Study on oxidation of styrene with molecular oxygen catalyzed by MoO<sub>2</sub>/Ag on polyionic liquid

WU Yuefeng; QU Yongfang; LI Dahuan; SU Miaojun; LIU Yong

doi:10.11949/0438-1157.20200810

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Study on oxidation of styrene with molecular oxygen catalyzed by MoO₂/Ag on polyionic liquid

Celebration Column for School of Chemistry and Chemical Engineering\, Nanjing University | 更新时间：2026-07-24

- Study on oxidation of styrene with molecular oxygen catalyzed by MoO₂/Ag on polyionic liquid
- CIESC Journal Vol. 71, Issue 11, Pages: 4990-4998(2020)
- 作者机构：
  
  河南大学化学化工学院，河南开封 475004
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20200810
  CLC： TQ 028.8
- Received：22 June 2020，
  
  Revised：2020-09-10，
  
  Online First：03 November 2020，
  
  Published：05 November 2020
- 稿件说明：
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吴岳峰, 曲永芳, 李大欢, 苏苗军, 刘勇. 聚离子液体载MoO₂/Ag催化分子氧氧化苯乙烯的研究[J]. 化工学报, 2020, 71(11): 4990-4998 DOI: 10.11949/0438-1157.20200810.

WU Yuefeng, QU Yongfang, LI Dahuan, SU Miaojun, LIU Yong. Study on oxidation of styrene with molecular oxygen catalyzed by MoO₂/Ag on polyionic liquid[J]. CIESC Journal, 2020, 71(11): 4990-4998 DOI: 10.11949/0438-1157.20200810.
吴岳峰, 曲永芳, 李大欢, 苏苗军, 刘勇. 聚离子液体载MoO₂/Ag催化分子氧氧化苯乙烯的研究[J]. 化工学报, 2020, 71(11): 4990-4998 DOI: 10.11949/0438-1157.20200810. DOI：

WU Yuefeng, QU Yongfang, LI Dahuan, SU Miaojun, LIU Yong. Study on oxidation of styrene with molecular oxygen catalyzed by MoO₂/Ag on polyionic liquid[J]. CIESC Journal, 2020, 71(11): 4990-4998 DOI: 10.11949/0438-1157.20200810. DOI：

摘要

以氨基功能化的聚离子液体为载体，通过离子交换和水热还原，制备出负载型催化剂PVAD/MoO

/Ag，考察了其催化苯乙烯氧化的性能。采用FT-IR、TG、XRD、SEM和BET对其所制备的催化剂进行表征。苯乙烯氧化性能研究结果表明，PVAD/MoO

/Ag

表现出最佳的催化活性，在乙腈为溶剂，温度为90℃，氧气压力为0.8 MPa的条件下，反应8 h，苯乙烯的转化率为49.9%，苯甲醛的选择性达到74.4%。并且催化剂重复使用5次，活性没有明显下降，表现出良好的重复利用性。

Abstract

The supported catalyst PVAD/MoO

/Ag was prepared by ion exchange and hydrothermal reduction using amino-functionalized polyionic liquid as the carrier

and its performance in catalyzing the oxidation of styrene was investigated. The prepared catalysts were characterized by FT-IR

XRD

SEM and BET. The results showed that PVAD/MoO

/Ag

showed the best catalytic activity.

Under the conditions of acetonitrile as solvent

temperature of 90℃ and oxygen pressure of 0.8 MPa for 8 h

the conversion rate of styrene was 49.9%

and the selectivity of benzaldehyde reached 74.4%. Moreover

the activity did not decrease significantly after reused 5 times

showing good reusability.

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references

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Study on oxidation of styrene with molecular oxygen catalyzed by MoO2/Ag on polyionic liquid

DOI：10.11949/0438-1157.20200810

摘要

Abstract

关键词

Keywords

references

Study on oxidation of styrene with molecular oxygen catalyzed by MoO₂/Ag on polyionic liquid