Full-chain technological advances in e-fuels production from carbon capture in coal-fired power plants

WU Sheng; CHEN Jiangang; HOU Wenhao; REN Yawen

doi:10.11949/0438-1157.20260202

您当前的位置：

首页 >

文章列表页 >

Full-chain technological advances in e-fuels production from carbon capture in coal-fired power plants

更新时间：2026-06-03

- Full-chain technological advances in e-fuels production from carbon capture in coal-fired power plants
- CIESC Journal (2026)
- 作者机构：
  
  1.国家能源集团科学技术研究院有限公司，江苏南京 210000
  2.中国科学院山西煤炭化学研究所煤炭高效低碳利用全国重点实验室，山西太原 030000
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20260202
  CLC： TQ 028.8
- Received：09 February 2026，
  
  Revised：2026-06-02，
  
  Accepted：03 June 2026，
- 稿件说明：
移动端阅览
WU Sheng, CHEN Jiangang, HOU Wenhao, et al. Full-chain technological advances in e-fuels production from carbon capture in coal-fired power plants[J/OL]. CIESC Journal, 2026.
DOI：

WU Sheng, CHEN Jiangang, HOU Wenhao, et al. Full-chain technological advances in e-fuels production from carbon capture in coal-fired power plants[J/OL]. CIESC Journal, 2026. DOI： 10.11949/0438-1157.20260202.

摘要

随着“双碳”目标的提出，燃煤发电行业必须同时承担减排责任和能源安全责任。利用燃煤电厂集中的二氧化碳排放源，将碳捕集（CC）与二氧化碳加氢生产合成燃料（e-Fuels）相结合，可以成为燃煤发电低碳转型的一条可行途径。本文考察了完整的“CC to e-Fuels”技术链，概述了系统边界和关其键耦合环节。文章回顾了逆水煤气变换、费托合成、甲醇衍生化和直接加氢制烃等主流工程与实验室先进技术路线，并探讨了反应器类型、催化剂体系、原料气特性和工艺集成对系统性能的影响。综述分析表明，“CC to e-Fuels”的关键不仅在于单个装置的效率，而更多是在于碳捕集、氢气供应和合成转化之间的匹配与协调，以及在多装置耦合下实现能效与政策经济性的协同考量。总体而言，在实现减排效益，可以有效连接源头排放和下游合成，并满足合理的能源和工程限制的情况下，该路线就具备大规模示范和工程应用的基础，并可为燃煤发电的低碳转型提供有价值的补充。

Abstract

Under the dual-carbon strategy

coal-fired power plants confront increasing pressure to reduce CO₂ emissions while maintaining energy security. Coupling carbon capture (CC) with CO₂ hydrogenation to synthetic fuels (e-Fuels) provides a promising pathway for the low-carbon transition of coal power. This review focuses on the full-chain “CC to e-Fuels” system

covering carbon capture

hydrogen supply

syngas generation

fuel synthesis

and process integration. Major units

including reverse water-gas shift

Fischer–Tropsch synthesis

methanol-derived pathways

and direct CO₂ hydrogenation

are summarized. The analysis shows that the key challenge lies in the coordinated matching of carbon capture

hydrogen supply

and downstream conversion

rather than the efficiency of individual units alone. With appropriate technique

engineering

energy and economic boundaries

this pathway has potential for large-scale demonstration and may become an important complement to coal power decarbonization.

关键词

Keywords

references

国家统计局 . 中华人民共和国2025年国民经济和社会发展统计公报 [R ] . 北京 , 2026 .

National Bureau of Statistics of China . Statistical Communiqué of the People's Republic of China on National Economic and Social Development in 2025 [R ] . Beijing : NBS of China , 2026 .

生态环境部，国家统计局，国家能源局 . 2024年全国电力碳足迹因子 [R ] . 北京 , 2025 .

Ministry of Ecology and Environment of the PRC . National Electricity Carbon Footprint Factor in 2024 [R ] . Beijing : MEE of the PRC , 2025 .

Song C F , Liu Q L , Deng S , et al . Cryogenic-based CO 2 capture technologies: State-of-the-art developments and current challenges [J ] . Renewable and Sustainable Energy Reviews , 2019 , 101 : 265 - 278 .

Buttler A , Spliethoff H . Current status of water electrolysis for energy storage, grid balancing and sector coupling via power-to-gas and power-to-liquids: a review [J ] . Renewable and Sustainable Energy Reviews , 2018 , 82 : 2440 - 2454 .

Thiedemann T M , Wark M . A compact review of current technologies for carbon capture as well as storing and utilizing the captured CO 2 [J ] . Processes , 2025 , 13 ( 1 ): 283 .

Spigarelli B P , Kawatra S K . Opportunities and challenges in carbon dioxide capture [J ] . Journal of CO2 Utilization , 2013 , 1 : 69 - 87 .

张贤 , 杨晓亮 , 鲁玺，等 . 中国二氧化碳捕集利用与封存（CCUS）年度报告（2023） [R ] . 北京：中国21世纪议程管理中心，全球碳捕集与封存研究院，清华大学 . 2023 .

Zhang X , Yang X L , Lu X , et al . China Carbon Capture, Utilization and Storage (CCUS) Annual Report (2023) [R ] . Beijing : China Agenda 21 Management Center, Global Carbon Capture and Storage Research Institute, Tsinghua University . 2023 .

El Hadri N , Quang D V , Goetheer E L V , et al . Aqueous amine solution characterization for post-combustion CO 2 capture process [J ] . Applied Energy , 2017 , 185 : 1433 - 1449 .

Rezaei S , Liu A , Hovington P . Emerging technologies in post-combustion carbon dioxide capture & removal [J ] . Catalysis Today , 2023 , 423 : 114286 .

Kittel J , Idem R , Gelowitz D , et al . Corrosion in MEA units for CO 2 capture: Pilot plant studies [J ] . Energy Procedia , 2009 , 1 ( 1 ): 791 - 797 .

李阳 , 王锐 , 赵清民 , 等 . 中国碳捕集利用与封存技术应用现状及展望 [J ] . 石油科学通报 , 2023 , 8 ( 4 ): 391 - 397 .

Li Y , Wang R , Zhao Q M , et al . Status and prospects for CO 2 capture, utilization and storage technology in China [J ] . Petroleum Science Bulletin , 2023 , 8 ( 4 ): 391 - 397 .

刘宏臣 , 周峰 , 尧超群 , 等 . 微反应器内CO 2 解吸过程流动行为及气提强化 [J ] . 化工学报 , 2019 , 70 ( 7 ): 2448 - 2455 .

Liu H C , Zhou F , Yao C Q , et al . Flow behavior and stripping enhancement of CO 2 desorption process in microreactor [J ] . CIESC Journal , 2019 , 70 ( 7 ): 2448 - 2455 .

谭方园 , 李康康 , 于海 , 等 . 金属离子促进乙醇胺捕集二氧化碳研究 [J ] . 化工学报 , 2021 , 72 ( 2 ): 1026 - 1035 .

Tan F Y , Li K K , Yu H , et al . Metal ions mediated amine-based post-combustion CO 2 capture [J ] . CIESC Journal , 2021 , 72 ( 2 ): 1026 - 1035 .

Kumari M , Vega F , Gallego Fernández L M , et al . Liquid amine functional, aqueous blends and the CO 2 absorption capacity: Molecular structure, size, interaction parameter and mechanistic aspects [J ] . Journal of Molecular Liquids , 2023 , 384 : 122288 .

He X W , He H , Barzagli F , et al . Analysis of the energy consumption in solvent regeneration processes using binary amine blends for CO 2 capture [J ] . Energy , 2023 , 270 : 126903 .

Valluri S , Kawatra S K . Use of frothers to improve the absorption efficiency of dilute sodium carbonate slurry for post combustion CO 2 capture [J ] . Fuel Processing Technology , 2021 , 212 : 106620 .

Yu W , Wang T , Park A A , et al . Review of liquid nano-absorbents for enhanced CO 2 capture [J ] . Nanoscale , 2019 , 11 ( 37 ): 17137 - 17156 .

Sibhat M , Zhu Q X , Tsegay G , et al . Enhancement technologies of ammonia-based carbon capture: a review of developments and challenges [J ] . International Journal of Greenhouse Gas Control , 2024 , 136 : 104196 .

Liu F , Shen Y , Shen L , et al . Novel amino-functionalized ionic liquid/organic solvent with low viscosity for CO 2 capture [J ] . Environmental Science & Technology , 2020 , 54 ( 6 ): 3520 - 3529 .

冷浩 , 高建民 , 张宇 , 等 . 强化结晶氨法脱碳实验研究 [J ] . 化工学报 , 2016 , 67 ( 6 ): 2440 - 2448 .

Leng H , Gao J M , Zhang Y , et al . Carbon capture by ammonia with reinforced crystallization [J ] . CIESC Journal , 2016 , 67 ( 6 ): 2440 - 2448 .

张履胜 , 王治红 , 柳青 , 等 . 液-液相变吸收剂捕集二氧化碳研究进展 [J ] . 化工学报 , 2025 , 76 ( 3 ): 933 - 950 .

Zhang L S , Wang Z H , Liu Q , et al . Research progress in carbon dioxide capture using liquid-liquid phase change absorbents [J ] . CIESC Journal , 2025 , 76 ( 3 ): 933 - 950 .

张样 , 黄志甲 , 谢福松 , 等 . 基于二乙烯三胺甲酸盐-乙醇胺-二甲亚砜无水CO 2 吸收剂的制备及性能 [J ] . 化工进展 , 2025 , 44 ( 10 ): 6073 - 6082 .

Zhang Y , Huang Z J , Xie F S , et al . Preparation and properties investigation of CO 2 anhydrous absorbent based on diethylenetriamine-ethanolamine-dimethyl sulfoxide [J ] . Chemical Industry and Engineering Progress , 2025 , 44 ( 10 ): 6073 - 6082 .

Jiang W H , Hu J B , Sun C Q , et al . Low-energy phase-change absorbents for efficient onboard CO₂ capture in the maritime sector [J ] . Scientific Reports , 2025 , 15 : 40318 .

Hu Y L , Wang Q , Hu D K , et al . Experimental study on CO 2 capture by MEA/ n -butanol/H 2 O phase change absorbent [J ] . RSC Advances , 2024 , 14 ( 5 ): 3146 - 3157 .

Cheng S H , Zheng Y , Li G L , et al . Research progress on phase change absorbents for CO 2 capture in industrial flue gas: Principles and application prospects [J ] . Separation and Purification Technology , 2025 , 354 : 129296 .

Zhang G Y , Liu J S , Qian J , et al . Review of research progress and stability studies of amine-based biphasic absorbents for CO 2 capture [J ] . Journal of Industrial and Engineering Chemistry , 2024 , 134 : 28 - 50 .

刘博文 , 邓帅 , 李双俊 , 等 . 变温吸附碳捕集系统能效性能实验研究 [J ] . 化工学报 , 2020 , 71 ( S1 ): 382 - 390 .

Liu B W , Deng S , Li S J , et al . Experimental investigation on energy-efficiency performance of temperature swing adsorption system for CO 2 capture [J ] . CIESC Journal , 2020 , 71 ( S1 ): 382 - 390 .

Moreno-Castilla C , Rivera-Utrilla J . Carbon materials as adsorbents for the removal of pollutants from the aqueous phase [J ] . MRS Bulletin , 2001 , 26 ( 11 ): 890 - 894 .

Tong L , Yue T , Zuo P L , et al . Effect of characteristics of KI-impregnated activated carbon and flue gas components on Hg0 removal [J ] . Fuel , 2017 , 197 : 1 - 7 .

Prashantha Kumar H G , Xavior M A . Graphene reinforced metal matrix composite (GRMMC): a review [J ] . Procedia Engineering , 2014 , 97 : 1033 - 1040 .

Zhang J , Singh R , Webley P A . Alkali and alkaline-earth cation exchanged chabazite zeolites for adsorption based CO 2 capture [J ] . Microporous and Mesoporous Materials , 2008 , 111 ( 1/2/3 ): 478 - 487 .

Ghahramaninezhad M , Soleimani B , Niknam Shahrak M . A simple and novel protocol for Li-trapping with a POM/MOF nano-composite as a new adsorbent for CO 2 uptake [J ] . New Journal of Chemistry , 2018 , 42 ( 6 ): 4639 - 4645 .

Lee S Y , Park S J . A review on solid adsorbents for carbon dioxide capture [J ] . Journal of Industrial and Engineering Chemistry , 2015 , 23 : 1 - 11 .

Jahandar Lashaki M , Sayari A . CO 2 capture using triamine-grafted SBA-15: The impact of the support pore structure [J ] . Chemical Engineering Journal , 2018 , 334 : 1260 - 1269 .

Liu Y Y , Wang Z U , Zhou H C . Recent advances in carbon dioxide capture with metal-organic frameworks [J ] . Greenhouse Gases: Science and Technology , 2012 , 2 ( 4 ): 239 - 259 .

Millward A R , Yaghi O M . Metal−Organic frameworks with exceptionally high capacity for storage of carbon dioxide at room temperature [J ] . Journal of the American Chemical Society , 2005 , 127 ( 51 ): 17998 - 17999 .

Sanz-Pérez E S , Arencibia A , Calleja G , et al . Tuning the textural properties of HMS mesoporous silica. Functionalization towards CO 2 adsorption [J ] . Microporous and Mesoporous Materials , 2018 , 260 : 235 - 244 .

Zhao P Y , Zhang G J , Sun Y H , et al . CO 2 adsorption behavior and kinetics on amine-functionalized composites silica with trimodal nanoporous structure [J ] . Energy & Fuels , 2017 , 31 ( 11 ): 12508 - 12520 .

Martínez F , Sanz R , Orcajo G , et al . Amino-impregnated MOF materials for CO 2 capture at post-combustion conditions [J ] . Chemical Engineering Science , 2016 , 142 : 55 - 61 .

Sevilla M , Fuertes A B . Sustainable porous carbons with a superior performance for CO 2 capture [J ] . Energy & Environmental Science , 2011 , 4 ( 5 ): 1765 - 1771 .

Rashidi N A , Yusup S , Borhan A , et al . Experimental and modelling studies of carbon dioxide adsorption by porous biomass derived activated carbon [J ] . Clean Technologies and Environmental Policy , 2014 , 16 ( 7 ): 1353 - 1361 .

Meng L Y , Park S J . Effect of exfoliation temperature on carbon dioxide capture of graphene nanoplates [J ] . Journal of Colloid and Interface Science , 2012 , 386 ( 1 ): 285 - 290 .

Orefuwa S , Iriowen E , Yang H W , et al . Effects of nitro-functionalization on the gas adsorption properties of isoreticular metal-organic framework-eight (IRMOF-8) [J ] . Microporous and Mesoporous Materials , 2013 , 177 : 82 - 90 .

Furukawa H , Ko N , Go Y B , et al . Ultrahigh porosity in metal-organic frameworks [J ] . Science , 2010 , 329 ( 5990 ): 424 - 428 .

Li H L , Eddaoudi M , O’Keeffe M , et al . Design and synthesis of an exceptionally stable and highly porous metal-organic framework [J ] . Nature , 1999 , 402 ( 6759 ): 276 - 279 .

Cinke M , Li J , Bauschlicher C W , et al . CO 2 adsorption in single-walled carbon nanotubes [J ] . Chemical Physics Letters , 2003 , 376 ( 5/6 ): 761 - 766 .

Kikkinides E S , Yang R T , Cho S H . Concentration and recovery of carbon dioxide from flue gas by pressure swing adsorption [J ] . Industrial & Engineering Chemistry Research , 1993 , 32 ( 11 ): 2714 - 2720 .

Li J R , Kuppler R J , Zhou H C . Selective gas adsorption and separation in metal–organic frameworks [J ] . Chemical Society Reviews , 2009 , 38 ( 5 ): 1477 - 1504 .

Berlier K , Frère M . Adsorption of CO 2 on activated carbon: simultaneous determination of integral heat and isotherm of adsorption [J ] . Journal of Chemical & Engineering Data , 1996 , 41 ( 5 ): 1144 - 1148 .

Hou C , Liu Q , Wang P , et al . Porous metal–organic frameworks with high stability and selective sorption for CO 2 over N2 [J ] . Microporous and Mesoporous Materials , 2013 , 172 : 61 - 66 .

Harlick P J E , Tezel F H . An experimental adsorbent screening study for CO 2 removal from N2 [J ] . Microporous and Mesoporous Materials , 2004 , 76 ( 1/2/3 ): 71 - 79 .

Siriwardane R V , Shen M S , Fisher E P . Adsorption of CO 2 , N 2 , and O 2 on natural zeolites [J ] . Energy & Fuels , 2003 , 17 ( 3 ): 571 - 576 .

Leeson D , Mac Dowell N , Shah N , et al . A Techno-economic analysis and systematic review of carbon capture and storage (CCS) applied to the iron and steel, cement, oil refining and pulp and paper industries, as well as other high purity sources [J ] . International Journal of Greenhouse Gas Control , 2017 , 61 : 71 - 84 .

Sholl D S , Lively R P . Seven chemical separations to change the world [J ] . Nature , 2016 , 532 ( 7600 ): 435 - 437 .

Bernardo P , Drioli E , Golemme G . Membrane gas separation: a review/state of the art [J ] . Industrial & Engineering Chemistry Research , 2009 , 48 ( 10 ): 4638 - 4663 .

Baker R W , Freeman B , Kniep J , et al . CO 2 capture from cement plants and steel mills using membranes [J ] . Industrial & Engineering Chemistry Research , 2018 , 57 ( 47 ): 15963 - 15970 .

He X Z , Lindbråthen A , Kim T J , et al . Pilot testing on fixed-site-carrier membranes for CO 2 capture from flue gas [J ] . International Journal of Greenhouse Gas Control , 2017 , 64 : 323 - 332 .

Smith S J D , Hou R J , Konstas K , et al . Control of physical aging in super-glassy polymer mixed matrix membranes [J ] . Accounts of Chemical Research , 2020 , 53 ( 7 ): 1381 - 1388 .

Hou R J , Fong C , Freeman B D , et al . Current status and advances in membrane technology for carbon capture [J ] . Separation and Purification Technology , 2022 , 300 : 121863 .

Merkel T C , Lin H Q , Wei X T , et al . Power plant post-combustion carbon dioxide capture: an opportunity for membranes [J ] . Journal of Membrane Science , 2010 , 359 ( 1/2 ): 126 - 139 .

张建民 , 何美贵 , 贾万鑫 , 等 . 聚氧化乙烯/冠醚共混膜及其二氧化碳分离性能 [J ] . 化工学报 , 2025 , 76 ( 9 ): 4862 - 4871 .

Zhang J M , He M G , Jia W X , et al . Poly(ethylene oxide)/crown ether blend membrane and performance for CO 2 separation [J ] . CIESC Journal , 2025 , 76 ( 9 ): 4862 - 4871 .

Mohsenpour , Chehrazi E . Metal–organic-frameworks based mixed-matrix membranes for CO 2 separation: an applicable-conceptual approach [J ] . ACS Applied Materials & Interfaces , 2024 , 16 ( 26 ): 32906 - 32929 .

Welton C , Chen F , Zhou H C , et al . Mixed matrix membrane formation with porous metal–organic nanomaterials for CO 2 capture and separation: a critical review [J ] . Carbon Capture Science & Technology , 2025 , 14 : 100347 .

Cao M Y , Zhao L H , Xu D W , et al . A carbon molecular sieve membrane-based reactive separation process for pre-combustion CO 2 capture [J ] . Journal of Membrane Science , 2020 , 605 : 118028 .

Batorshin V A , Suchkov S I , Tugov A N . Integrated gasification combined cycle (IGCC) units: history, state-of-the art, development prospects (review) [J ] . Thermal Engineering , 2023 , 70 ( 6 ): 418 - 429 .

Payne R , L CHEN S , Wolsky A M , et al . CO 2 recovery via coal combustion in mixtures of oxygen and recycled flue gas [J ] . Combustion Science and Technology , 1989 , 67 ( 1/2/3 ): 1 - 16 .

Ndibe C , Spörl R , Maier J , et al . Experimental study of NO and NO 2 formation in a PF oxy-fuel firing system [J ] . Fuel , 2013 , 107 : 749 - 756 .

Buhre B J P , Elliott L K , Sheng C D , et al . Oxy-fuel combustion technology for coal-fired power generation [J ] . Progress in Energy and Combustion Science , 2005 , 31 ( 4 ): 283 - 307 .

Nandy A , Loha C , Gu S , et al . Present status and overview of Chemical Looping Combustion technology [J ] . Renewable and Sustainable Energy Reviews , 2016 , 59 : 597 - 619 .

Daneshmand-Jahromi S , Sedghkerdar M H , Mahinpey N . A review of chemical looping combustion technology: Fundamentals, and development of natural, industrial waste, and synthetic oxygen carriers [J ] . Fuel , 2023 , 341 : 127626 .

中国东方电气集团有限公司 . 全球最大化学链燃烧示范装置建成 [EB/OL ] . 北京 : 国务院国有资产监督管理委员会 , 2023 [ 2026-03-02 ] . http://www.sasac.gov.cn/n2588025/n2588124/c27618599/content.html http://www.sasac.gov.cn/n2588025/n2588124/c27618599/content.html .

China Eastern Electric Group Co., Ltd . World's largest chemical looping combustion demonstration device completed [EB/OL ] . Beijing : State-owned Assets Supervision and Administration Commission of the State Council , 2023 [ 2026-03-02 ] . http://www.sasac.gov.cn/n2588025/n2588124/c27618599/content.html http://www.sasac.gov.cn/n2588025/n2588124/c27618599/content.html .

李振山 . 能动系研究团队在化学链燃烧技术研究中取得重大进展 [EB/OL ] . 北京 : 清华大学 , 2024 [ 2026-03-02 ] . https://www.te.tsinghua.edu.cn/info/1095/3291.htm https://www.te.tsinghua.edu.cn/info/1095/3291.htm .

Li Z . Energy and Power Engineering Research Team Makes Major Progress in Chemical Looping Combustion Technology Research [EB/OL ] . Beijing : Tsinghua University , 2024 [ 2026-03-02 ] . https://www.te.tsinghua.edu.cn/info/1095/3291.htm https://www.te.tsinghua.edu.cn/info/1095/3291.htm .

McQueen N , Gomes K V , McCormick C , et al . A review of direct air capture (DAC): scaling up commercial technologies and innovating for the future [J ] . Progress in Energy , 2021 , 3 ( 3 ): 032001 .

Keith D W , Holmes G , St Angelo D , et al . A process for capturing CO 2 from the atmosphere [J ] . Joule , 2018 , 2 ( 8 ): 1573 - 1594 .

Choi S , Watanabe T , Bae T H , et al . Modification of the Mg/DOBDC MOF with amines to enhance CO 2 adsorption from ultradilute gases [J ] . The Journal of Physical Chemistry Letters , 2012 , 3 ( 9 ): 1136 - 1141 .

Climeworks . Turn CO₂ removal into economic value [EB/OL ] . Swiss : Climeworks , 2009 [ 2026-01-03 ] . https://climeworks.com https://climeworks.com .

Carbon Engineering . We believe humanity can Achieve net zero [EB/OL ] . Squamish : Carbon Engineering , 2009 [ 2026-01-03 ] . https://carbonengineering.com https://carbonengineering.com .

Zero Carbon Systems . We remove CO 2 from the air to counter climate change [EB/OL ] . Denver : Zero Carbon Systems , 2020 [ 2026-01-03 ] . https://www.zerocarbonsystems.com https://www.zerocarbonsystems.com .

Fasihi M , Efimova O , Breyer C . Techno-economic assessment of CO 2 direct air capture plants [J ] . Journal of Cleaner Production , 2019 , 224 : 957 - 980 .

Zhang Y R , Zhao S , Li L J , et al . Integrated CO 2 capture and utilization: a review of the synergistic effects of dual function materials [J ] . Catalysis Science & Technology , 2024 , 14 ( 4 ): 790 - 819 .

Sun H M , Sun S Z , Liu T , et al . Integrated CO 2 capture and utilization: selection, matching, and interactions between adsorption and catalytic sites [J ] . ACS Catalysis , 2024 , 14 ( 20 ): 15572 - 15589 .

Kim Y , Lees E W , Donde C , et al . Integrated CO 2 capture and conversion to form syngas [J ] . Joule , 2024 , 8 ( 11 ): 3106 - 3125 .

Badreldin A , Li Y . A critical appraisal of advances in integrated CO 2 capture and electrochemical conversion [J ] . Chemical Science , 2025 , 16 ( 6 ): 2483 - 2513 .

Vedrtnam A , Kalauni K , Pahwa R . A review of water electrolysis technologies with insights into optimization and numerical simulations [J ] . International Journal of Hydrogen Energy , 2025 , 140 : 694 - 727 .

El-Shafie M . Hydrogen production by water electrolysis technologies: a review [J ] . Results in Engineering , 2023 , 20 : 101426 .

Solmaz R , Döner A , Doğrubaş M , et al . Enhancement of electrochemical activity of Raney-type NiZn coatings by modifying with PtRu binary deposits: Application for alkaline water electrolysis [J ] . International Journal of Hydrogen Energy , 2016 , 41 ( 3 ): 1432 - 1440 .

Etzi Coller Pascuzzi M , Man A J W , Goryachev A , et al . Investigation of the stability of NiFe-(oxy)hydroxide anodes in alkaline water electrolysis under industrially relevant conditions [J ] . Catalysis Science & Technology , 2020 , 10 ( 16 ): 5593 - 5601 .

Bhandari R , Trudewind C A , Zapp P . Life cycle assessment of hydrogen production via electrolysis–a review [J ] . Journal of Cleaner Production , 2014 , 85 : 151 - 163 .

Rakousky C , Reimer U , Wippermann K , et al . Polymer electrolyte membrane water electrolysis: Restraining degradation in the presence of fluctuating power [J ] . Journal of Power Sources , 2017 , 342 : 38 - 47 .

Langemann M , Fritz D L , Müller M , et al . Validation and characterization of suitable materials for bipolar plates in PEM water electrolysis [J ] . International Journal of Hydrogen Energy , 2015 , 40 ( 35 ): 11385 - 11391 .

Wang Y , Guo W Q , Xing D F , et al . Hydrogen production using biocathode single-chamber microbial electrolysis cells fed by molasses wastewater at low temperature [J ] . International Journal of Hydrogen Energy , 2014 , 39 ( 33 ): 19369 - 19375 .

Carmo M , Fritz D L , Mergel J , et al . A comprehensive review on PEM water electrolysis [J ] . International Journal of Hydrogen Energy , 2013 , 38 ( 12 ): 4901 - 4934 .

Wang C R , et al . Proton exchange membrane (PEM) water electrolysis: cell-level considerations for gigawatt-scale deployment [J ] . Chemical Reviews , 2025 , 125 ( 3 ): 1257 - 1302 .

Sharma A , Hussain Mehdi S E , Pandit S , et al . Factors affecting hydrogen production in microbial electrolysis cell (MEC): a review [J ] . International Journal of Hydrogen Energy , 2024 , 61 : 1473 - 1484 .

Kilicaslan A F , Dincer I , Khalvati A . Microbial electrolysis cells designed for BioH2 production: Potential improvements with carbon dioxide and nitrogen [J ] . International Journal of Hydrogen Energy , 2024 , 62 : 794 - 802 .

Ehlers J C , Feidenhans’l A A , Therkildsen K T , et al . Affordable green hydrogen from alkaline water electrolysis: key research needs from an industrial perspective [J ] . ACS Energy Letters , 2023 , 8 ( 3 ): 1502 - 1509 .

黄琮琪 , 吴一梅 , 陈建业 , 等 . 碱性电解水制氢装置热管理系统仿真研究 [J ] . 化工学报 , 2023 , 74 ( S1 ): 320 - 328 .

Huang C Q , Wu Y M , Chen J Y , et al . Simulation study of thermal management system of alkaline water electrolysis device for hydrogen production [J ] . CIESC Journal , 2023 , 74 ( S1 ): 320 - 328 .

Kıstı M , Hüner B , Albadwi A , et al . Recent advances in polymer electrolyte membrane water electrolyzer stack development studies: a review [J ] . ACS Omega , 2025 , 10 ( 10 ): 9824 - 9853 .

Wang T Z , Cao X J , Jiao L F . PEM water electrolysis for hydrogen production: fundamentals, advances, and prospects [J ] . Carbon Neutrality , 2022 , 1 ( 1 ): 21 .

Bora A , Mohanrasu K , Angelin Swetha T , et al . Microbial electrolysis cell (MEC): Reactor configurations, recent advances and strategies in biohydrogen production [J ] . Fuel , 2022 , 328 : 125269 .

Liu J W , Liu H , Yang Y , et al . Efficient and stable proton exchange membrane water electrolysis enabled by stress optimization [J ] . ACS Central Science , 2024 , 10 ( 4 ): 852 - 859 .

赵鹏飞 , 戚若玫 , 郭新锋 , 等 . 千标方级碱性水电解制氢系统氧中氢杂质分析 [J ] . 化工学报 , 2025 , 76 ( 4 ): 1765 - 1778 .

Zhao P F , Qi R M , Guo X F , et al . Analysis of hydrogen-to-oxygen impurities in a 1000 m3/h alkaline water electrolysis system [J ] . CIESC Journal , 2025 , 76 ( 4 ): 1765 - 1778 .

Kuleshov V N , Kuleshov N V , Grigoriev S A , et al . Development and characterization of new nickel coatings for application in alkaline water electrolysis [J ] . International Journal of Hydrogen Energy , 2016 , 41 ( 1 ): 36 - 45 .

Flis-Kabulska I , Flis J , Sun Y , et al . Hydrogen evolution on plasma carburised nickel and effect of iron deposition from the electrolyte in alkaline water electrolysis [J ] . Electrochimica Acta , 2015 , 167 : 61 - 68 .

Dash S , Arjun Singh K , Jose S , et al . Advances in green hydrogen production through alkaline water electrolysis: a comprehensive review [J ] . International Journal of Hydrogen Energy , 2024 , 83 : 614 - 629 .

Bhattacharyya R , Misra A , Sandeep K C . Photovoltaic solar energy conversion for hydrogen production by alkaline water electrolysis: Conceptual design and analysis [J ] . Energy Conversion and Management , 2017 , 133 : 1 - 13 .

González-Buch C , Herraiz-Cardona I , Ortega E M , et al . Synthesis and characterization of Au-modified macroporous Ni electrocatalysts for alkaline water electrolysis [J ] . International Journal of Hydrogen Energy , 2016 , 41 ( 2 ): 764 - 772 .

Zuo Y , Bellani S , Ferri M , et al . High-performance alkaline water electrolyzers based on Ru-perturbed Cu nanoplatelets cathode [J ] . Nature Communications , 2023 , 14 : 4680 .

白谨豪 , 管小平 , 杨宁 . 压滤式水电解槽乳突板内的流动特性分析与优化 [J ] . 化工学报 , 2025 , 76 ( 2 ): 584 - 595 .

Bai J H , Guan X P , Yang N . Analysis and optimization of flow characteristics in a filter-press water electrolyzer mastoid plate [J ] . CIESC Journal , 2025 , 76 ( 2 ): 584 - 595 .

Egelund S , Caspersen M , Nikiforov A , et al . Manufacturing of a LaNiO3 composite electrode for oxygen evolution in commercial alkaline water electrolysis [J ] . International Journal of Hydrogen Energy , 2016 , 41 ( 24 ): 10152 - 10160 .

Yao S K , Wang C C , Li M , et al . Dimensionally stable NiFe@Co/Ti nanoporous electrodes by reactive deposition for water electrolysis [J ] . International Journal of Hydrogen Energy , 2017 , 42 ( 10 ): 7143 - 7150 .

Wang M Y , Wang Z , Gong X Z , et al . The intensification technologies to water electrolysis for hydrogen production–A review [J ] . Renewable and Sustainable Energy Reviews , 2014 , 29 : 573 - 588 .

Kumar S S , Himabindu V . Hydrogen production by PEM water electrolysis–A review [J ] . Materials Science for Energy Technologies , 2019 , 2 ( 3 ): 442 - 454 .

Xu W , Scott K . The effects of ionomer content on PEM water electrolyser membrane electrode assembly performance [J ] . International Journal of Hydrogen Energy , 2010 , 35 ( 21 ): 12029 - 12037 .

Martin S , Garcia-Ybarra P L , Castillo J L . Ten-fold reduction from the state-of-the-art platinum loading of electrodes prepared by electrospraying for high temperature proton exchange membrane fuel cells [J ] . Electrochemistry Communications , 2018 , 93 : 57 - 61 .

Ramakrishna S U B , Srinivasulu Reddy D , Shiva Kumar S , et al . Nitrogen doped CNTs supported Palladium electrocatalyst for hydrogen evolution reaction in PEM water electrolyser [J ] . International Journal of Hydrogen Energy , 2016 , 41 ( 45 ): 20447 - 20454 .

Ayers K E , Renner J N , Danilovic N , et al . Pathways to ultra-low platinum group metal catalyst loading in proton exchange membrane electrolyzers [J ] . Catalysis Today , 2016 , 262 : 121 - 132 .

Lee B S , Park H Y , Choi I , et al . Polarization characteristics of a low catalyst loading PEM water electrolyzer operating at elevated temperature [J ] . Journal of Power Sources , 2016 , 309 : 127 - 134 .

Badwal S P S , Giddey S , Ciacchi F T . Hydrogen and oxygen generation with polymer electrolyte membrane (PEM)-based electrolytic technology [J ] . Ionics , 2006 , 12 ( 1 ): 7 - 14 .

Hinnemann B , Moses P G , Bonde J , et al . Biomimetic hydrogen evolution: MoS 2 nanoparticles as catalyst for hydrogen evolution [J ] . ChemInform , 2005 , 36 ( 25 ): 200525015 .

Sarno M , Ponticorvo E . High hydrogen production rate on RuS2@MoS 2 hybrid nanocatalyst by PEM electrolysis [J ] . International Journal of Hydrogen Energy , 2019 , 44 ( 9 ): 4398 - 4405 .

Sarkar S , Peter S C . An overview on Pd-based electrocatalysts for the hydrogen evolution reaction [J ] . Inorganic Chemistry Frontiers , 2018 , 5 ( 9 ): 2060 - 2080 .

Hasa B , Aryal U R , Higashi S , et al . Porous transport layer influence on overpotentials in PEM water electrolysis at low anode catalyst loadings [J ] . Applied Catalysis B: Environment and Energy , 2025 , 361 : 124616 .

Zhang L , Liu J , Du S J . Optimizing porous transport layers in PEM water electrolyzers: a 1D two-phase model [J ] . Batteries , 2025 , 11 ( 6 ): 222 .

张生安 , 刘桂莲 . 高效太阳能电解水制氢系统及其性能的多目标优化 [J ] . 化工学报 , 2023 , 74 ( 3 ): 1260 - 1274 .

Zhang S A , Liu G L . Multi-objective optimization of high-efficiency solar water electrolysis hydrogen production system and its performance [J ] . CIESC Journal , 2023 , 74 ( 3 ): 1260 - 1274 .

陶智能 , 邱彤 , 王保国 . 阴离子交换膜电解水制氢稳态建模 [J ] . 化工学报 , 2025 , 76 ( 4 ): 1711 - 1721 .

Tao Z N , Qiu T , Wang B G . Steady-state modeling on hydrogen production by anion exchange membrane water electrolysis [J ] . CIESC Journal , 2025 , 76 ( 4 ): 1711 - 1721 .

周怀荣 , 伊嘉伟 , 曹阿波 , 等 . 共电解耦合CO 2 间接加氢制甲醇工艺集成设计与性能评价 [J ] . 化工学报 , 2025 , 76 ( 9 ): 4586 - 4600 .

Zhou H R , Yi J W , Cao A B , et al . Integrated design and performance evaluation of co-electrolysis coupled CO 2 indirect hydrogenation methanol synthesis process [J ] . CIESC Journal , 2025 , 76 ( 9 ): 4586 - 4600 .

Kim-Lohsoontorn P , Bae J . Electrochemical performance of solid oxide electrolysis cell electrodes under high-temperature coelectrolysis of steam and carbon dioxide [J ] . Journal of Power Sources , 2011 , 196 ( 17 ): 7161 - 7168 .

Luo Y , Shi Y X , Li W Y , et al . Comprehensive modeling of tubular solid oxide electrolysis cell for co-electrolysis of steam and carbon dioxide [J ] . Energy , 2014 , 70 : 420 - 434 .

Zhang W Q , Zheng Y , Yu B , et al . Electrochemical characterization and mechanism analysis of high temperature co-electrolysis of CO 2 and H 2 O in a solid oxide electrolysis cell [J ] . International Journal of Hydrogen Energy , 2017 , 42 ( 50 ): 29911 - 29920 .

Xi C Q , Sang J K , Wu A Q , et al . Electrochemical performance and durability of flat-tube solid oxide electrolysis cells for H 2 O/CO 2 co-electrolysis [J ] . International Journal of Hydrogen Energy , 2022 , 47 ( 18 ): 10166 - 10174 .

Ioannidou E , Neophytides S , Niakolas D K . Experimental clarification of the RWGS reaction effect in H 2 O/CO 2 SOEC co-electrolysis conditions [J ] . Catalysts , 2019 , 9 ( 2 ): 151 .

Xu Y H , Cai S S , Chi B , et al . Technological limitations and recent developments in a solid oxide electrolyzer cell: a review [J ] . International Journal of Hydrogen Energy , 2024 , 50 : 548 - 591 .

Alenazey F , Alyousef Y , Almisned O , et al . Production of synthesis gas (H2 and CO) by high-temperature co-electrolysis of H 2 O and CO 2 [J ] . International Journal of Hydrogen Energy , 2015 , 40 ( 32 ): 10274 - 10280 .

Hubert M , Laurencin J , Cloetens P , et al . Impact of Nickel agglomeration on Solid Oxide Cell operated in fuel cell and electrolysis modes [J ] . Journal of Power Sources , 2018 , 397 : 240 - 251 .

Skafte T L , Graves C , Blennow P , et al . Carbon deposition during CO 2 electrolysis in Ni-based solid-oxide-cell electrodes [J ] . ECS Transactions , 2015 , 68 ( 1 ): 3429 - 3437 .

Nechache A , Boukamp B A , Cassir M , et al . Accelerated degradation of yttria stabilized zirconia electrolyte during high-temperature water electrolysis [J ] . Journal of Solid State Electrochemistry , 2019 , 23 ( 3 ): 871 - 881 .

Nechache A , Cassir M , Ringuedé A . Solid oxide electrolysis cell analysis by means of electrochemical impedance spectroscopy: a review [J ] . Journal of Power Sources , 2014 , 258 : 164 - 181 .

Kadier A , Simayi Y , Abdeshahian P , et al . A comprehensive review of microbial electrolysis cells (MEC) reactor designs and configurations for sustainable hydrogen gas production [J ] . Alexandria Engineering Journal , 2016 , 55 ( 1 ): 427 - 443 .

Kadier A , Jain P , Lai B , et al . Biorefinery perspectives of microbial electrolysis cells (MECs) for hydrogen and valuable chemicals production through wastewater treatment [J ] . Biofuel Research Journal , 2020 , 7 ( 1 ): 1128 - 1142 .

Ye Y J , Wang L Y , Chen Y W , et al . High yield hydrogen production in a single-chamber membrane-less microbial electrolysis cell [J ] . Water Science and Technology , 2010 , 61 ( 3 ): 721 - 727 .

Ma X L , Li Z F , Zhou A J , et al . Energy recovery from tubular microbial electrolysis cell with stainless steel mesh as cathode [J ] . Royal Society Open Science , 2017 , 4 ( 12 ): 170967 .

Hu H Q , Fan Y Z , Liu H . Optimization of NiMo catalyst for hydrogen production in microbial electrolysis cells [J ] . International Journal of Hydrogen Energy , 2010 , 35 ( 8 ): 3227 - 3233 .

Lei G , Wang Y Q , Xiao G , et al . CoMo/SS cathode catalyst for enhanced hydrogen production in microbial electrolysis cells [J ] . Catalysts , 2025 , 15 ( 5 ): 439 .

Tang J , Bian Y H , Jin S , et al . Cathode material development in the past decade for H 2 production from microbial electrolysis cells [J ] . ACS Environmental Au , 2022 , 2 ( 1 ): 20 - 29 .

Manuel M F , Neburchilov V , Wang H , et al . Hydrogen production in a microbial electrolysis cell with nickel-based gas diffusion cathodes [J ] . Journal of Power Sources , 2010 , 195 ( 17 ): 5514 - 5519 .

Jiang J Y , Lopez-Ruiz J A , Bian Y H , et al . Scale-up and techno-economic analysis of microbial electrolysis cells for hydrogen production from wastewater [J ] . Water Research , 2023 , 241 : 120139 .

徐明 , 邵明飞 , 刘清雅 , 等 . 电解水制氢耦合碳酸盐还原展望 [J ] . 化工进展 , 2022 , 41 ( 3 ): 1121 - 1124 .

Xu M , Shao M F , Liu Q Y , et al . Hydrogen generation from electrochemical water splitting coupling carbonate reduction [J ] . Chemical Industry and Engineering Progress , 2022 , 41 ( 3 ): 1121 - 1124 .

殷爱鸣 , 李建华 , 聂晋峰 , 等 . 大型电解水制氢工厂水系统与节水展望 [J ] . 工业水处理 , 2026 , 46 ( 4 ): 17 - 24 .

Yin A M , Li J H , Nie J F , et al . Water system and water saving outlook of large-scale renewable energy electrolysis hydrogen production plant [J ] . Industrial Water Treatment , 2026 , 46 ( 4 ): 17 - 24 .

陈建刚 , 相宏伟 , 李永旺 , 等 . 费托法合成液体燃料关键技术研究进展 [J ] . 化工学报 , 2003 , 54 ( 4 ): 516 - 523 .

Chen J G , Xiang H W , Li Y W , et al . Advance in key techniques of Fischer-Tropsch synthesis for liquid fuel production [J ] . Journal of Chemical Industry and Engineering (China) , 2003 , 54 ( 4 ): 516 - 523 .

Stone F S , Waller D . Cu–ZnO and Cu–ZnO/Al 2 O 3 catalysts for the reverse water-gas shift reaction. the effect of the Cu/Zn ratio on precursor characteristics and on the activity of the derived catalysts [J ] . Topics in Catalysis , 2003 , 22 ( 3 ): 305 - 318 .

Iqbal M W , Yu Y , Simakov D S A . Enhancing the surface area stability of the cerium oxide reverse water gas shift nanocatalyst via reverse microemulsion synthesis [J ] . Catalysis Today , 2023 , 407 : 230 - 243 .

Seuser G , Martinelli M , Garcia E S , et al . Reverse water-gas shift: Na doping of m-ZrO 2 supported Pt for selectivity control [J ] . Applied Catalysis A: General , 2023 , 650 : 119000 .

Kim S S , Lee H H , Hong S C . The effect of the morphological characteristics of TiO 2 supports on the reverse water–gas shift reaction over Pt/TiO 2 catalysts [J ] . Applied Catalysis B: Environmental , 2012 , 119 : 100 - 108 .

Xu J H , Liu Z H , Zhang R Y , et al . Solid solution derived Cu clusters on partially reduced CuCeO 2 with abundant oxygen vacancies enable efficient reverse water gas reaction [J ] . Chemistry – An Asian Journal , 2025 , 20 ( 8 ): e202401485 .

Ajakaiye Jensen L I , Blomberg S , Hulteberg C . Effect of Pd and Ir as promoters in the activity of Ni/CeZrO 2 catalyst for the reverse water-gas shift reaction [J ] . Catalysts , 2021 , 11 ( 9 ): 1076 .

Wang J R , Wang C X , Feng Y Q , et al . Cu/CeO 2 catalysts for reverse water gas shift reactions: the effect of the preparation method [J ] . RSC Advances , 2024 , 14 ( 24 ): 16736 - 16746 .

Holder C , Shabaev A , Baldwin J , et al . Elucidating the role of the Mo2C/MgO catalyst interface in the mechanism of the reverse water gas shift reaction [J ] . Nanomaterials , 2025 , 15 ( 20 ): 1591 .

Chen L , Wu D R , Wang C Z , et al . Study on Cu-Fe/CeO 2 bimetallic catalyst for reverse water gas shift reaction [J ] . Journal of Environmental Chemical Engineering , 2021 , 9 ( 3 ): 105183 .

Zhang Q , Pastor-Pérez L , Gu S , et al . Transition metal carbides (TMCs) catalysts for gas phase CO 2 upgrading reactions: a comprehensive overview [J ] . Catalysts , 2020 , 10 ( 9 ): 955 .

Zhang Q , Bown M , Pastor-Pérez L , et al . CO 2 conversion via reverse water gas shift reaction using fully selective Mo–P multicomponent catalysts [J ] . Industrial & Engineering Chemistry Research , 2022 , 61 ( 34 ): 12857 - 12865 .

Du Y S , Sun Z Q , Ma H M , et al . The copper-cerium catalyst promoted by SMSI has achieved the efficient conversion of RWGS [J ] . Molecular Catalysis , 2025 , 587 : 115517 .

Brust D , Wullenkord M , Gómez H G , et al . Experimental investigation of photo-thermal catalytic reactor for the reverse water gas shift reaction under concentrated irradiation [J ] . Journal of Environmental Chemical Engineering , 2024 , 12 ( 5 ): 113372 .

Kim D Y , Zhang W J , Dong K Y , et al . Plasma-driven redox mechanism in the reverse water–gas shift reaction over Ni–In intermetallic catalysts [J ] . EES Catalysis , 2025 , 3 ( 5 ): 1098 - 1105 .

Mo S P , University T , et al . Asymmetric interaction between carbon and Ni-cluster in Ni–C–In photothermal catalysts for point-concentrated solar-driven CO 2 reverse water–gas shift reaction [J ] . ACS Catalysis , 2025 , 15 ( 4 ): 2796 - 2808 .

Farzi F , Baudillon E , Kersaudy R , et al . Non-thermal plasma-enhanced reverse water-gas shift reaction over hydroxyapatite-supported Ni catalyst: Effect of severe process conditions [J ] . Journal of CO2 Utilization , 2025 , 100 : 103181 .

Ghuman K K , Hoch L B , Szymanski P , et al . Photoexcited surface frustrated lewis pairs for heterogeneous photocatalytic CO 2 reduction [J ] . Journal of the American Chemical Society , 2016 , 138 ( 4 ): 1206 - 1214 .

Alipour Z , Babu Borugadda V , Wang H , et al . Syngas production through dry reforming: a review on catalysts and their materials, preparation methods and reactor type [J ] . Chemical Engineering Journal , 2023 , 452 : 139416 .

郭丹 , 方雨洁 , 许一寒 , 等 . 乙烷和二氧化碳催化转化的研究进展 [J ] . 化工学报 , 2022 , 73 ( 8 ): 3406 - 3416 .

Guo D , Fang Y J , Xu Y H , et al . Research progress of the catalytic conversion of ethane and carbon dioxide [J ] . CIESC Journal , 2022 , 73 ( 8 ): 3406 - 3416 .

Fang X Z , Mao L , Xu L J , et al . Ni-Fe/La 2 O 3 bimetallic catalysts for methane dry reforming: Elucidating the role of Fe for improving coke resistance [J ] . Fuel , 2024 , 357 : 129950 .

Singha R K , Shukla A , Sandupatla A , et al . Synthesis and catalytic activity of a Pd doped Ni–MgO catalyst for dry reforming of methane [J ] . Journal of Materials Chemistry A , 2017 , 5 ( 30 ): 15688 - 15699 .

Turap Y , Wang I , Fu T T , et al . Co–Ni alloy supported on CeO 2 as a bimetallic catalyst for dry reforming of methane [J ] . International Journal of Hydrogen Energy , 2020 , 45 ( 11 ): 6538 - 6548 .

Yao Z W , Jiang J , Zhao Y , et al . Insights into the deactivation mechanism of metal carbide catalysts for dry reforming of methane via comparison of nickel-modified molybdenum and tungsten carbides [J ] . RSC Advances , 2016 , 6 ( 24 ): 19944 - 19951 .

O’Modhrain C , Pajares A , Coutino-Gonzalez E , et al . Dry reforming of methane in gliding arc plasma: bridging thermal and post-plasma catalysis [J ] . EES Catalysis , 2025 , 3 ( 5 ): 1087 - 1097 .

Mei D H , Sun M J , Liu S Y , et al . Plasma-enabled catalytic dry reforming of CH 4 into syngas, hydrocarbons and oxygenates: Insight into the active metals of γ-Al 2 O 3 supported catalysts [J ] . Journal of CO2 Utilization , 2023 , 67 : 102307 .

Zhao W , Mei X Y , Zhang Z H , et al . Electrified dry reforming of methane on Ni-La 2 O 3 –loaded activated carbon: A net CO 2 -negative reaction [J ] . Science Advances. , 2025 , 11 : eadv1585 .

Kanchanakul I , Srinophakun T R , Kuboon S , et al . Development of photothermal catalyst from biomass ash (bagasse) for hydrogen production via dry reforming of methane (DRM): an experimental study [J ] . Molecules , 2023 , 28 ( 12 ): 4578 .

Kazemi P , Moradi G . Dry reforming of methane over Ni/ZrO 2 and NiCu/ZrO 2 thin layer nanocatalysts in a microchannel reactor: The effect of coating time [J ] . Environmental Progress & Sustainable Energy , 2023 , 42 ( 2 ): e13996 .

Bosko M L , Múnera J F , Lombardo E A , et al . Dry reforming of methane in membrane reactors using Pd and Pd–Ag composite membranes on a NaA zeolite modified porous stainless steel support [J ] . Journal of Membrane Science , 2010 , 364 ( 1/2 ): 17 - 26 .

Li J N , Qin C L , Lv Z Z , et al . Techno-economic analysis of integrated carbon capture and dry reforming of methane [J ] . Energy , 2025 , 316 : 134516 .

Kim B J , Park H R , Lee Y L , et al . Customized Ni-MgO-ZrO 2 catalysts for the dry reforming of methane using coke oven gas: Optimizing the MgO content [J ] . Journal of CO2 Utilization , 2023 , 68 : 102379 .

高鹏 , 崔勖 , 钟良枢 , 等 . CO/CO 2 加氢高选择性合成化学品和液体燃料 [J ] . 化工进展 , 2019 , 38 ( 1 ): 183 - 195 .

Gao P , Cui X , Zhong L S , et al . CO/CO 2 hydrogenation to chemicals and liquid fuels with high selectivity [J ] . Chemical Industry and Engineering Progress , 2019 , 38 ( 1 ): 183 - 195 .

Wang Y , Tan L , Tan M H , et al . Rationally designing bifunctional catalysts as an efficient strategy to boost CO 2 hydrogenation producing value-added aromatics [J ] . ACS Catalysis , 2019 , 9 ( 2 ): 895 - 901 .

Du C , Gapu Chizema L , Hondo E , et al . One-step conversion of syngas to light olefins over bifunctional metal-zeolite catalyst [J ] . Chinese Journal of Chemical Engineering , 2021 , 36 : 101 - 110 .

Liu X L , Zhou W , Yang Y D , et al . Design of efficient bifunctional catalysts for direct conversion of syngas into lower olefins via methanol/dimethyl ether intermediates [J ] . Chemical Science , 2018 , 9 ( 20 ): 4708 - 4718 .

Zhang X D , Zhong L S , Zeng G F , et al . Process intensification of honeycomb fractal micro-reactor for the direct production of lower olefins from syngas [J ] . Chemical Engineering Journal , 2018 , 351 : 12 - 21 .

Marinho A L A , Panzone C , Chidraoui A M , et al . State-of-the-art direct CO 2 hydrogenation to liquid hydrocarbons: Analysis of Fischer–Tropsch and methanol-mediated routes [J ] . Journal of CO2 Utilization , 2025 , 101 : 103189 .

Yohannes A , Gates I . A century of evolution: Progress and milestones in Fischer-Tropsch synthesis [J ] . Coordination Chemistry Reviews , 2026 , 547 : 217096 .

陈康伟 , 熊文婷 , 符继乐 , 等 . 合成气费托合成制重质烃Ru-Co/SiC催化剂的制备及性能 [J ] . 化工学报 , 2021 , 72 ( 7 ): 3648 - 3657 .

Chen K W , Xiong W T , Fu J L /Y) , et al . Preparation and catalytic performance of Ru-Co/SiC catalysts for the synthesis of heavy hydrocarbons from syngas by Fischer-Tropsch reaction [J ] . CIESC Journal , 2021 , 72 ( 7 ): 3648 - 3657 .

van Ravenhorst I K , Hoffman A S , Vogt C , et al . On the cobalt carbide formation in a Co/TiO 2 Fischer–Tropsch synthesis catalyst as studied by high-pressure, long-term operando X-ray absorption and diffraction [J ] . ACS Catalysis , 2021 , 11 ( 5 ): 2956 - 2967 .

Jung J S , Kim S W , Moon D J . Fischer–Tropsch Synthesis over cobalt based catalyst supported on different mesoporous silica [J ] . Catalysis Today , 2012 , 185 ( 1 ): 168 - 174 .

Chen Y P , Wei J T , Duyar M S , et al . Carbon-based catalysts for Fischer–Tropsch synthesis [J ] . Chemical Society Reviews , 2021 , 50 ( 4 ): 2337 - 2366 .

Suo Y J , Yao Y L , Zhang Y S , et al . Recent advances in cobalt-based Fischer-Tropsch synthesis catalysts [J ] . Journal of Industrial and Engineering Chemistry , 2022 , 115 : 92 - 119 .

den Breejen J P , Radstake P B , Bezemer G L , et al . On the origin of the cobalt particle size effects in Fischer−Tropsch catalysis [J ] . Journal of the American Chemical Society , 2009 , 131 ( 20 ): 7197 - 7203 .

Luo Q X , Guo L P , Yao S Y , et al . Cobalt nanoparticles confined in carbon matrix for probing the size dependence in Fischer-Tropsch synthesis [J ] . Journal of Catalysis , 2019 , 369 : 143 - 156 .

Cheng Q P , Liu Y H , Lyu S S , et al . Manipulating metal-support interactions of metal catalysts for Fischer-Tropsch synthesis [J ] . Chinese Journal of Chemical Engineering , 2021 , 35 : 220 - 230 .

Hu C S , Qiu C W , Zhang W L , et al . Insights into the role of Pt promoter in Co/TiO 2 catalysts for CO hydrogenation [J ] . Catalysts , 2024 , 14 ( 12 ): 922 .

Iglesia E . Design, synthesis, and use of cobalt-based Fischer-Tropsch synthesis catalysts [J ] . Applied Catalysis A: General , 1997 , 161 ( 1/2 ): 59 - 78 .

Iqbal S , Davies T E , Hayward J S , et al . Fischer Tropsch Synthesis using promoted cobalt-based catalysts [J ] . Catalysis Today , 2016 , 272 : 74 - 79 .

van de Loosdrecht J , Botes F G , Ciobica I M , et al . Fischer–Tropsch synthesis: catalysts and chemistry [M ] // Comprehensive Inorganic Chemistry II . Amsterdam : Elsevier , 2013 : 525 - 557 .

Zhang J , Abbas M , Zhao W T , et al . Enhanced stability of a fused iron catalyst under realistic Fischer–Tropsch synthesis conditions: insights into the role of iron phases (χ-Fe5C2, θ-Fe3C and α-Fe) [J ] . Catalysis Science & Technology , 2022 , 12 ( 13 ): 4217 - 4227 .

Bukur D B , Todic B , Elbashir N . Role of water-gas-shift reaction in Fischer–Tropsch synthesis on iron catalysts: a review [J ] . Catalysis Today , 2016 , 275 : 66 - 75 .

Jahangiri H , Bennett J , Mahjoubi P , et al . A review of advanced catalyst development for Fischer–Tropsch synthesis of hydrocarbons from biomass derived syn-gas [J ] . Catalysis Science & Technology , 2014 , 4 ( 8 ): 2210 - 2229 .

Gao Y L , Shao L , Yang S Q , et al . Recent advances in iron-based catalysts for Fischer–Tropsch to olefins reaction [J ] . Catalysis Communications , 2023 , 181 : 106720 .

Yang Z X , Zhang Z P , Liu Y T , et al . Tuning direct CO hydrogenation reaction over Fe-Mn bimetallic catalysts toward light olefins: Effects of Mn promotion [J ] . Applied Catalysis B: Environmental , 2021 , 285 : 119815 .

Li W Z , Lin Q , Lv Y J , et al . Optimization strategy and research progress of iron-based Fischer–Tropsch synthesis catalysts: a green and low-carbon perspective [J ] . Clean Energy , 2025 , 9 ( 5 ): 39 - 54 .

Wu X C , Anthony R G . Effect of feed composition on methanol conversion to light olefins over SAPO-34 [J ] . Applied Catalysis A: General , 2001 , 218 ( 1/2 ): 241 - 250 .

Matam S K , O’Malley A J , Catlow C R A , et al . The effects of MTG catalysis on methanol mobility in ZSM-5 [J ] . Catalysis Science & Technology , 2018 , 8 ( 13 ): 3304 - 3312 .

Chu Y Y , Yi X F , Li C B , et al . Brønsted/Lewis acid sites synergistically promote the initial C–C bond formation in the MTO reaction [J ] . Chemical Science , 2018 , 9 ( 31 ): 6470 - 6479 .

Zhu Y L , Dai H W , Duan Y , et al . Excellent methanol to olefin performance of SAPO-34 crystal deriving from the mixed micropore, mesopore, and macropore architecture [J ] . Crystal Growth & Design , 2020 , 20 ( 4 ): 2623 - 2631 .

Kaarsholm M , Joensen F , Nerlov J , et al . Phosphorous modified ZSM-5: Deactivation and product distribution for MTO [J ] . Chemical Engineering Science , 2007 , 62 ( 18/19/20 ): 5527 - 5532 .

Elwalily A , Verkama E , Mantei F , et al . Sustainable aviation fuel production via the methanol pathway: a technical review [J ] . Sustainable Energy & Fuels , 2025 , 9 ( 19 ): 5151 - 5180 .

Richter S , Braun-Unkhoff M , Hasselwander S , et al . Evaluation of the applicability of synthetic fuels and their life cycle analyses [J ] . Energies , 2024 , 17 ( 5 ): 981 .

Yılbaşı Z . Biofuels, E-fuels, and waste-derived fuels: advances, challenges, and future directions [J ] . Sustainability , 2025 , 17 ( 13 ): 6145 .

Chen Z H , Song W L , Hou Y L , et al . Temperature-dependent secondary conversion of primary products from methanol aromatization in a two-stage fluidized bed [J ] . Fuel , 2020 , 267 : 117204 .

Wang H , Dong X L , Lin J Z , et al . Topologically guided tuning of Zr-MOF pore structures for highly selective separation of C6 alkane isomers [J ] . Nature Communications , 2018 , 9 : 1745 .

Semelsberger T A , Borup R L , Greene H L . Dimethyl ether (DME) as an alternative fuel [J ] . Journal of Power Sources , 2006 , 156 ( 2 ): 497 - 511 .

Feiling A , Münz M , Beidl C . Potential of the synthetic fuel OME1b for the soot-free diesel engine [J ] . ATZextra Worldwide , 2016 , 21 ( 11 ): 16 - 21 .

Haltenort P , Hackbarth K , Oestreich D , et al . Heterogeneously catalyzed synthesis of oxymethylene dimethyl ethers (OME) from dimethyl ether and trioxane [J ] . Catalysis Communications , 2018 , 109 : 80 - 84 .

Mazari F . A study on emission reduction and combustion efficiency, analyzing oxymethylene ether (OME1-5) with diesel fuel [J ] . Fuel , 2024 , 375 : 132578 .

Shapril N N , Abdul Wahab Y , Suppiah D D , et al . Catalytic CO 2 hydrogenation to sustainable aviation fuel: mechanisms and pathways to net-zero [J ] . Sustainable Energy & Fuels , 2025 , 9 ( 24 ): 6631 - 6641 .

沈辰阳 , 孙楷航 , 张月萍 , 等 . 二氧化碳加氢合成甲醇氧化铟及其负载金属催化剂研究进展 [J ] . 化工学报 , 2023 , 74 ( 1 ): 145 - 156 .

Shen C Y , Sun K H , Zhang Y P , et al . Research progresses on In 2 O 3 and In 2 O 3 supported metal catalysts for CO 2 hydrogenation to methanol [J ] . CIESC Journal , 2023 , 74 ( 1 ): 145 - 156 .

曹晨熙 , 陈天元 , 丁晓旭 , 等 . 负载型铟基催化剂二氧化碳加氢动力学研究 [J ] . 化工学报 , 2019 , 70 ( 10 ): 3985 - 3993 .

Cao C X , Chen T Y , Ding X X , et al . Kinetics study on supported indium-based catalysts in carbon dioxide hydrogenation [J ] . CIESC Journal , 2019 , 70 ( 10 ): 3985 - 3993 .

Shi Z B , Yang H Y , Gao P , et al . Effect of alkali metals on the performance of CoCu/TiO 2 catalysts for CO 2 hydrogenation to long-chain hydrocarbons [J ] . Chinese Journal of Catalysis , 2018 , 39 ( 8 ): 1294 - 1302 .

Wei J , Ge Q J , Yao R W , et al . Directly converting CO 2 into a gasoline fuel [J ] . Nature Communications , 2017 , 8 : 15174 .

Amoyal M , Vidruk-Nehemya R , Landau M V , et al . Effect of potassium on the active phases of Fe catalysts for carbon dioxide conversion to liquid fuels through hydrogenation [J ] . Journal of Catalysis , 2017 , 348 : 29 - 39 .

Gao X Y , Liang J L , Wu L Q , et al . Dielectric barrier discharge plasma-assisted catalytic CO 2 hydrogenation: synergy of catalyst and plasma [J ] . Catalysts , 2022 , 12 ( 1 ): 66 .

Xin H , Lin L , Li R T , et al . Overturning CO 2 hydrogenation selectivity with high activity via reaction-induced strong metal–support interactions [J ] . Journal of the American Chemical Society , 2022 , 144 ( 11 ): 4874 - 4882 .

Noreen A , Li M Q , Fu Y J , et al . One-pass hydrogenation of CO 2 to multibranched isoparaffins over bifunctional zeolite-based catalysts [J ] . ACS Catalysis , 2020 , 10 ( 23 ): 14186 - 14194 .

Zhang C D , Hu K H , Chen X X , et al . Direct hydrogenation of CO 2 into valuable aromatics over K/Fe-Cu-Al @HZSM-5 tandem catalysts: Effects of zeolite surface acidity on aromatics formation [J ] . Fuel Processing Technology , 2023 , 248 : 107824 .

Wang D , Xie Z H , Porosoff M D , et al . Recent advances in carbon dioxide hydrogenation to produce olefins and aromatics [J ] . Chem , 2021 , 7 ( 9 ): 2277 - 2311 .

Ni Y M , Chen Z Y , Fu Y , et al . Selective conversion of CO2 and H2 into aromatics [J ] . Nature Communications , 2018 , 9 : 3457 .

Ramirez A , Gong X , Caglayan M , et al . Selectivity descriptors for the direct hydrogenation of CO 2 to hydrocarbons during zeolite-mediated bifunctional catalysis [J ] . Nature Communications , 2021 , 12 : 5914 .

Yue Y H , Tian J , Ma J C , et al . Regulation of acidity properties of ZSM-5 and proximity between metal oxide and zeolite on bifunctional catalysts for enhanced CO 2 hydrogenation to aromatics [J ] . Applied Catalysis B: Environment and Energy , 2024 , 355 : 124158 .

Wang M R , Zhang G H , Wang H , et al . Understanding and tuning the effects of H 2 O on catalytic CO and CO 2 hydrogenation [J ] . Chemical Reviews , 2024 , 124 ( 21 ): 12006 - 12085 .

Zhou J F , Miao Y T , Ding H X , et al . Direct and stable hydrogenation of CO 2 to aromatics over a tandem catalyst Zn 0.1 Ti 0.9 O x /HZSM-5 [J ] . iScience , 2024 , 27 ( 7 ): 110360 .

Ali B , Arslan M T , Hussain I , et al . “ Catalyst engineering strategies for the direct hydrogenation of CO 2 into aromatics: a state-of-the-art review ”[J ] . International Journal of Hydrogen Energy , 2025 , 141 : 615 - 649 .

Panzeri M , Visconti C G , Groppi G , et al . Process Intensification of the Fischer-Tropsch synthesis using conductive packed POCS with skin: the role of the POCS design parameters [J ] . Chemical Engineering Journal , 2025 , 521 : 166359 .

Zhang H , Shuai Y , Lougou B G , et al . Effects of multilayer porous ceramics on thermochemical energy conversion and storage efficiency in solar dry reforming of methane reactor [J ] . Applied Energy , 2020 , 265 : 114799 .

Xu W K , Hu Q , Dong Y C , et al . Photothermal and electrothermal-driven thermochemical conversion of biomass: a critical review [J ] . Carbon Capture Science & Technology , 2025 , 17 : 100527 .

Kiss B P , Dobo Z , Kaptay G . Green reverse water gas shift reaction achieved by microwave-induced plasma [J ] . Green Chemistry Letters and Reviews , 2025 , 18 ( 1 ): 2583584 .

Cao H L , Xu R , Tang X J , et al . Microchannel reactors for Fischer-Tropsch synthesis: Experimental investigation and mathematical modeling [J ] . Chinese Journal of Chemical Engineering , 2023 , 64 : 224 - 240 .

Rohde M P , Unruh D , Schaub G . Membrane application in Fischer–Tropsch synthesis reactors: Overview of concepts [J ] . Catalysis Today , 2005 , 106 ( 1/2/3/4 ): 143 - 148 .

Cheng K , Zhou W , Kang J C , et al . Bifunctional catalysts for one-step conversion of syngas into aromatics with excellent selectivity and stability [J ] . Chem , 2017 , 3 ( 2 ): 334 - 347 .

Maghsoudy S , Mansouri Borujeni M , Nouri F , et al . A design kinetic and hydrodynamic study of a coupled dual fluidized bed MTO reactor-regenerator system [J ] . Fuel , 2024 , 377 : 132753 .

de Klerk A . Fischer–Tropsch fuels refinery design [J ] . Energy & Environmental Science , 2011 , 4 ( 4 ): 1177 - 1205 .

Shao S S , Liu L , Li X H . Production of solid fuel in the vacuum distillation of bio-oil [J ] . Fuel Processing Technology , 2023 , 242 : 107618 .

Perez-Carbajo J , Gómez-Álvarez P , Bueno-Perez R , et al . Optimisation of the Fischer–Tropsch process using zeolites for tail gas separation [J ] . Physical Chemistry Chemical Physics , 2014 , 16 ( 12 ): 5678 - 5688 .

Biales J M , Wan Y D , Kilpatrick P K , et al . Separation of Fischer–Tropsch wax from catalyst using near-critical fluid extraction: analysis of process feasibility [J ] . Energy & Fuels , 1999 , 13 ( 3 ): 667 - 677 .

Liu Z C , Li H , Liu S L , et al . Thermodynamics fundamentals and energy efficiency for the separation and high-valued utilization of Fischer–Tropsch heavy oil [J ] . International Journal of Coal Science & Technology , 2022 , 9 ( 1 ): 57 .

Sun C H , Luo Z H , Choudhary A , et al . Influence of the condensable hydrocarbons on an integrated Fischer–Tropsch synthesis and hydrocracking process: simulation and experimental validation [J ] . Industrial & Engineering Chemistry Research , 2017 , 56 ( 45 ): 13075 - 13085 .

Gambaro C , Calemma V , Molinari D , et al . Hydrocracking of Fischer-Tropsch waxes: Kinetic modeling via LHHW approach [J ] . AIChE Journal , 2011 , 57 ( 3 ): 711 - 723 .

王燕 , 葛喜慧 , 张敏卿 , 等 . 费托合成高温油相产品中正构烃的分离 [J ] . 化工进展 , 2014 , 33 ( 11 ): 2894 - 2898 .

Wang Y , Ge X H , Zhang M Q , et al . Separation of n-hydrocarbons from high temperature oil phase products of Fischer-Tropsch synthesis [J ] . Chemical Industry and Engineering Progress , 2014 , 33 ( 11 ): 2894 - 2898 .

Boilley J H , Berrady A , Bin Shahrel H , et al . Energy analysis of a power-to-jet-fuel plant [J ] . International Journal of Hydrogen Energy , 2024 , 58 : 1160 - 1176 .

Liu X P , Hao C L , Li J , et al . An anionic metal–organic framework: metathesis of zinc(ii) with copper(ii) for efficient C 3 /C 2 hydrocarbon and organic dye separation [J ] . Inorganic Chemistry Frontiers , 2018 , 5 ( 11 ): 2898 - 2905 .

Tian P , Wei Y X , Ye M , et al . Methanol to olefins (MTO): from fundamentals to commercialization [J ] . ACS Catalysis , 2015 , 5 ( 3 ): 1922 - 1938 .

Li N , Zhao L W , Li D , et al . A simultaneous design and optimization framework for the reaction and distillation sections of methanol to olefins process [J ] . Processes , 2023 , 11 ( 1 ): 58 .

Remy T , Cousin Saint Remi J , Singh R , et al . Adsorption and separation of C1–C8 alcohols on SAPO-34 [J ] . The Journal of Physical Chemistry C , 2011 , 115 ( 16 ): 8117 - 8125 .

Tang B B , Yu X Y , Liu Y L . Metal–organic frameworks for purification of methanol-to-olefin (MTO) products [J ] . Dalton Transactions , 2025 , 54 ( 29 ): 11141 - 11149 .

张轩 , 樊昕晔 , 吴振宇 , 等 . 氢能供应链成本分析及建议 [J ] . 化工进展 , 2022 , 41 ( 5 ): 2364 - 2371 .

Zhang X , Fan X Y , Wu Z Y , et al . Hydrogen energy supply chain cost analysis and suggestions [J ] . Chemical Industry and Engineering Progress , 2022 , 41 ( 5 ): 2364 - 2371 .

International Energy Agency . Global Hydrogen Review [R ] . Paris : International Energy Agency , 2023 .

Hubert M , Peterson D , Miller E , et al . DOE Hydrogen Program Record 24005: Clean Hydrogen Production Cost Scenarios with PEM Electrolyzer Technology [R ] . the United States : Department of Energy , 2022 .

Zang G Y , Sun P P , Elgowainy A A , et al . Performance and cost analysis of liquid fuel production from H 2 and CO 2 based on the Fischer-Tropsch process [J ] . Journal of CO2 Utilization , 2021 , 46 : 101459 .

Pratschner S , Hammerschmid M , Müller S , et al . Evaluation of CO 2 sources for Power-to-Liquid plants producing Fischer-Tropsch products [J ] . Journal of CO 2 Utilization , 2023 , 72 : 102508 .

Seymour K , Held M , Stolz B , et al . Future costs of power-to-liquid sustainable aviation fuels produced from hybrid solar PV-wind plants in Europe [J ] . Sustainable Energy & Fuels , 2024 , 8 ( 4 ): 811 - 825 .

Wentrup J , Pesch G R , Thöming J . Dynamic operation of Fischer-Tropsch reactors for power-to-liquid concepts: a review [J ] . Renewable and Sustainable Energy Reviews , 2022 , 162 : 112454 .

Wallnöfer-Ogris E , Grimmer I , Ranz M , et al . A review on understanding and identifying degradation mechanisms in PEM water electrolysis cells: Insights for stack application, development, and research [J ] . International Journal of Hydrogen Energy , 2024 , 65 : 381 - 397 .

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Research on crosslinking of epichlorohydrin and ionic liquids

Ammonia escape and its prevention in CO2 absorption process using ammonia solution

Development on iron-based moving bed chemical looping process

Experimental study of heat transfer enhancement by pressure waves in cross flow tube bundles

Progress of solar photo-thermo-catalysis for ammonia synthesis and decomposition under mild conditions

Related Author

Zhuoheng TU

Mingzhen SHI

Xiaomin ZHANG

Youting WU

Xingbang HU

MA Shuangchen

CHEN Gongda

WEN Jiaqi

Related Institution

School of Chemistry and Chemical Engineering, Nanjing University

School of Environment, North China Electric Power University

⁰