Study on inhibition of AEEA degradation in flue gas carbon capture by β-cyclodextrin inclusion complexes

XIA Ying; LU Shijian; KANG Guojun; LIU Ling; HUA Kaimin; MA Yanhui; YANG Fei; HOU Ting; YU Chang

doi:10.11949/0438-1157.20251315

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Study on inhibition of AEEA degradation in flue gas carbon capture by β-cyclodextrin inclusion complexes

更新时间：2026-02-24

- Study on inhibition of AEEA degradation in flue gas carbon capture by β-cyclodextrin inclusion complexes
- CIESC Journal Pages: 1-16(2026)
- 作者机构：
  
  1.中国矿业大学江苏省煤基温室气体减排与资源化利用重点实验室，江苏徐州 221008
  2.中国矿业大学碳中和研究院，江苏徐州 221008
  3.河南心连心化学工业集团股份有限公司，河南新乡 453700
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20251315
  CLC： TQ
- Received：25 November 2025，
  
  Revised：2026-01-07，
  
  Online First：24 February 2026，
- 稿件说明：
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夏颖, 陆诗建, 康国俊, 刘玲, 华凯敏, 马艳辉, 杨菲, 侯婷, 于畅. β-环糊精包合物抑制AEEA烟气碳捕集降解研究[J]. 化工学报,

XIA Ying, LU Shijian, KANG Guojun, LIU Ling, HUA Kaimin, MA Yanhui, YANG Fei, HOU Ting, YU Chang. Study on inhibition of AEEA degradation in flue gas carbon capture by β-cyclodextrin inclusion complexes[J]. CIESC Journal,
夏颖, 陆诗建, 康国俊, 刘玲, 华凯敏, 马艳辉, 杨菲, 侯婷, 于畅. β-环糊精包合物抑制AEEA烟气碳捕集降解研究[J]. 化工学报, DOI： 10.11949/0438-1157.20251315

XIA Ying, LU Shijian, KANG Guojun, LIU Ling, HUA Kaimin, MA Yanhui, YANG Fei, HOU Ting, YU Chang. Study on inhibition of AEEA degradation in flue gas carbon capture by β-cyclodextrin inclusion complexes[J]. CIESC Journal, DOI： 10.11949/0438-1157.20251315

摘要

化学吸收法是目前最具规模化应用的CO

捕集技术之一，但胺吸收剂在捕集过程中易降解，导致捕集成本增加。相比于传统单乙醇胺（MEA），N-（2-羟乙基）乙二胺（AEEA）具有CO

吸收量高和反应速率快等优点。然而AEEA在含氧环境下易降解的问题限制了其进一步应用。针对AEEA开展了负载CO

、高温和高O

分压条件下的降解实验研究，开发了采用β-环糊精（β-CD）作为载体包合带有活性羟基的酚类作为AEEA体系的降解抑制剂，分析添加降解抑制剂前后AEEA的性能变化，提出了“物理包合-化学协同-自由基还原”抑制氧化降解的协同方法。研究发现，随降解时间的延长，空白AEEA的CO

吸收/解吸性能和降解率呈阶梯式下降趋势。而添加0.1 vt% β-CD包合物后，CO

吸收量提高131.03%，解吸量提高58.49%。

Abstract

Chemical absorption is one of the most

scalable CO

capture technologies currently available

yet amine absorbents are prone to degradation during the capture process

leading to increased costs. Compared with conventional monoethanolamine (MEA)

N-(2-hydroxyethyl)ethylenediamine (AEEA) offers advantages such as higher CO

absorption capacity and faster reaction rate. However

its susceptibility to degradation in oxygen-containing environments limits further application. To address this

degradation experiments were conducted on AEEA under CO

loaded

high temperature

and high O

partial pressure conditions. A degradation inhibitor was developed using β-cyclodextrin (β-CD) as a carrier to encapsulate phenols containing active hydroxyl groups for the AEEA system. Performance changes of AEEA before and after adding the inhibitor were analyzed

and a synergistic approach termed "physical encapsulation–chemical synergy–free radical reduction" was proposed to suppress oxidative degradation. The results showed that with prolonged degradation time

the CO

absorption/desorption performance and degradation rate of blank AEEA declined in a stepwise manner. In contrast

after adding 0.1 vt% of the β-CD inclusion complex

the CO

absorption capacity increased by 131.03%

and the desorption capacity increased by 58.49%.

关键词

Keywords

references

Krótki A , Więcław-Solny L , Tatarczuk A , et al . A pilot study comparing MEA and AEEA solvents in carbon capture [J ] . International Journal of Greenhouse Gas Control , 2023 , 126 : 103891 .

Clery D S , Mason P E , Barnes D C , et al . The effect of biomass ashes and potassium salts on MEA degradation for BECCS [J ] . International Journal of Greenhouse Gas Control , 2021 , 108 : 103305 .

Vega F , Sanna A , Maroto-Valer M M , et al . Study of the MEA degradation in a CO 2 capture process based on partial oxy-combustion approach [J ] . International Journal of Greenhouse Gas Control , 2016 , 54 : 160 - 167 .

Liu Q , Luo T , Yin Y Y , et al . Oxidative stability of structurally varied amines for post-combustion CO 2 capture [J ] . Chemical Engineering Science , 2024 , 299 : 120458 .

Fytianos G , Ucar S , Grimstvedt A , et al . Corrosion and degradation in MEA based post-combustion CO 2 capture [J ] . International Journal of Greenhouse Gas Control , 2016 , 46 : 48 - 56 .

Zhou S , Wang S J , Sun C C , et al . SO 2 effect on degradation of MEA and some other amines [J ] . Energy Procedia , 2013 , 37 : 896 - 904 .

黄宇辉 , 方梦祥 , 王涛 , 等 . 新型MEA-AMP混合胺吸收剂的抗降解剂研究 [J ] . 能源工程 , 2021 , 41 ( 5 ): 35 - 42 .

Huang Y H , Fang M X , Wang T , et al . Inhibitor for new MEA-AMP blended amine absorbent [J ] . Energy Engineering , 2021 , 41 ( 5 ): 35 - 42 .

王洪山 , 郭琛 , 孙亚斌 . 酚类抗氧剂及结构优化 [J ] . 石油化工应用 , 2010 , 29 ( 7 ): 1 - 6 .

Wang H S , Guo C , Sun Y B . Phenolic antioxidants and their structure modification [J ] . Petrochemical Industry Application , 2010 , 29 ( 7 ): 1 - 6 .

王正平 , 杨淑华 . 新型除氧剂研究 [J ] . 应用科技 , 2001 , 28 ( 3 ): 37 - 38 .

Wang Z P , Yang S H . Research on new deoxidants [J ] . Applied Science and Technology , 2001 , 28 ( 3 ): 37 - 38 .

李乐天 , 陆诗建 , 刘含笑 , 等 . 有机胺富液解吸再生研究进展 [J ] . 化工进展 , 2025 , 44 ( 1 ): 490 - 499 .

Li L T , Lu S J , Liu H X , et al . Progress of desorption and regeneration of organic amine-enriched liquids [J ] . Chemical Industry and Engineering Progress , 2025 , 44 ( 1 ): 490 - 499 .

Tocháček J . Effect of secondary structure on physical behaviour and performance of hindered phenolic antioxidants in polypropylene [J ] . Polymer Degradation and Stability , 2004 , 86 ( 2 ): 385 - 389 .

顾光临 . 二氧化碳化学吸收剂的复配研究 [D ] . 北京 : 北京化工大学 , 2010 .

Gu G L . Research of compound chemical absorbent for carbon dioxide [D ] . Beijing : Beijing University of Chemical Technology , 2010 .

陈思铭 . 基于乙基乙醇胺的非水溶液法捕集二氧化碳 [D ] . 大连 : 大连理工大学 , 2018 .

Chen S M . Non-aqueous solution capture of carbon dioxide based on ethyl ethanolamine [D ] . Dalian : Dalian University of Technology , 2018 .

Costa H E , Cairrao E . Effect of bisphenol A on the neurological system: a review update [J ] . Archives of Toxicology , 2024 , 98 ( 1 ): 1 - 73 .

Alizadeh N , Nazari F . Thymol essential oil/β-cyclodextrin inclusion complex into chitosan nanoparticles: Improvement of thymol properties in vitro studies [J ] . Journal of Molecular Liquids , 2022 , 346 : 118250 .

Saha S , Roy A , Roy K , et al . Study to explore the mechanism to form inclusion complexes of β-cyclodextrin with vitamin molecules [J ] . Scientific Reports , 2016 , 6 : 35764 .

Shi C , Zhou A Y , Fang D L , et al . Oregano essential oil/β-cyclodextrin inclusion compound polylactic acid/polycaprolactone electrospun nanofibers for active food packaging [J ] . Chemical Engineering Journal , 2022 , 445 : 136746 .

Braithwaite M C , Kumar P , Choonara Y E , et al . A novel multi-tiered experimental approach unfolding the mechanisms behind cyclodextrin-vitamin inclusion complexes for enhanced vitamin solubility and stability [J ] . International Journal of Pharmaceutics , 2017 , 532 ( 1 ): 90 - 104 .

Dai J M , Hu W , Yang H Y , et al . Controlled release and antibacterial properties of PEO/casein nanofibers loaded with Thymol/β-cyclodextrin inclusion complexes in beef preservation [J ] . Food Chemistry , 2022 , 382 : 132369 .

Kono H , Onishi K , Nakamura T . Characterization and bisphenol A adsorption capacity of β-cyclodextrin-carboxymethylcellulose-based hydrogels [J ] . Carbohydrate Polymers , 2013 , 98 ( 1 ): 784 - 792 .

Zhang R Y , Zhang Y , Deng X L , et al . A novel dual-signal electrochemical sensor for bisphenol A determination by coupling nanoporous gold leaf and self-assembled cyclodextrin [J ] . Electrochimica Acta , 2018 , 271 : 417 - 424 .

Garnero C , Longhi M . Study of ascorbic acid interaction with hydroxypropyl-β-cyclodextrin and triethanolamine, separately and in combination [J ] . Journal of Pharmaceutical and Biomedical Analysis , 2007 , 45 ( 4 ): 536 - 545 .

Chin K Z , Chang S M . Insights into the imprinting and rebinding performance of molecularly imprinted hybrids for bisphenol A and bisphenol F [J ] . ACS Applied Materials & Interfaces , 2025 , 17 ( 19 ): 28568 - 28584 .

Yu Z L , Zikela L , Li Y Q , et al . Acerola cherry (Malpighia emarginata) concentrate: separation and purification of vitamin C components and research on immune-regulating synergy [J ] . Journal of Food Measurement and Characterization , 2024 , 18 ( 7 ): 5254 - 5264 .

Dabbagh H A , Azami F . Experimental and theoretical study of racemization, stability and tautomerism of vitamin C stereoisomers [J ] . Food Chemistry , 2014 , 164 : 355 - 362 .

孙大成 , 刘保森 , 王永磊 , 等 . 高级氧化技术降解水中双酚A研究进展 [J ] . 应用化工 , 2025 , 54 ( 4 ): 1024 - 1030 .

Sun D C , Liu B S , Wang Y L , et al . Research progress on the degradation of bisphenol A in source water by advanced oxidation technology [J ] . Applied Chemical Industry , 2025 , 54 ( 4 ): 1024 - 1030 .

Hu Y , Mo G J , Wang Y , et al . Fabrication and characterization of TPP-β-cyclodextrin/chitosan supramolecular nanoparticles for delivery dual bioactive compounds [J ] . Journal of Molecular Liquids , 2021 , 343 : 117650 .

Lu S J , Ma Y H , Kang G J , et al . Forced degradation of AEEA under full CO 2 loading, high temperature and high O 2 partial pressure conditions: Degradation reaction pathway and degradation inhibitor studies [J ] . Separation and Purification Technology , 2025 , 363 : 132010 .

Saeed I M , Lee V S , Ali Mazari S , et al . Thermal degradation of aqueous 2-aminoethylethanolamine in CO 2 capture; identification of degradation products, reaction mechanisms and computational studies [J ] . Chemistry Central Journal , 2017 , 11 ( 1 ): 10 .

Lu S , Geng C , Zhao D , et al . Degradation performance of binary composite amine reagents based on AEEA for CO 2 absorption [J ] . Journal of Chemical Engineering in Higher Education , 2017 , 31 ( 6 ): 1442 - 1451 .

Wu D W , Yin Y H , Fan Y C , et al . Hybrid behaviors of CO 2 absorption into blended DEEA-based solution for the improvement of capture performance [J ] . Journal of Chemical Technology & Biotechnology , 2024 , 99 ( 7 ): 1564 - 1575 .

Sirach R , Dave P N . Thermal and bisphenol-a adsorption properties of a zinc ferrite/β-cyclodextrin polymer nanocomposite [J ] . RSC Advances , 2023 , 13 ( 32 ): 21991 - 22006 .

Zhou Y B , Gu X C , Zhang R Z , et al . Influences of various cyclodextrins on the photodegradation of phenol and bisphenol A under UV light [J ] . Industrial & Engineering Chemistry Research , 2015 , 54 ( 1 ): 426 - 433 .

Liu M Y , Gao C P , Han R P , et al . Assessment of β-cyclodextrin-immobilizing hydrolyzed polyacrylonitrile membrane for enhanced remediation of bisphenol A and tetracyclines: Adsorption and antibacterial studies [J ] . Journal of Cleaner Production , 2023 , 387 : 135839 .

Qu J H , Dong M , Wei S Q , et al . Microwave-assisted one pot synthesis of β-cyclodextrin modified biochar for concurrent removal of Pb(II) and bisphenol A in water [J ] . Carbohydrate Polymers , 2020 , 250 : 117003 .

Chaurasiya A , Pande P P , Dey K K , et al . Synthesis and characterization of novel β-CD-Xanthate and its application in the treatment of heavy metal containing wastewater and lignin enriched paper industry wastewater [J ] . International Journal of Environmental Analytical Chemistry , 2025 , 105 ( 13 ): 3073 - 3095 .

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