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华中科技大学煤燃烧国家重点实验室,湖北 武汉 430074
Received:08 December 2025,
Revised:2026-03-31,
Online First:01 April 2026,
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蔡宛臻, 肖涵, 张琳, 刘欢, 姚洪. 基于碳基骨架热水解污泥的储运焚烧特性研究[J]. 化工学报,
CAI Wanzhen, XIAO Han, ZHANG Lin, LIU Huan, YAO Hong. Storage, transportation and incineration characteristics of carbon-based skeleton-assisted thermally hydrolyzed sludge[J]. CIESC Journal,
蔡宛臻, 肖涵, 张琳, 刘欢, 姚洪. 基于碳基骨架热水解污泥的储运焚烧特性研究[J]. 化工学报, DOI: 10.11949/0438-1157.20251377-基于碳基骨架热水解污泥的储运焚烧特性研究-修改稿
CAI Wanzhen, XIAO Han, ZHANG Lin, LIU Huan, YAO Hong. Storage, transportation and incineration characteristics of carbon-based skeleton-assisted thermally hydrolyzed sludge[J]. CIESC Journal, DOI: 10.11949/0438-1157.20251377-基于碳基骨架热水解污泥的储运焚烧特性研究-修改稿
针对污泥衍生燃料储运以及燃烧安全性问题,本研究基于前期研发的碳基骨架辅助污泥热水解提质方法,重点考察了碳基骨架辅助热水解对污泥储运特性与焚烧特性的影响。在储运特性方面,尽管在同质量造粒条件下碳基骨架污泥的复吸水率会升高,但在同体积造粒条件下,其复吸水率可降低近30%;添加木质纤维素废弃物骨架可使吸氧量降低30%-70%,自燃倾向略有下降。在焚烧特性方面,不同类型碳基骨架对燃料性能的影响存在差异,其中废木屑类骨架表现最优,可使污泥热值提高25%,并将可燃性指数和稳燃性指数分别提高约8%和42%,有效改善了燃烧性能;该骨架材料还可将灰熔融温度中的软化温度(ST)提升约100 ℃,结渣倾向略有降低。加工副产品类骨架在多数燃烧指标上表现中等,虽能一定程度改善燃烧性能,但在改善结渣风险上的效果不如废木屑类骨架显著;而废秸秆类骨架由于引入过量的硅和钙,可能会带来结渣风险,应用中需严格把控其添加比例。本研究为污泥衍生燃料储运与焚烧特性的改善提供了理论支撑。
To address the challenges associated with the storage
transportation
and combustion safety of sludge-derived fuel
this study investigated the effects of carbon-based skeleton-assisted thermal hydrolysis on the storage/transportation and incineration characteristics of sludge
based on a previously developed method. Regarding storage/transportation characteristics
although the water re-absorption rate of carbon-based skeleton sludge increased under equal-mass pelletizing conditions
it decreased by nearly 30% under equal-volume pelletizing conditions. The addition of lignocellulosic waste skeletons reduced oxygen absorption by 30-70%
indicating a slightly lower spontaneous ignition tendency. In terms of incineration characteristics
the influence of different carbon-based skeletons on fuel properties varied. Waste wood-based skeletons performed optimally
increasing the sludge calorific value by 25%
and enhancing the combustibility index and combustion stability index by approximately 8% and 42%
respectively
thereby effectively improving combustion performance. This skeleton material also raised the softening temperature (ST) in ash fusion temperatures by about 100 °C and slightly reduced slagging tendency. Processing by-product skeletons showed moderate performance in most combustion indicators
improving combustion performance to some extent but being less effective than waste wood skeletons in mitigating slagging risk. Conversely
waste straw skeletons
due to introducing excessive SiO₂
exacerbated ash fusion and slagging risks
necessitating strict control of their addition ratio in application. This study provides theoretical support for improving the storage
transportation
and incineration characteristics of sludge-derived fuel.
中华人民共和国住房和城乡建设部 . 中国城乡建设统计年鉴-2024 [M ] . 北京 : 中国城市出版社 , 2025 .
Ministry of Housing and Urban-Rural Development of the People's Republic of China . China urban-rural construction statistical yearbook [M ] . Beijing : China City Press , 2025 .
陈虎 , 李庆召 . 市政污泥资源化途径现状研究 [J ] . 环境科学与管理 , 2025 , 50 ( 3 ): 178 - 183 .
Chen H , Li Q Z . Analysis on current situation of municipal sludge resource utilization [J ] . Environmental Science and Management , 2025 , 50 ( 3 ): 178 - 183 .
郑琪豫 . 城市污水处理厂的污泥处理及处置技术研究 [J ] . 皮革制作与环保科技 , 2025 , 6 ( 14 ): 141 - 143 .
Zheng Q Y . Research on sludge treatment and disposal technologies in urban wastewater treatment plants [J ] . Leather Manufacture and Environmental Technology , 2025 , 6 ( 14 ): 141 - 143 .
汪家兴 . 碳基骨架辅助热水解对污泥脱水性能及基础燃料特性的影响研究 [D ] . 武汉 : 华中科技大学 , 2021 .
Wang J X . Effect of carbon-based skeleton-assisted thermal hydrolysis on sludge dewatering performance and basic fuel characteristics [D ] . Wuhan : Huazhong University of Science and Technology , 2021 .
张锦萍 . 提质褐煤复吸水及燃烧特性的实验研究 [D ] . 武汉 : 华中科技大学 , 2015 .
Zhang J P . Experimental study on reabsorbing water and combustion characteristics of upgraded lignite [D ] . Wuhan : Huazhong University of Science and Technology , 2015 .
李云妹 , 尚曼霞 , 郑欣昱 , 等 . 污泥掺烧对于褐煤灰熔融特性的影响研究 [J ] . 煤炭技术 , 2024 , 43 ( 10 ): 278 - 281 .
Li Y M , Shang M X , Zheng X Y , et al . Study on influence of sludge mixed combustion on melting characteristics of lignite ash [J ] . Coal Technology , 2024 , 43 ( 10 ): 278 - 281 .
Xiao H , Liu H , Jin M H , et al . Process control for improving dewatering performance of sewage sludge based on carbonaceous skeleton-assisted thermal hydrolysis [J ] . Chemospheree , 2022 , 296 : 134006 .
张盛 . 多种固体废物协同热处置过程中交互反应机理及污染物排放规律研究 [D ] . 杭州 : 浙江大学 , 2022 .
Zhang S . Research on interaction mechanism and pollutants emission characteristics during co-thermal treatment of various solid wastes [D ] . Hangzhou : Zhejiang University , 2022 .
王利平 . 水热处理耦合机械压滤对剩余污泥的深度脱水性能研究 [D ] . 大连 : 大连理工大学 , 2015 .
Wang L P . Hydrothermal treatment coupled with mechanical expression for excess sludge deep dewatering [D ] . Dalian : Dalian University of Technology , 2015 .
国家质量监督检验检疫总局 , 中国国家标准化管理委员会 . 煤灰熔融性的测定方法 : GB/T 219—2008 [S ] . 北京 : 中国标准出版社 , 2009 .
General Administration of Quality Supervision , Inspection and Quarantine of the People's Republic of China , Standardization Administration of the People's Republic of China . Determination of fusibility of coal ash : GB/T 219—2008 [S ] . Beijing : Standards Press of China , 2009 .
赵旭升 . 入炉煤粒径对循环流化床锅炉的影响分析 [J ] . 山西化工 , 2024 , 44 ( 2 ): 127 - 128 .
Zhao X S . Analysis of the influence of coal particle size on circulating fluidized bed boilers [J ] . Shanxi Chemical Industry , 2024 , 44 ( 2 ): 127 - 128 .
李杰 , 王小勇 , 马伟 . 不同粒径炉煤对气流式内热炉温度场的影响研究 [J ] . 工业加热 , 2025 , 54 ( 5 ): 62 - 67 .
Li J , Wang X Y , Ma W . Research on the influence of different particle sizes of furnace coal on the temperature field of airflow internal heating furnace [J ] . Industrial Heating , 2025 , 54 ( 5 ): 62 - 67 .
马亚飞 . 基于低场~1H-NMR技术的不同煤种水分复吸形态研究 [D ] . 武汉 : 华中科技大学 , 2018 .
Ma Y F . Study on moisture reabsorption forms of different coals based on low field ~1H-NMR technology [D ] . Wuhan : Huazhong University of Science and Technology , 2018 .
许龙泉 . CFB锅炉改烧褐煤的适应性研究 [D ] . 长沙 : 长沙理工大学 , 2018 .
Xu L Q . Study on adaptability of CFB boiler to lignite-burning [D ] . Changsha : Changsha University of Science & Technology , 2018 .
Hu H , Liu H , Xiao H , et al . Assisting role of carbonaceous skeleton in sludge thermal hydrolysis and press filtration [J ] . Chemosphere , 2024 , 352 : 141501 .
冯淋淋 , 王志强 , 白力 . 干化污泥造粒对垃圾焚烧厂协同焚烧的影响研究 [J ] . 四川环境 , 2020 , 39 ( 1 ): 81 - 86 .
Feng L L , Wang Z Q , Bai L . Study on the effect of dry sludge granulation on co-incineration in waste incineration plant [J ] . Sichuan Environment , 2020 , 39 ( 1 ): 81 - 86 .
Jiang L B , Liang J , Yuan X Z , et al . Co-pelletization of sewage sludge and biomass: The density and hardness of pellet [J ] . Bioresource Technology , 2014 , 166 : 435 - 443 .
李嘉薇 . 水热提质褐煤水分复吸特性及含硫、氧官能团演化研究 [D ] . 徐州 : 中国矿业大学 , 2019 .
Li J W . Study on water re-absorption and sulfur, oxygen-containing functional groups evolution of hydrothermally upgraded lignite [D ] . Xuzhou : China University of Mining and Technology , 2019 .
Wang J X , Liu H , Deng H P , et al . Deep dewatering of sewage sludge and simultaneous preparation of derived fuel via carbonaceous skeleton-aided thermal hydrolysis [J ] . Chemical Engineering Journal , 2020 , 402 : 126255 .
王婷婷 , 盛昌栋 . 城镇污水污泥低温氧化放热特性的恒温量热分析 [J ] . 环境工程 , 2021 , 39 ( 10 ): 110 - 115, 123 .
Wang T T , Sheng C D . Isothermal calorimetric analysis of exothermic characteristics of municipal sewage sludge during low temperature oxidation [J ] . Environmental Engineering , 2021 , 39 ( 10 ): 110 - 115, 123 .
Li X R , Lim W S , Iwata Y , et al . Safety evaluation of sewage-sludge-derived fuels by comparison with other fuels [J ] . Fire and Materials , 2009 , 33 ( 4 ): 187 - 200 .
许芹 . 氧化煤表面吸氧能力演化及分子活性结构二次氧化特性研究 [D ] . 徐州 : 中国矿业大学 , 2021 .
Xu Q . Oxygen adsorption capacity evolution of pre-oxidized coal and secondary oxidation characteristics of molecular active structure [D ] . Xuzhou : China University of Mining and Technology , 2021 .
Zhang Y T , Zhang J , Li Y Q , et al . Oxidation characteristics of functional groups in relation to coal spontaneous combustion [J ] . ACS Omega , 2021 , 6 ( 11 ): 7669 - 7679 .
Xu Z X , Song H , Li P J , et al . Hydrothermal carbonization of sewage sludge: Effect of aqueous phase recycling [J ] . Chemical Engineering Journal , 2020 , 387 : 123410 .
Xu X W , Jiang E C . Treatment of urban sludge by hydrothermal carbonization [J ] . Bioresource Technology , 2017 , 238 : 182 - 187 .
Wang L P , Chang Y Z , Li A M . Hydrothermal carbonization for energy-efficient processing of sewage sludge: a review [J ] . Renewable and Sustainable Energy Reviews , 2019 , 108 : 423 - 440 .
郑旭 , 刘晨 , 王昕 , 等 . 水泥窑用垃圾衍生燃料燃烧特性的TG-DTG研究 [J ] . 水泥技术 , 2017 ( 2 ): 21 - 28 .
Zheng X , Liu C , Wang X , et al . Research on the combustion characteristics of RDF for cement kiln by TG-DTG [J ] . Cement Technology , 2017 ( 2 ): 21 - 28 .
修浩然 , 王云刚 , 白彦渊 , 等 . 准东煤/市政污泥混燃燃烧特性及灰熔融行为分析 [J ] . 化工进展 , 2023 , 42 ( 6 ): 3242 - 3252 .
Xiu H R , Wang Y G , Bai Y Y , et al . Combustion characteristics and ash melting behavior of Zhundong coal/municipal sludge blended combustion [J ] . Chemical Industry and Engineering Progress , 2023 , 42 ( 6 ): 3242 - 3252 .
宋文佳 . 高温煤气化炉中煤灰熔融、流动和流变行为特性研究 [D ] . 上海 : 华东理工大学 , 2011 .
Song W J . Study on melting, flowing and rheological behavior characteristics of coal ash in high temperature coal gasifier [D ] . Shanghai : East China University of Science and Technology , 2011 .
王腾 . 污泥—稻壳混烧灰熔融特性及自固化机理研究 [D ] . 武汉 : 武汉大学 , 2017 .
Wang T . Study on melting characteristics and self-solidifying mechanism of sludge-rice husk co-combustion ash [D ] . Wuhan : Wuhan University , 2017 .
刘志 . 配煤煤灰内矿物质转变过程与熔融特性规律研究 [D ] . 杭州 : 浙江大学 , 2006 .
Liu Z . The study on minerals transition process and fusing regularity of blending coal-ashes [D ] . Hangzhou : Zhejiang University , 2006 .
薛瑞轩 . 准东煤燃烧与结渣特性研究 [D ] . 北京 : 华北电力大学 , 2015 .
Xue R X . Study on combustion and slagging characteristics of Zhundong coal [D ] . Beijing : North China Electric Power University , 2015 .
李德波 , 崔乘亮 , 蒋勇军 , 等 . 煤和市政污泥掺烧的灰熔融特性研究 [J ] . 发电技术 , 2019 , 40 ( 4 ): 347 - 354 .
Li D B , Cui C L , Jiang Y J , et al . Investigation of fusion characteristics in co-combustion of coal with municipal sludge [J ] . Power Generation Technology , 2019 , 40 ( 4 ): 347 - 354 .
王雪花 . 污泥与煤混烧成灰及结渣特性研究 [D ] . 沈阳 : 沈阳航空航天大学 , 2011 .
Wang X H . Research on the characteristics of ash and slagging from co-combustion of sewage sludge and coal [D ] . Shenyang : Shenyang Aerospace University , 2011 .
Vassilev S V , Baxter D , Andersen L K , et al . An overview of the chemical composition of biomass [J ] . Fuel , 2010 , 89 ( 5 ): 913 - 933 .
Beidaghy Dizaji H , Zeng T , Hölzig H , et al . Ash transformation mechanism during combustion of rice husk and rice straw [J ] . Fuel , 2022 , 307 : 121768 .
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