Research progress of high-rate capacity layered double hydroxide supercapacitor materials

ZHAO Jie; GUO Yue; SHEN Zhen; YANG Lijun; WU Qiang; WANG Xizhang; HU Zheng

doi:10.11949/0438-1157.20201296

您当前的位置：

首页 >

文章列表页 >

Research progress of high-rate capacity layered double hydroxide supercapacitor materials

Celebration Column for School of Chemistry and Chemical Engineering\, Nanjing University | 更新时间：2026-07-24

- Research progress of high-rate capacity layered double hydroxide supercapacitor materials
- CIESC Journal Vol. 71, Issue 11, Pages: 4851-4872(2020)
- 作者机构：
  
  1.南京大学化学化工学院，介观化学教育部重点实验室，江苏南京 210023
  2.江苏省纳米技术重点实验室，江苏南京 210023
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20201296
  CLC： TQ 152
- Received：09 September 2020，
  
  Revised：2020-09-17，
  
  Online First：03 November 2020，
  
  Published：05 November 2020
- 稿件说明：
移动端阅览
赵杰, 郭月, 沈桢, 杨立军, 吴强, 王喜章, 胡征. 高倍率容量层状双金属氢氧化物超级电容材料的研究进展[J]. 化工学报, 2020, 71(11): 4851-4872

ZHAO Jie, GUO Yue, SHEN Zhen, YANG Lijun, WU Qiang, WANG Xizhang, HU Zheng. Research progress of high-rate capacity layered double hydroxide supercapacitor materials[J]. CIESC Journal, 2020, 71(11): 4851-4872
赵杰, 郭月, 沈桢, 杨立军, 吴强, 王喜章, 胡征. 高倍率容量层状双金属氢氧化物超级电容材料的研究进展[J]. 化工学报, 2020, 71(11): 4851-4872 DOI： 10.11949/0438-1157.20201296.

ZHAO Jie, GUO Yue, SHEN Zhen, YANG Lijun, WU Qiang, WANG Xizhang, HU Zheng. Research progress of high-rate capacity layered double hydroxide supercapacitor materials[J]. CIESC Journal, 2020, 71(11): 4851-4872 DOI： 10.11949/0438-1157.20201296.

摘要

层状双金属氢氧化物（LDHs）是由带正电荷的金属氢氧化物层板、层间带负电荷的阴离子和水分子组成的二维层状材料，可通过氢氧化物与羟基氧化物之间的可逆氧化还原反应存储与释放电荷，具有理论容量高、形貌与组分可调、成本低、易宏量制备等优点，成为近年来备受关注的超级电容器电极材料。超级电容材料在大电流密度下的比容量与其应用潜力密切相关，研究者们通过材料设计及电极工程，探索了多种提升LDHs倍率容量（即不同电流密度下的容量）的方法与技术，但至今LDHs的实际储能性能仍然远低于预期。简述了LDHs的结构、储能机理与面临的挑战，从增加反应活性、促进电荷传输动力学的角度归纳总结了提升LDHs倍率容量的研究进展，探讨了通过匹配电子传输和离子输运能力进一步提升LDHs倍率容量的新思路。

Abstract

Layered double hydroxides （LDHs） are two-dimensional layered materials composed of positively charged metal hydroxide laminates， negatively charged anions between the layers， and water molecules， which can store and release charge through the reversible oxidation-reduction reaction between hydroxide and oxyhydroxide. LDHs have the advantages of high theoretical capacity， adjustable morphology and composition， low cost， and easy large-scale preparation， and have become the supercapacitor electrode materials with increasing attraction in recent years. To date

the rate capacities of LDHs are far from the expectation due to the low activity associated with low intrinsic activity and small active surface area

and the slow charge transport kinetics arising from the poor intrinsic conductivity to hinder electron transfer and the narrow interlayer distance to impede ion diffusion. Various strategies have developed to increase the activity

by regulating compositions

amorphizating

nanostructuring and constructing hierarchical str

uctures

and to facilitate the charge transport kinetics

by compositing with carbon

depositing/growing on conductive substrates

expanding interlayer distance

exfoliation-self-assembly. This review starts with the structural characteristics and energy storage mechanism of LDHs

and then summarizes the strategies for improving the rate capacities of LDHs. The up-to-date progress in achieving the high-rate capacity by matching electron transfer with ion diffusion is also included

which suggests a new avenue to explore the advanced LDHs for energy storage.

关键词

Keywords

references

Miller J R , Simon P . Electrochemical capacitors for energy management [J ] . Science , 2008 , 321 ( 5889 ): 651 - 652 .

Wang Y , Song Y , Xia Y . Electrochemical capacitors: mechanism, materials, systems, characterization and applications [J ] . Chem. Soc. Rev. , 2016 , 45 ( 21 ): 5925 - 5950 .

Zhu Q , Zhao D , Cheng M , et al . A new view of supercapacitors: integrated supercapacitors [J ] . Adv. Energy Mater. , 2019 , 9 ( 36 ): 1901081 .

Gao Q , Demarconnay L , Raymundo-Piñero E , et al . Exploring the large voltage range of carbon/carbon supercapacitors in aqueous lithium sulfate electrolyte [J ] . Energy Environ. Sci. , 2012 , 5 ( 11 ): 9611 - 9617 .

Wu T H , Hsu C T , Hu C C , et al . Important parameters affecting the cell voltage of aqueous electrical double-layer capacitors [J ] . J. Power Sources , 2013 , 242 : 289 - 298 .

Xia J , Chen F , Li J , et al . Measurement of the quantum capacitance of graphene [J ] . Nat. Nanotechnol. , 2009 , 4 ( 8 ): 505 - 509 .

Xiang K , Xu Z , Qu T , et al . Two dimensional oxygen-vacancy-rich Co 3 O 4 nanosheets with excellent supercapacitor performances [J ] . Chem. Commun. , 2017 , 53 ( 92 ): 12410 - 12413 .

Ma Q , Yao Y , Yan M , et al . Effective enhancement of electrochemical energy storage of cobalt-based nanocrystals by hybridization with nitrogen-doped carbon nanocages [J ] . Sci. China Mater. , 2019 , 62 ( 10 ): 1393 - 1402 .

Lai H , Shang L , Wu Q , et al . Spinel nickel cobaltite mesostructures assembled from ultrathin nanosheets for high-performance electrochemical energy storage [J ] . ACS Appl. Energy Mater. , 2018 , 1 ( 2 ): 684 - 691 .

Lai H , Wu Q , Zhao J , et al . Mesostructured NiO/Ni composites for high-performance electrochemical energy storage [J ] . Energy Environ. Sci. , 2016 , 9 ( 6 ): 2053 - 2060 .

Song W , Wu J , Wang G , et al . Rich-mixed-valence Ni x Co 3- x P y porous nanowires interwelded junction-free 3D network architectures for ultrahigh areal energy density supercapacitors [J ] . Adv. Funct. Mater. , 2018 , 28 ( 46 ): 1804620 .

Chen L Y , Hou Y , Kang J L , et al . Toward the theoretical capacitance of RuO 2 reinforced by highly conductive nanoporous gold [J ] . Adv. Energy Mater. , 2013 , 3 ( 7 ): 851 - 856 .

Zhao M , Zhao Q , Li B , et al . Recent progress in layered double hydroxide based materials for electrochemical capacitors: design, synthesis and performance [J ] . Nanoscale , 2017 , 9 ( 40 ): 15206 - 15225 .

Zhou G , Xu L , Hu G , et al . Nanowires for electrochemical energy storage [J ] . Chem. Rev. , 2019 , 119 : 11042 - 11109 .

Shao Y , El-Kady M F , Sun J , et al . Design and mechanisms of asymmetric supercapacitors [J ] . Chem. Rev. , 2018 , 118 : 9233 - 9280 .

Yin H , Tang Z . Ultrathin two-dimensional layered metal hydroxides: an emerging platform for advanced catalysis, energy conversion and storage [J ] . Chem. Soc. Rev. , 2016 , 45 ( 18 ): 4873 - 4891 .

Gao X , Wang P , Pan Z , et al . Recent progress in two-dimensional layered double hydroxides and their derivatives for supercapacitors [J ] . ChemSusChem , 2020 , 13 ( 6 ): 1226 - 1254 .

孟格 , 刘军枫 , 孙晓明 , 等 . 水滑石纳米阵列电极在能量储存和转化中的应用 [J ] . 中国科学: 化学 , 2017 , 47 ( 4 ): 408 - 419 .

Meng G , Liu J F , Sun X M , et al . Layered double hydroxide nanoarrays toward electrochemical energy storage and conversion [J ] . Sci. Sin. Chim. , 2017 , 47 ( 4 ): 408 - 419 .

安哲 , 何静 , 段雪 . 基于层状前体制备活性位高分散催化材料 [J ] . 催化学报 , 2013 , 34 ( 1 ): 225 - 234 .

An Z , He J , Duan X . Catalysts with catalytic sites highly dispersed from layered double hydroxide as precursors [J ] . Chin. J. Catal. , 2013 , 34 ( 1 ): 225 - 234 .

闫东鹏 , 陆军 , 段雪 . 层状复合金属氢氧化物: 主客体结构研究进展 [J ] . 中国科学: 化学 , 2013 , 43 ( 1 ): 1 - 14 .

Yan D P , Lu J , Duan X . Layered double hydroxide: research progress of host-guest structure [J ] . Sci. Sin. Chim. , 2013 , 43 ( 1 ): 1 - 14 .

陈艳 , 王丽秋 , 王晨晔 , 等 . 以钢渣为原料合成层状双氢氧化物及其结构表征 [J ] . 化工学报 , 2015 , 66 ( 12 ): 5149 - 5156 .

Chen Y , Wang L Q , Wang C Y , et al . Synthesis and structural characterization of layered double hydroxide using steel slag as raw material [J ] . CIESC Journal , 2015 , 66 ( 12 ): 5149 - 5156 .

王瑞瑞 , 赵有璟 , 邵明飞 , 等 . 层状双金属氢氧化物用于催化水氧化的研究进展 [J ] . 化工学报 , 2016 , 67 ( 1 ): 54 - 72 .

Wang R R , Zhao Y J , Shao M F , et al . Recent progresses in water oxidation over layered double hydroxide catalysts [J ] . CIESC Journal , 2016 , 67 ( 1 ): 54 - 72 .

Li X , Du D , Zhang Y , et al . Layered double hydroxides toward high-performance supercapacitors [J ] . J. Mater. Chem. A , 2017 , 5 ( 30 ): 15460 - 15485 .

Yu J , Wang Q , O’Hare D , et al . Preparation of two dimensional layered double hydroxide nanosheets and their applications [J ] . Chem. Soc. Rev. , 2017 , 46 ( 19 ): 5950 - 5974 .

Wang Q , O’Hare D . Recent advances in the synthesis and application of layered double hydroxide (LDH) nanosheets [J ] . Chem. Rev. , 2012 , 112 ( 7 ): 4124 - 4155 .

Chen J , Wang X , Wang J , et al . Sulfidation of NiMn-layered double hydroxides/graphene oxide composites toward supercapacitor electrodes with enhanced performance [J ] . Adv. Energy Mater. , 2016 , 6 ( 5 ): 1501745 .

Quan W , Tang Z , Hong Y , et al . Hydroxyl compensation effects on the cycle stability of nickel-cobalt layered double hydroxides synthesized via solvothermal method [J ] . Electrochim. Acta , 2015 , 182 : 445 - 451 .

Wang X , Lin Y , Su Y , et al . Design and synthesis of ternary-component layered double hydroxides for high-performance supercapacitors: understanding the role of trivalent metal ions [J ] . Electrochim. Acta , 2017 , 225 : 263 - 271 .

Li Z , Duan H , Shao M , et al . Ordered-vacancy-induced cation intercalation into layered double hydroxides: a general approach for high-performance supercapacitors [J ] . Chem , 2018 , 4 ( 9 ): 2168 - 2179 .

Xie L , Hu Z , Lv C , et al . Co x Ni 1 -x double hydroxide nanoparticles with ultrahigh specific capacitances as supercapacitor electrode materials [J ] . Electrochim. Acta , 2012 , 78 : 205 - 211 .

Vialat P , Mousty C , Taviot-Gueho C , et al . High-performing monometallic cobalt layered double hydroxide supercapacitor with defined local structure [J ] . Adv. Funct. Mater. , 2014 , 24 ( 30 ): 4831 - 4842 .

Vialat P , Rabu P , Mousty C , et al . Insight of an easy topochemical oxidative reaction in obtaining high performance electrochemical capacitor based on Co Ⅱ Co Ⅲ monometallic cobalt layered double hydroxide [J ] . J. Power Sources , 2015 , 293 : 1 - 10 .

Chen H C , Qin Y , Cao H , et al . Synthesis of amorphous nickel-cobalt-manganese hydroxides for supercapacitor-battery hybrid energy storage system [J ] . Energy Storage Mater. , 2019 , 17 : 194 - 203 .

Li H B , Yu M H , Wang F X , et al . Amorphous nickel hydroxide nanospheres with ultrahigh capacitance and energy density as electrochemical pseudocapacitor materials [J ] . Nat. Commun. , 2013 , 4 : 1894 .

Li S , Zhang Y , Liu N , et al . Operando revealing dynamic reconstruction of NiCo carbonate hydroxide for high-rate energy storage [J ] . Joule , 2020 , 4 : 1 - 15 .

Zhao Y , Wang Q , Bian T , et al . Ni 3+ doped monolayer layered double hydroxide nanosheets as efficient electrodes for supercapacitors [J ] . Nanoscale , 2015 , 7 ( 16 ): 7168 - 7173 .

Yang J , Yu C , Hu C , et al . Surface-confined fabrication of ultrathin nickel cobalt-layered double hydroxide nanosheets for high-performance supercapacitors [J ] . Adv. Funct. Mater. , 2018 , 28 ( 44 ): 1803272 .

Gu Z , Atherton J J , Xu Z P . Hierarchical layered double hydroxide nanocomposites: structure, synthesis and applications [J ] . Chem. Commun. , 2015 , 51 ( 15 ): 3024 - 3036 .

Shao M , Ning F , Zhao Y , et al . Core-shell layered double hydroxide microspheres with tunable interior architecture for supercapacitors [J ] . Chem. Mater. , 2012 , 24 ( 6 ): 1192 - 1197 .

Yan T , Li Z , Li R , et al . Nickel-cobalt double hydroxides microspheres with hollow interior and hedgehog-like exterior structures for supercapacitors [J ] . J. Mater. Chem. , 2012 , 22 ( 44 ): 23587 - 23592 .

Yan T , Zhu H , Li R , et al . Microwave synthesis of nickel/cobalt double hydroxide ultrathin flowerclusters with three-dimensional structures for high-performance supercapacitors [J ] . Electrochim. Acta , 2013 , 111 : 71 - 79 .

Li X , Zai J , Liu Y , et al . Atomically thin layered NiFe double hydroxides assembled 3D microspheres with promoted electrochemical performances [J ] . J. Power Sources , 2016 , 325 : 675 - 681 .

Liu X , Zhou A , Pan T , et al . Ultrahigh-rate-capability of a layered double hydroxide supercapacitor based on a self-generated electrolyte reservoir [J ] . J. Mater. Chem. A , 2016 , 4 ( 21 ): 8421 - 8427 .

Yang J , Yu C , Fan X , et al . 3D architecture materials made of NiCoAl-LDH nanoplates coupled with NiCo-carbonate hydroxide nanowires grown on flexible graphite paper for asymmetric supercapacitors [J ] . Adv. Energy Mater. , 2014 , 4 ( 18 ): 1400761 .

Li Z , Shao M , Zhou L , et al . A flexible all-solid-state micro-supercapacitor based on hierarchical CuO@layered double hydroxide core–shell nanoarrays [J ] . Nano Energy , 2016 , 20 : 294 - 304 .

Yu L , Shi N , Liu Q , et al . Facile synthesis of exfoliated Co-Al LDH-carbon nanotube composites with high performance as supercapacitor electrodes [J ] . Phys. Chem. Chem. Phys. , 2014 , 16 ( 33 ): 17936 - 17942 .

Chen H , Cai F , Kang Y , et al . Facile assembly of Ni-Co hydroxide nanoflakes on carbon nanotube network with highly electrochemical capacitive performance [J ] . ACS Appl. Mater. Interfaces , 2014 , 6 ( 22 ): 19630 - 19637 .

Wang Y , Chen Z , Li H , et al . The synthesis and electrochemical performance of core-shell structured Ni-Al layered double hydroxide/carbon nanotubes composites [J ] . Electrochim. Acta , 2016 , 222 : 185 - 193 .

Zhao J , Chen J , Xu S , et al . Hierarchical NiMn layered double hydroxide/carbon nanotubes architecture with superb energy density for flexible supercapacitors [J ] . Adv. Funct. Mater. , 2014 , 24 ( 20 ): 2938 - 2946 .

Liu C G , Lee Y S , Kim Y J , et al . Electrochemical characteristics of hydrothermally deposited nickel hydroxide on multi-walled carbon nanotube for supercapacitor electrode [J ] . Synthetic Met. , 2009 , 159 : 2009 - 2012 .

Yang W , Gao Z , Wang J , et al . Solvothermal one-step synthesis of Ni-Al layered double hydroxide/carbon nanotube/reduced graphene oxide sheet ternary nanocomposite with ultrahigh capacitance for supercapacitors [J ] . ACS Appl. Mater. Interfaces , 2013 , 5 ( 12 ): 5443 - 5454 .

Zhou Q , Fan T , Li Y , et al . Hollow-structure NiCo hydroxide/carbon nanotube composite for high-performance supercapacitors [J ] . J. Power Sources , 2019 , 426 : 111 - 115 .

Yu C , Yang J , Zhao C , et al . Nanohybrids from NiCoAl-LDH coupled with carbon for pseudocapacitors: understanding the role of nano-structured carbon [J ] . Nanoscale , 2014 , 6 ( 6 ): 3097 - 3104 .

Bai C , Sun S , Xu Y , et al . Facile one-step synthesis of nanocomposite based on carbon nanotubes and Nickel-Aluminum layered double hydroxides with high cycling stability for supercapacitors [J ] . J. Colloid Interf. Sci. , 2016 , 480 : 57 - 62 .

Li M , Liu F , Zhang X B , et al . A comparative study of Ni-Mn layered double hydroxide/carbon composites with different morphologies for supercapacitors [J ] . Phys. Chem. Chem. Phys. , 2016 , 18 ( 43 ): 30068 - 30078 .

Su L , Zhang X , Yuan C , et al . Symmetric self-hybrid supercapacitor consisting of multiwall carbon nanotubes and Co-Al layered double hydroxides [J ] . J . Electrochem. Soc. , 2008 , 155 ( 2 ): A110 - A114 .

Lai F , Miao Y E , Zuo L , et al . Biomass-derived nitrogen-doped carbon nanofiber network: a facile template for decoration of ultrathin nickel-cobalt layered double hydroxide nanosheets as high-performance asymmetric supercapacitor electrode [J ] . Small , 2016 , 12 ( 24 ): 3235 - 3244 .

Xu J , Gai S , He F , et al . A sandwich-type three-dimensional layered double hydroxide nanosheet array/graphene composite: fabrication and high supercapacitor performance [J ] . J. Mater. Chem. A , 2014 , 2 ( 4 ): 1022 - 1031 .

Gao Z , Wang J , Li Z , et al . Graphene nanosheet/Ni 2+ /Al 3+ layered double-hydroxide composite as a novel electrode for a supercapacitor [J ] . Chem. Mater. , 2011 , 23 ( 15 ): 3509 - 3516 .

Zhang L , Wang J , Zhu J , et al . 3D porous layered double hydroxides grown on graphene as advanced electrochemical pseudocapacitor materials [J ] . J. Mater. Chem. A , 2013 , 1 ( 32 ): 9046 - 9053 .

Wimalasiri Y , Fan R , Zhao X S , et al . Assembly of Ni-Al layered double hydroxide and graphene electrodes for supercapacitors [J ] . Electrochim. Acta , 2014 , 134 : 127 - 135 .

Yan L , Li R , Li Z , et al . Three-dimensional activated reduced graphene oxide nanocup/nickel aluminum layered double hydroxides composite with super high electrochemical and capacitance performances [J ] . Electrochim. Acta , 2013 , 95 : 146 - 154 .

Huang P , Cao C , Sun Y , et al . One-pot synthesis of sandwich-like reduced graphene oxide@CoNiAl layered double hydroxide with excellent pseudocapacitive properties [J ] . J. Mater. Chem. A , 2015 , 3 ( 20 ): 10858 - 10863 .

Cai X , Shen X , Ma L , et al . Solvothermal synthesis of NiCo-layered double hydroxide nanosheets decorated on RGO sheets for high performance supercapacitor [J ] . Chem. Eng. J. , 2015 , 268 : 251 - 259 .

Zhong Y , Liao Y , Gao A , et al . Supercapacitive behavior of electrostatic self-assembly reduced graphene oxide/CoAl-layered double hydroxides nanocomposites [J ] . J. Alloy. Compd. , 2016 , 669 : 146 - 155 .

Fang J , Li M , Li Q , et al . Microwave-assisted synthesis of CoAl-layered double hydroxide/graphene oxide composite and its application in supercapacitors [J ] . Electrochim. Acta , 2012 , 85 : 248 - 255 .

Zhang L , Zhang X , Shen L , et al . Enhanced high-current capacitive behavior of graphene/CoAl-layered double hydroxide composites as electrode material for supercapacitors [J ] . J. Power Sources , 2012 , 199 : 395 - 401 .

Dong X , Wang L , Wang D , et al . Layer-by-layer engineered Co-Al hydroxide nanosheets/graphene multilayer films as flexible electrode for supercapacitor [J ] . Langmuir , 2012 , 28 ( 1 ): 293 - 298 .

Zhang W , Ma C , Fang J , et al . Asymmetric electrochemical capacitors with high energy and power density based on graphene/CoAl-LDH and activated carbon electrodes [J ] . RSC Adv. , 2013 , 3 ( 7 ): 2483 - 2490 .

Yan T , Li R , Li Z . Nickel-cobalt layered double hydroxide ultrathin nanoflakes decorated on graphene sheets with a 3D nanonetwork structure as supercapacitive materials [J ] . Mater. Res. Bull. , 2014 , 51 : 97 - 104 .

Wan H , Liu J , Ruan Y , et al . Hierarchical configuration of NiCo 2 S 4 nanotube@Ni-Mn layered double hydroxide arrays/three-dimensional graphene sponge as electrode materials for high-capacitance supercapacitors [J ] . ACS Appl. Mater. Interfaces , 2015 , 7 ( 29 ): 15840 - 15847 .

Li M , Cheng J P , Liu F , et al . 3D-Architectured nickel-cobalt-manganese layered double hydroxide/reduced graphene oxide composite for high-performance supercapacitor [J ] . Chem. Phys. Lett. , 2015 , 640 : 5 - 10 .

Zhang L , Hui K N , Hui K S , et al . Facile synthesis of porous CoAl-layered double hydroxide/graphene composite with enhanced capacitive performance for supercapacitors [J ] . Electrochim. Acta , 2015 , 186 : 522 - 529 .

Hatui G , Nayak G C , Udayabhanu G . One pot solvothermal synthesis of sandwich-like Mg Al layered double hydroxide anchored reduced graphene oxide: an excellent electrode material for supercapacitor [J ] . Electrochim. Acta , 2016 , 219 : 214 - 226 .

Li M , Cheng J P , Wang J , et al . The growth of nickel-manganese and cobalt-manganese layered double hydroxides on reduced graphene oxide for supercapacitor [J ] . Electrochim. Acta , 2016 , 206 : 108 - 115 .

Zheng C H , Yao T , Xu T R , et al . Growth of ultrathin Ni-Co-Al layered double hydroxide on reduced graphene oxide and superb supercapacitive performance of the resulting composite [J ] . J. Alloy. Compd. , 2016 , 678 : 93 - 101 .

严琳 , 孔惠 , 李在均 . 3D石墨烯/镍铝层状双金属氢氧化物的制备及超级电容性能 [J ] . 化学学报 , 2013 , 71 ( 5 ): 822 - 828 .

Yan L , Kong H , Li Z J . Synthesis and supercapacitor property of three-dimensional graphene/Ni-Al layered double hydroxide composite [J ] . Acta Chim. Sinica , 2013 , 71 ( 5 ): 822 - 828 .

Gao X , Lv H , Li Z , et al . Low-cost and high-performance of a vertically grown 3D Ni-Fe layered double hydroxide/graphene aerogel supercapacitor electrode material [J ] . RSC Adv. , 2016 , 6 ( 109 ): 107278 - 107285 .

Peng W , Li H , Song S . Synthesis of fluorinated graphene/CoAl-layered double hydroxide composites as electrode materials for supercapacitors [J ] . ACS Appl. Mater. Interfaces , 2017 , 9 ( 6 ): 5204 - 5212 .

Daud M , Kamal M S , Shehzad F , et al . Graphene/layered double hydroxides nanocomposites: a review of recent progress in synthesis and applications [J ] . Carbon , 2016 , 104 : 241 - 252 .

Gu T H , Gunjakar J L , Kim I Y , et al . Porous hybrid network of graphene and metal oxide nanosheets as useful matrix for improving the electrode performance of layered double hydroxides [J ] . Small , 2015 , 11 ( 32 ): 3921 - 3931 .

Wei Y , Zhang X , Wu X , et al . Carbon quantum dots/Ni-Al layered double hydroxide composite for high-performance supercapacitors [J ] . RSC Adv. , 2016 , 6 ( 45 ): 39317 - 39322 .

Xiong G , He P , Wang D , et al . Hierarchical Ni-Co hydroxide petals on mechanically robust graphene petal foam for high-energy asymmetric supercapacitors [J ] . Adv. Funct. Mater. , 2016 , 26 ( 30 ): 5460 - 5470 .

Malak-Polaczyk A , Vix-Guterl C , Frackowiak E . Carbon/layered double hydroxide (LDH) composites for supercapacitor application [J ] . Energy Fuels , 2010 , 24 ( 6 ): 3346 - 3351 .

Yang Q , Li Z , Zhang R , et al . Carbon modified transition metal oxides/hydroxides nanoarrays toward high-performance flexible all-solid-state supercapacitors [J ] . Nano Energy , 2017 , 41 : 408 - 416 .

Wei J , Wang J , Song Y , et al . Synthesis of self-assembled layered double hydroxides/carbon composites by in situ solvothermal method and their application in capacitors [J ] . J. Solid State Chem. , 2012 , 196 : 175 - 181 .

Zhang L , Ou M , Yao H , et al . Enhanced supercapacitive performance of graphite-like C 3 N 4 assembled with NiAl-layered double hydroxide [J ] . Electrochim. Acta , 2015 , 186 : 292 - 301 .

Xu J , Ma C , Cao J , et al . Facile synthesis of core-shell nanostructured hollow carbon nanospheres@nickel cobalt double hydroxide as high-performance electrode materials for supercapacitors [J ] . Dalton Trans. , 2017 , 46 ( 10 ): 3276 - 3283 .

Wang Y , Dou H , Wang J , et al . Three-dimensional porous MXene/layered double hydroxide composite for high performance supercapacitors [J ] . J. Power Sources , 2016 , 327 : 221 - 228 .

Zhang D , Cao J , Zhang X , et al . NiMn layered double hydroxide nanosheets in - situ anchored on Ti 3 C 2 MXene via chemical bonds for superior supercapacitors [J ] . ACS Appl. Energy Mater. , 2020 , 3 ( 6 ): 5949 - 5964 .

Li S , Cheng P , Luo J , et al . High-performance flexible asymmetric supercapacitor based on CoAl-LDH and rGO electrodes [J ] . Nano-Micro Lett. , 2017 , 9 ( 3 ): 31 .

Shi L , Sun P , Du L , et al . Flexible honeycomb-like NiMn layered double hydroxide/carbon cloth architecture for electrochemical energy storage [J ] . Mater. Lett. , 2016 , 175 : 275 - 278 .

Li S , Yu C , Yang J , et al . A superhydrophilic “nanoglue” for stabilizing metal hydroxides onto carbon materials for high-energy and ultralong-life asymmetric supercapacitors [J ] . Energy Environ. Sci. , 2017 , 10 ( 9 ): 1958 - 1965 .

Zhao J , Chen J , Xu S , et al . CoMn-layered double hydroxide nanowalls supported on carbon fibers for high-performance flexible energy storage devices [J ] . J. Mater. Chem. A , 2013 , 1 ( 31 ): 8836 - 8843 .

Shakir I , Shahid M , Rana U A , et al . Nickel-cobalt layered double hydroxide anchored zinc oxide nanowires grown on carbon fiber cloth for high-performance flexible pseudocapacitive energy storage devices [J ] . Electrochim. Acta , 2014 , 129 : 28 - 32 .

Nagaraju G , Raju G S R , Ko Y H , et al . Hierarchical Ni-Co layered double hydroxide nanosheets entrapped on conductive textile fibers: a cost-effective and flexible electrode for high-performance pseudocapacitors [J ] . Nanoscale , 2016 , 8 ( 2 ): 812 - 825 .

Chen H , Hu L , Chen M , et al . Nickel-cobalt layered double hydroxide nanosheets for high-performance supercapacitor electrode materials [J ] . Adv. Funct. Mater. , 2014 , 24 ( 7 ): 934 - 942 .

Liu S , Lee S C , Patil U , et al . Hierarchical MnCo-layered double hydroxides@Ni(OH) 2 core-shell heterostructures as advanced electrodes for supercapacitors [J ] . J. Mater. Chem. A , 2017 , 5 ( 3 ): 1043 - 1049 .

Gu Y , Lu Z , Chang Z , et al . NiTi layered double hydroxide thin films for advanced pseudocapacitor electrodes [J ] . J. Mater. Chem. A , 2013 , 1 ( 36 ): 10655 - 10661 .

Guo X L , Liu X Y , Hao X D , et al . Nickel-manganese layered double hydroxide nanosheets supported on nickel foam for high-performance supercapacitor electrode materials [J ] . Electrochim. Acta , 2016 , 194 : 179 - 186 .

Zheng X , Gu Z , Hu Q , et al . Ultrathin porous nickel-cobalt hydroxide nanosheets for high-performance supercapacitor electrodes [J ] . RSC Adv. , 2015 , 5 ( 22 ): 17007 - 17013 .

Han J , Dou Y , Zhao J , et al . Flexible CoAl LDH@PEDOT core/shell nanoplatelet array for high-performance energy storage [J ] . Small , 2013 , 9 ( 1 ): 98 - 106 .

Abushrenta N , Wu X , Wang J , et al . Hierarchical Co-based porous layered double hydroxide arrays derived via alkali etching for highperformance supercapacitors [J ] . Sci. Rep. , 2015 , 5 : 13082 .

Adhikari S P , Awasthi G P , Kim K S , et al . Synthesis of three-dimensional mesoporous Cu-Al layered double hydroxide/g-C 3 N 4 nanocomposites on Ni-foam for enhanced supercapacitors with excellent long-term cycling stability [J ] . Dalton Trans. , 2018 , 47 ( 13 ): 4455 - 4466 .

Wang J , Song Y , Li Z , et al . In situ Ni/Al layered double hydroxide and its electrochemical capacitance performance [J ] . Energy Fuels , 2010 , 24 ( 12 ): 6463 - 6467 .

Guo W , Yu C , Li S , et al . High-stacking-density, superior-roughness LDH bridged with vertically aligned graphene for high-performance asymmetric supercapacitors [J ] . Small , 2017 , 13 ( 37 ): 1701288 .

Gupta V , Gupta S , Miura N . Potentiostatically deposited nanostructured Co x Ni 1 -x layered double hydroxides as electrode materials for redox-supercapacitors [J ] . J. Power Sources , 2008 , 175 ( 1 ): 680 - 685 .

Ge X , Gu C D , Wang X L , et al . Ionothermal synthesis of cobalt iron layered double hydroxides (LDHs) with expanded interlayer spacing as advanced electrochemical materials [J ] . J. Mater. Chem. A , 2014 , 2 ( 40 ): 17066 - 17076 .

Xiao Y , Su D , Wang X , et al . Layered double hydroxides with larger interlayer distance for enhanced pseudocapacitance [J ] . Sci. China Mater. , 2018 , 61 ( 2 ): 263 - 272 .

Lin Y , Xie X , Wang X , et al . Understanding the enhancement of electrochemical properties of NiCo layered double hydroxides via functional pillared effect: an insight into dual charge storage mechanisms [J ] . Electrochim. Acta , 2017 , 246 : 406 - 414 .

Zhang H , Tahir M U , Yan X , et al . Ni-Al layered double hydroxide with regulated interlayer spacing as electrode for aqueous asymmetric supercapacitor [J ] . Chem. Eng. J. , 2019 , 368 : 905 - 913 .

Silva A S , Sanchis-Gual R , Carrasco J A , et al . Boosting the supercapacitive behavior of CoAl layered double hydroxides via tuning the metal composition and interlayer space [J ] . Batter. Supercaps , 2020 , 3 ( 6 ): 499 - 509 .

Wang L , Dong Z H , Wang Z G , et al . Layered α-Co(OH) 2 nanocones as electrode materials for pseudocapacitors: understanding the effect of interlayer space on electrochemical activity [J ] . Adv. Funct. Mater. , 2013 , 23 ( 21 ): 2758 - 2764 .

Wang X , Zhang J , Yang S , et al . Interlayer space regulating of NiMn layered double hydroxides for supercapacitors by controlling hydrothermal reaction time [J ] . Electrochim. Acta , 2019 , 295 : 1 - 6 .

Liu X , Ma R , Bando Y , et al . A general strategy to layered transition-metal hydroxide nanocones: tuning the composition for high electrochemical performance [J ] . Adv. Mater. , 2012 , 24 ( 16 ): 2148 - 2153 .

Liu X , Ma R , Bando Y , et al . High-yield preparation, versatile structural modification, and properties of layered cobalt hydroxide nanocones [J ] . Adv. Funct. Mater. , 2014 , 24 ( 27 ): 4292 - 4302 .

Wang X , Yan C , Sumboja A , et al . Achieving high rate performance in layered hydroxide supercapacitor electrodes [J ] . Adv. Energy Mater. , 2014 , 4 ( 6 ): 1301240 .

Ge X , Gu C , Yin Z , et al . Periodic stacking of 2D charged sheets: self-assembled superlattice of Ni-Al layered double hydroxide (LDH) and reduced graphene oxide [J ] . Nano Energy , 2016 , 20 : 185 - 193 .

Ma R , Liu X , Liang J , et al . Molecular-scale heteroassembly of redoxable hydroxide nanosheets and conductive graphene into superlattice composites for high-performance supercapacitors [J ] . Adv. Mater. , 2014 , 26 ( 24 ): 4173 - 4178 .

Zhang R , An H , Li Z , et al . Mesoporous graphene-layered double hydroxides free-standing films for enhanced flexible supercapacitors [J ] . Chem. Eng. J. , 2016 , 289 : 85 - 92 .

Wu X , Jiang L , Long C , et al . Dual support system ensuring porous Co-Al hydroxide nanosheets with ultrahigh rate performance and high energy density for supercapacitors [J ] . Adv. Funct. Mater. , 2015 , 25 ( 11 ): 1648 - 1655 .

Zhao J , Xu S , Tschulik K , et al . Molecular-scale hybridization of clay monolayers and conducting polymer for thin-film supercapacitors [J ] . Adv. Funct. Mater. , 2015 , 25 ( 18 ): 2745 - 2753 .

Lan Y , Li M , Fan W , et al . Functional molecules regulated and intercalated nickel-cobalt LDH nano-sheets on carbon fiber cloths as an advanced free-standing electrode for high-performance asymmetric supercapacitors [J ] . Electrochim. Acta , 2019 , 321 : 134708 .

Yin Q , Zhang J , Liu X , et al . Pillaring-effect induced ultrahigh-rate pseudocapacitive energy storage based on layered double hydroxide nanoplate arrays [J ] . Ind. Eng. Chem. Res. , 2019 , 58 ( 27 ): 11954 - 11963 .

Zhao J , Ge C , Zhao Z , et al . Sub-nanometer-scale fine regulation of interlayer distance in Ni-Co layered double hydroxides leading to high-rate supercapacitors [J ] . Nano Energy , 2020 , 76 : 105026 .

Simon P , Gogotsi Y . Perspectives for electrochemical capacitors and related devices [J ] . Nat. Mater. , 2020 , https://doi.org/10.1038/s41563-020-0747-z https://doi.org/10.1038/s41563-020-0747-z .

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Cu cation vacancies enhance the lithium storage performance of perovskite-type high-entropy oxides

Preparation and lithium storage performance of K+-doped spinel (Co0.2Cr0.2Fe0.2Mn0.2Ni0.2)3O4 high-entropy oxide anode materials

Construction of free binder V2O5 and Fe2O3 flexible electrode and its application in supercapacitor

Hydrolysis reaction mechanism of CNCl on the surface of composite metal CuCr2O4

Recent advances and perspectives on sulfide-based photocatalysts for hydrogen production

Related Author

XU Shibiao

WEI Zhengbing

BAO Mengfan

CHENG Yi

JIA Yanggang

LIN Na

MAO Aiqin

WANG Pengpeng

Related Institution

Advanced Ceramics Research Center, School of Materials Science and Engineering, Anhui University of Technology, Ma’anshan

Anhui Province Key Laboratory of Efficient Conversion and Solid-State Storage of Hydrogen & Electricity, Anhui University of Technology,Ma’anshan

Key Laboratory of Green Fabrication and Surface Technology of Advanced Metal Materials, Ministry of Education, School of Materials Science and Engineering, Anhui University of Technology, Ma’anshan

Schoolge of Chemistry and Chemical Engineering, Chongqing University

School of Materials Science and Engineering, Anhui University of Technology, Ma’anshan

⁰