘有智 , 等 . 错流旋转填料床的质、热同传性能及传热机理研究 [J ] . 化工学报 , 2021 , 72 ( 11 ): 5543 - 5551 .

Guo D , Qi G S , Liu Y Z , et al . Research on mass and heat synchronous performance and heat transfer mechanism of cross-flow rotating packed bed [J ] . CIESC Journal , 2021 , 72 ( 11 ): 5543 - 5551 .

郭奋 . 错流旋转床内流体力学与传质特性的研究 [D ] . 北京 : 北京化工大学 , 1996 .

Guo F . Study on hydrodynamics and mass transfer characteristics in cross-flow rotating bed [D ] . Beijing : Beijing University of Chemical Technology , 1996 .

张君 , 彭本军 , 黄浩 . 圆盘塔中CO 2 吸收的传质动力学研究 [J ] . 石油与天然气化工 , 2010 , 39 ( 2 ): 128 - 130 .

Zhang J , Peng B J , Huang H . Study on mass transfer kinetics of carbon dioxide absorption in disc column [J ] . Chemical Engineering of Oil and Gas , 2010 , 39 ( 2 ): 128 - 130 .

Yu H L , Wang D X , Chen G , et al . Insights int o the diffusion coefficient and adsorption energy of NH 3 in MgCl 2 from molecular simulation, experiments, and machine learning [J ] . Journal of Molecular Liquids , 2024 , 395 : 123822 .

Sklabinskyi V , Pavlenko I , Skydanenko M , et al . Improvement of mass transfer characteristics for the gas-liquid system in a vortex counterflow apparatus [J ] . Energies , 2025 , 18 ( 4 ): 1 - 18 .

王鑫 , 张莹 , 张丽 . 六方片状氢氧化镁的制备及其热分解动力学研究 [J ] . 无机盐工业 , 2026 , 58 ( 4 ): 49 - 55 .

Wang X , Zhang Y , Zhang L . Study on preparation and thermal decomposition kinetics of hexagonal plate-like magnesium hydroxide [J ] . Inorganic Chemicals Industry , 2026 , 58 ( 4 ): 49 - 55 .

李雪 , 程沛 , 侯睿 , 等 . 轻烧粉氨气法制备氢氧化镁阻燃剂的研究 [J ] . 无机盐工业 , 2016 , 48 ( 11 ): 21 - 24 .

Li X , Cheng P , Hou R , et al . Preparation of Mg(OH)2 with caustic calcined magnesia through ammonium circulation [J ] . Inorganic Chemicals Industry , 2016 , 48 ( 11 ): 21 - 24 .

孙晓君 , 丁珂 , 仇龙 , 等 . 以轻烧粉制备六方片状氢氧化镁 [J ] . 硅酸盐学报 , 2019 , 47 ( 4 ): 538 - 544 .

Sun X J , Ding K , Qiu L , et al . Preparation of hexagonal-sheet magnesium hydroxide by surfactant free method [J ] . Journal of the Chinese Ceramic Society , 2019 , 47 ( 4 ): 538 - 544 .

宋雪雪 , 李丽娟 , 刘志启 , 等 . 氨气法制备氢氧化镁工艺研究 [J ] . 化学工程 , 2014 , 42 ( 6 ): 74 - 78 .

Song X X , Li L J , Liu Z Q , et al . Preparation of magnesium hydroxide by ammonia gas method [J ] . Chemical Engineering (China) , 2014 , 42 ( 6 ): 74 - 78 .

申红艳 , 刘有智 , 朱芝敏 . 超重力反应器制备纳米氢氧化镁的实验研究 [J ] . 无机盐工业 , 2019 , 51 ( 4 ): 14 - 18, 31 .

Shen H Y , Liu Y Z , Zhu Z M . Study on preparation of magnesium hydroxide nanoparticles with high-gravity reactor [J ] . Inorganic Chemicals Industry , 2019 , 51 ( 4 ): 14 - 18, 31 .

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Construction and tetracycline hydrochloride degradation performance of g-C3N4/Fe3O4 microchannel reactor

Current status and research progress of crystallization technology of electronic grade phosphoric acid

Flow and mass transfer characteristics of Newtonian/non-Newtonian liquid-liquid flow in a microreactor

Research progress of reactors for liquid-liquid heterogeneous system

Comparative study on the flow and mass transfer characteristics of sub-millimeter bubbles and conventional bubbles in gas-liquid two-phase flow

Related Author

SUN Han

DONG Yanmao

ZHANG Yi

YUAN Yan

WU Haitao

PANG Shulei

DONG Ju

YU Liuyang

Related Institution

School of Chemistry and Life Sciences, Suzhou University of Science and Technology

State Key Laboratory of Chemical Engineering, School of Chemical Engineering and Technology, Tianjin University

State Key Laboratory of Efficient Utilization for Low Grade Phosphate Rock and Its Associated Resources

Wengfu (Group) Co., Ltd.

Dalian Institute of Chemical Physics, Chinese Academy of Sciences

⁰