Optimization of Process Parameters and Mechanism Study on Hierarchical Pore Ni-Mo/Y Catalyzed Hydrocracking of Coal Tar to High-Aromatics Potential Naphtha

XING Shenkang; ZHOU Xiaodong; ZHANG Xingzu; WANG Chao; WANG Shunwu; LI Guangjun; CHEN Buning; XIANG Hui; SUN Xianfeng; ZHANG Qingjun; LIU Lang

doi:10.11949/0438-1157.20251466

您当前的位置：

首页 >

文章列表页 >

Optimization of Process Parameters and Mechanism Study on Hierarchical Pore Ni-Mo/Y Catalyzed Hydrocracking of Coal Tar to High-Aromatics Potential Naphtha

更新时间：2026-04-28

- Optimization of Process Parameters and Mechanism Study on Hierarchical Pore Ni-Mo/Y Catalyzed Hydrocracking of Coal Tar to High-Aromatics Potential Naphtha
- CIESC Journal Pages: 1-12(2026)
- 作者机构：
  
  1.新疆大学化学学院省部共建碳基能源资源化学与利用国家重点实验室，新疆乌鲁木齐 830046
  2.中石化（大连）石油化工研究院有限公司，辽宁大连 116045
  3.哈密富油煤研究院，新疆哈密 839000
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20251466
  CLC： TQ522.64
- Received：26 December 2025，
  
  Revised：2026-03-08，
  
  Online First：28 April 2026，
- 稿件说明：
移动端阅览
邢申康, 周晓东, 张兴祖, 王超, 唐亚昆, 王顺武, 李光俊, 陈步宁, 向辉, 孙显锋, 张庆军, 刘浪. 多级孔Ni-Mo/Y催化煤焦油加氢裂化制高芳潜石脑油工艺参数优化及作用机制研究[J]. 化工学报,

XING Shenkang, ZHOU Xiaodong, ZHANG Xingzu, WANG Chao, WANG Shunwu, LI Guangjun, CHEN Buning, XIANG Hui, SUN Xianfeng, ZHANG Qingjun, LIU Lang. Optimization of Process Parameters and Mechanism Study on Hierarchical Pore Ni-Mo/Y Catalyzed Hydrocracking of Coal Tar to High-Aromatics Potential Naphtha[J]. CIESC Journal,
邢申康, 周晓东, 张兴祖, 王超, 唐亚昆, 王顺武, 李光俊, 陈步宁, 向辉, 孙显锋, 张庆军, 刘浪. 多级孔Ni-Mo/Y催化煤焦油加氢裂化制高芳潜石脑油工艺参数优化及作用机制研究[J]. 化工学报, DOI： 10.11949/0438-1157.20251466

XING Shenkang, ZHOU Xiaodong, ZHANG Xingzu, WANG Chao, WANG Shunwu, LI Guangjun, CHEN Buning, XIANG Hui, SUN Xianfeng, ZHANG Qingjun, LIU Lang. Optimization of Process Parameters and Mechanism Study on Hierarchical Pore Ni-Mo/Y Catalyzed Hydrocracking of Coal Tar to High-Aromatics Potential Naphtha[J]. CIESC Journal, DOI： 10.11949/0438-1157.20251466

摘要

在能源转型背景下，利用煤焦油通过加氢裂化技术生产芳烃是实现“减油增化”的重要途径。本文采用多级孔Ni-Mo/Y催化剂，在固定床反应器中考察了温度、压力与空速对煤焦油加氢裂化产物分布及芳烃潜含量的影响，重点研究工艺参数对芳烃转化和单环烷烃保留之间的协同调控机制。结果表明，温度和空速具有关键调控作用，在366

C时、0.50 h

-1

时转化率与芳潜达最优平衡。温度过低或空速过高则多环芳烃转化不足，反之易导致单环环烷烃过度裂解；提高压力主要促进芳烃加氢并抑制裂解。在最优工艺参数（366

C， 15.0 MPa， 0.50 h

-1

）下，转化率、重石脑油产率及芳烃潜含量分别达到71.0 %、52.0 %和61.89 %。本文阐明了工艺参数在多级孔分子筛催化剂催化煤焦油制高芳潜石脑油中的作用机制，对推动煤焦油高值转化和芳烃生产多元化发展具有重要指导意义。

Abstract

Under the strategic background of low-carbon transformation of the energy structure

utilizing the rich aromatic hydrocarbon structure in coal tar and producing aromatics through hydrocracking technology is one of the key approaches to achieving the goal of "reducing oil and increasing chemicals". In this paper

using coal tar as the raw material and hierarchical pore Ni-Mo/Y catalyst

the effects of temperature

pressure and space velocity on the product distribution and aromatic hydrocarbon potential content of medium and low-temperature coal tar hydrocracking were investigated in a 100 mL fixed-bed reactor. We focused on the synergistic regulation of process parameters for aromatic hydrocracking and monocyclic alkane retention. Results show that reaction temperature and space velocity are key to controlling product selectivity. At 366

C and 0.50 h

-1

we achieved an optimal balance between conversion and aromatic potential. Lower temperatures or higher space velocity can prevent the full hydrogenation of polycyclic aromatic hydrocarbons. While the opposite conditions cause excessive cracking of monocyclic cycloalkanes and reduce aroma

tic potential. Additionally

higher reaction pressure mainly enhances aromatic hydrogenation and inhibits excessive cracking. Under optimal conditions (366

15.0 MPa

0.50 h

-1

)

coal tar conversion

heavy naphtha yield

and aromatic potential reached 71.0 %

52.0 %

and 61.89 %

respectively. This work clarifies the mechanism of action of process parameters in the process of multi-stage porous molecular sieve catalytic hydrocracking of coal tar to produce high-aromatic potential naphtha

which is of great guiding significance for promoting the high-value conversion of coal tar and the diversified development of aromatics production technology.

关键词

Keywords

references

中国国家能源局 . 能源行业持续聚力低碳发展 [EB/OL ] . ( 2025-05-09 )[ 2025-08-16 ] .

China National Energy Administration . Energy industry continues to focus on low-carbon development [EB/OL ] . ( 2025-05-09 )[ 2025-08-16 ] . https://www.nea.gov.cn/20250509/0a6189501ab84779b9f0b9d65d0402f0/c.html https://www.nea.gov.cn/20250509/0a6189501ab84779b9f0b9d65d0402f0/c.html .

International Energy Agency . Oil demand for fuels in China has reached a plateau - analysis [EB/OL ] . ( 2025-03-11 )[ 2025-08-09 ] . https://www.iea.org/commentaries/oil-demand-for-fuels-in-china-has-reached-a-plateau https://www.iea.org/commentaries/oil-demand-for-fuels-in-china-has-reached-a-plateau .

罗靖 . 中国应在炼厂"减油增化"转型中走在前列 [EB/OL ] . ( 2025-08-06 )[ 2025-11-04 ] .

Luo Jing . China should take the lead in refining industry's transition from oil to chemicals [EB/OL ] . ( 2025-08-06 )[ 2025-11-04 ] . http://www.sinopecnews.com.cn/xnews/content/2025-08/06/content_7130624.html http://www.sinopecnews.com.cn/xnews/content/2025-08/06/content_7130624.html .

Leckel D . Hydrodeoxygenation of heavy oils derived from low-temperature coal gasification over NiW catalysts: effect of pore structure [J ] . Energy & Fuels , 2008 , 22 ( 1 ): 231 - 236 .

Niu M L , Zheng H A , Sun X H , et al . Kinetic model for low-temperature coal tar hydrorefining [J ] . Energy & Fuels , 2017 , 31 ( 5 ): 5441 - 5447 .

He L , Zhang S L , Yao Q X , et al . A review of catalytic conversion of coal tar value-added chemicals at the molecular level based on first principles [J ] . Energy Conversion and Management , 2025 , 326 : 119466 .[LinkOut ]

Weitkamp J . Catalytic hydrocracking: mechanisms and versatility of the process [J ] . ChemCatChem , 2012 , 4 ( 3 ): 292 - 306 .

Kong X Y , Li Y Y , Liu Z T , et al . Pore-structure engineering of hierarchical Ni/Y catalysts for the enhanced selective hydrocracking of naphthalene to BTX [J ] . ACS Sustainable Chemistry & Engineering , 2025 , 13 ( 23 ): 8817 - 8828 .

Dong Q , Zhang C H , Zhang H F , et al . Design and preparation of Pt@SSZ-13@β core-shell catalyst for hydrocracking of naphthalene [J ] . Journal of Catalysis , 2023 , 421 : 365 - 375 .

Lee S U , Lee Y J , Kim J R , et al . Selective ring opening of phenanthrene over NiW-supported mesoporous HY zeolite catalyst depending on their mesoporosity [J ] . Materials Research Bulletin , 2017 , 96 : 149 - 154 .

Kim Y S , Cho K S , Lee Y K . Morphology effect of β-zeolite supports for Ni 2 P catalysts on the hydrocracking of polycyclic aromatic hydrocarbons to benzene, toluene, and xylene [J ] . Journal of Catalysis , 2017 , 351 : 67 - 78 .

Zhao W R , Yu H , Peng S Z , et al . Mechanistic understanding of anthracene hydrocracking over HY zeolite encapsulated single-atom Pt catalysts [J ] . ACS Catalysis , 2024 , 14 ( 11 ): 8836 - 8855 .

Fujikawa T , Idei K , Ebihara T , et al . Aromatic hydrogenation of distillates over SiO 2 -Al 2 O 3 -supported noble metal catalysts [J ] . Applied Catalysis A: General , 2000 , 192 ( 2 ): 253 - 261 .

Abdulridha S , Jiao Y L , Xu S J , et al . A comparative study on mesoporous Y zeolites prepared by hard-templating and post-synthetic treatment methods [J ] . Applied Catalysis A: General , 2021 , 612 : 117986 .

Wang X H , Yu Z Q , Sun J X , et al . Synthesis of small crystal size Y zeolite catalysts with high hydrocracking performance on n -hexadecane [J ] . Energy & Fuels , 2022 , 36 ( 22 ): 13817 - 13832 .

Anis S F , Singaravel G , Hashaikeh R . Hierarchical nano zeolite-Y hydrocracking composite fibers with highly efficient hydrocracking capability [J ] . RSC Advances , 2018 , 8 ( 30 ): 16703 - 16715 .

冯新娟 , 闵小建 , 郑化安 , 等 . 中低温煤焦油重油正庚烷萃余物的反应(甲醛)分离与分析 [J ] . 燃料化学学报 , 2018 , 46 ( 1 ): 15 - 26 .

Feng X J , Min X J , Zheng H A , et al . Reaction (formaldehyde) separation and analysis of n-heptane extraction residue from heavy oil of medium and low temperature coal tar [J ] . Journal of Fuel Chemistry and Technology , 2018 , 46 ( 1 ): 15 - 26 .

Zhang M N , Qin B , Zhang W M , et al . Hydrocracking of light diesel oil over catalysts with industrially modified Y zeolites [J ] . Catalysts , 2020 , 10 ( 8 ): 815 .

Kumar Parsapur R , Hengne A M , Melinte G , et al . Post‐synthetic ensembling design of hierarchically ordered FAU‐type zeolite frameworks for vacuum gas oil hydrocracking [J ] . Angewandte Chemie International Edition , 2024 , 63 ( 6 ): e202314217 .

Palos R , Crespo I , Trueba D , et al . Hydrocracking of plastic pyrolysis oil (PPO) blended with vacuum gas oil (VGO) over Pt–Pd catalysts supported on USY-ASA-Al 2 O 3 composites [J ] . Energy & Fuels , 2024 , 38 ( 18 ): 17866 - 17877 .

Ho T C , Katritzky A R , Cato S J . Effect of nitrogen compounds on cracking catalysts [J ] . Industrial & Engineering Chemistry Research , 1992 , 31 ( 7 ): 1589 - 1597 .

Xiao X , Chen Z M , Chen B L . H/C atomic ratio as a smart linkage between pyrolytic temperatures, aromatic clusters and sorption properties of biochars derived from diverse precursory materials [J ] . Scientific Reports , 2016 , 6 : 22644 .

Martens G G , Marin G B , Martens J A , et al . A fundamental kinetic model for hydrocracking of C 8 to C 12 alkanes on Pt/US-Y zeolites [J ] . Journal of Catalysis , 2000 , 195 ( 2 ): 253 - 267 .

Calemma V , Ferrari M , Rabl S , et al . Selective ring opening of naphthenes: From mechanistic studies with a model feed to the upgrading of a hydrotreated light cycle oil [J ] . Fuel , 2013 , 111 : 763 - 770 .

Jampaiah D , Murzin D Y , Lee A F , et al . Catalytic selective ring opening of polyaromatics for cleaner transportation fuels [J ] . Energy & Environmental Science , 2022 , 15 ( 5 ): 1760 - 1804 .

Montalvo-Castro H , DeLuca M , Kilburn L , et al . Mechanisms and kinetics of the dehydrogenation of C 6 –C 8 cycloalkanes, cycloalkenes, and cyclodienes to aromatics in H-MFI zeolite framework [J ] . ACS Catalysis , 2023 , 13 ( 1 ): 99 - 112 .

Vela F J , Palos R , Bilbao J , et al . Hydrogen pressure as a key parameter to control the quality of the naphtha produced in the hydrocracking of an HDPE/VGO blend [J ] . Catalysts , 2022 , 12 ( 5 ): 543 .

Jing Z K , Guo Y K , Wang Q , et al . Ambient hydrogenation of solid aromatics enabled by a high entropy alloy nanocatalyst [J ] . Nature Communications , 2024 , 15 : 5806 .

Vasina T V , Masloboishchikova O V , Khelkovskaya-Sergeeva E G , et al . Cyclohexane transformations over metal oxide catalysts. 2. Selective cyclohexane ring opening to form n-hexane over mono- and bimetallic rhodium catalysts [J ] . Russian Chemical Bulletin , 2002 , 51 ( 2 ): 255 - 258 .

Botchwey C , Dalai A K , Adjaye J . Product selectivity during hydrotreating and mild hydrocracking of bitumen-derived gas oil [J ] . Energy & Fuels , 2003 , 17 ( 5 ): 1372 - 1381 .

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Study on continuous alcoholysis of fructose to methyl lactate over TS-1 and In-TS-1

Design of cobalt-nitrogen-carbon/activated carbon rich in zero valent cobalt active site and application of catalytic oxidation of formaldehyde

Study on binder of extruded mordenite catalyst for dimethyl ether carbonylation

Recent advances in high value added reuse of waste polystyrene in environment and energy

Simultaneous removal of NO and soot over La1-xLixMnO3 perovskite catalysts

Related Author

LI Bolong

JIANG Yuxi

REN Aotian

QIN Wenqi

FU Jie

LYU Xiuyang

LI Kaixuan

TAN Wei

Related Institution

Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University

Institute of Zhejiang University-Quzhou

School of Chemical Engineering and Light Industry, Guangdong University of Technology

School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology

Institute of Green Petroleum Processing and Light Hydrocarbon Conversion, College of Chemical Engineering, Zhejiang University of Technology

⁰