Physical properties characterizations and NH<sub>3</sub> capture performance investigation of novel phenol-based deep eutectic solvents

CHENG Ningning; ZENG Lihua; DENG Yulin; PENG Hailong; HUANG Kuan

doi:10.11949/0438-1157.20200796

您当前的位置：

首页 >

文章列表页 >

Physical properties characterizations and NH₃ capture performance investigation of novel phenol-based deep eutectic solvents

Celebration Column for School of Chemistry and Chemical Engineering\, Nanjing University | 更新时间：2026-07-24

- Physical properties characterizations and NH₃ capture performance investigation of novel phenol-based deep eutectic solvents
- CIESC Journal Vol. 71, Issue 11, Pages: 5043-5051(2020)
- 作者机构：
  
  1.南昌大学资源环境与化工学院，江西南昌 330031
  2.南昌大学鄱阳湖环境资源与利用教育部重点实验室，江西南昌 330031
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20200796
  CLC： TQ 028.8
- Received：22 June 2020，
  
  Revised：2020-09-02，
  
  Online First：03 November 2020，
  
  Published：05 November 2020
- 稿件说明：
移动端阅览
程宁宁, 曾丽花, 邓毓麟, 彭海龙, 黄宽. 新型酚基深共熔溶剂的物性表征及NH₃捕集性能研究[J]. 化工学报, 2020, 71(11): 5043-5051 DOI: 10.11949/0438-1157.20200796.

CHENG Ningning, ZENG Lihua, DENG Yulin, PENG Hailong, HUANG Kuan. Physical properties characterizations and NH₃ capture performance investigation of novel phenol-based deep eutectic solvents[J]. CIESC Journal, 2020, 71(11): 5043-5051 DOI: 10.11949/0438-1157.20200796.
程宁宁, 曾丽花, 邓毓麟, 彭海龙, 黄宽. 新型酚基深共熔溶剂的物性表征及NH₃捕集性能研究[J]. 化工学报, 2020, 71(11): 5043-5051 DOI: 10.11949/0438-1157.20200796. DOI：

CHENG Ningning, ZENG Lihua, DENG Yulin, PENG Hailong, HUANG Kuan. Physical properties characterizations and NH₃ capture performance investigation of novel phenol-based deep eutectic solvents[J]. CIESC Journal, 2020, 71(11): 5043-5051 DOI: 10.11949/0438-1157.20200796. DOI：

摘要

污染问题一直是化工、环保等领域关注的重点问题，对工业尾气中的NH

进行捕集和回收具有十分重要的意义。以氯化1-乙基-3-甲基咪唑（［Emim］Cl）为氢键受体，苯酚、间苯二酚和间苯三酚为氢键

供体，构建了一类新型酚基深共熔溶剂。详细测定了酚基深共熔溶剂在不同温度下的密度和黏度，并采用经验方程对密度和黏度数据进行了关联。此外，系统考察了酚基深共熔溶剂对NH

的吸收-解吸性能和吸收选择性，发现其具有较高的NH

吸收容量，被吸收的NH

可在加热和减压的条件下释放出来，经过多次循环NH

吸收容量基本保持不变。而酚基深共熔溶剂的CO

吸收容量则较低，因而具有优异的NH

/CO

吸收选择性。最后，借助光谱表征和量子化学计算，深入探究了NH

在酚基深共熔溶剂中吸收的相互作用机制。

Abstract

pollution has always been a key concern in chemical industry

environmental protection and other fields. The capture and recovery of NH

in industrial exhaust gas is of great significance. A novel class of phenol-based deep eutectic solvents (DESs) were constructed by using 1-ethyl-3-methylimidazolium chloride ([Emim

]

Cl) as the hydrogen bond acceptor

while phenol (Phe)

resorcinol (Res) and phloroglucinol (Phl) as the hydrogen bond donors. The densities and viscosities of phenol-based DESs at different temperatures were determined in detail

and the density and viscosity data were correlated by empirical equations. In addition

the NH

absorption-desorption performance and absorption selectivity of phenol-based DESs were systematically investigated. It is found that the capacities of phenol-based DESs for NH

absorption are quite high

and the absorbed NH

can be released by heating and evacuating

with the capacities for NH

absorption remaining almost unchanged after several cycles. However

the capacities of phenol-based DESs for CO

absorption are quite low

indicating the excellent performance of phenol-based DESs for NH

/CO

selective absorption. Finally

the interaction mechanism of NH

absorption in phenol-based DESs was studied in depth with the help of spectral characterizations and quantum chemistry calculations.

关键词

Keywords

references

Meng W , Zhong Q , Yun X , et al . Improvement of a global high-resolution ammonia emission inventory for combustion and industrial sources with new data from the residential and transportation sectors [J ] . Environ. Sci. Technol. , 2017 , 51 : 2821 - 2829 .

Rahimpour M R , Asgari A . Modeling and simulation of ammonia removal from purge gases of ammonia plants using a catalytic Pd-Ag membrane reactor [J ] . J. Hazard. Mater. , 2008 , 153 : 557 - 565 .

Travlou N A , Bandosz T J . N-Doped polymeric resin-derived porous carbons as efficient ammonia removal and detection media [J ] . Carbon , 2017 , 117 : 228 - 239 .

Ashtari A K , Majd A M S , Riskowski G L , et al . Removing ammonia from air with a constant pH, slightly acidic water spray wet scrubber using recycled scrubbing solution [J ] . Environ. Sci. Eng. , 2016 , 10 : 159 - 168 .

Tao W , Ukwuani A T . Coupling thermal stripping and acid absorption for ammonia recovery from dairy manure: ammonia volatilization kinetics and effects of temperature, pH and dissolved solids content [J ] . Chem. Eng. J. , 2015 , 280 : 188 - 196 .

Plechkova N V , Seddon K R . Applications of ionic liquids in the chemical industry [J ] . Chem. Soc. Rev. , 2008 , 37 : 123 - 150 .

Rogers R D , Seddon K R . Ionic liquid — solvents of the future? [J ] . Science , 2003 , 302 : 792 - 793 .

Earle M J , Seddon K R . Ionic liquids: green solvents for the future [J ] . Pure Appl. Chem. , 2000 , 72 : 1391 - 1398 .

Chen F F , Hang K , Fan J P , et al . Chemical solvent in chemical solvent: a class of hybrid materials for effective capture of CO 2 [J ] . AIChE J. , 2018 , 64 ( 2 ): 632 - 639 .

Yokozeki A , Shiflett M B . Ammonia solubilities in room-temperature ionic liquids [J ] . Ind. Eng. Chem. Res. , 2007 , 46 : 1605 - 1610 .

Yokozeki A , Shiflett M B . Vapor-liquid equilibria of ammonia plus ionic liquid mixtures [J ] . Appl. Energy , 2007 , 84 : 1258 - 1273 .

Shang D W , Bai L , Zeng S J , et al . Enhanced NH 3 capture by imidazolium-based protic ionic liquids with different anions and cation substituents [J ] . J. Chem. Technol. Biotechnol. , 2018 , 93 : 1228 - 1236 .

Wang J L , Zeng S J , Huo F , et al . Metal chloride anion-based ionic liquids for efficient separation of NH 3 [J ] . J. Cleaner Prod. , 2019 , 206 : 661 - 669 .

Zhang Q H , Vigier K D O , Royer S , et al . Deep eutectic solvents: syntheses, properties and applications [J ] . Chem. Soc. Rev. , 2012 , 41 : 7108 - 7146 .

Smith E L , Abbott A P , Ryder K S , et al . Deep eutectic solvents (DESs) and their applications [J ] . Chem. Rev. , 2014 , 114 : 11060 - 11082 .

García G , Aparicio S , Ullah R , et al . Deep eutectic solvents: physicochemical properties and gas separation applications [J ] . Energy Fuels , 2015 , 29 : 2616 - 2644 .

Carriazo D , Concepcion S M , Concepcion G M , et al . Deep-eutectic solvents playing multiple roles in the synthesis of polymers and related materials [J ] . Chem. Soc. Rev. , 2012 , 41 ( 14 ): 4996 - 5014 .

Wagle D V , Zhao H , Baker G A , et al . Deep eutectic solvents: sustainable media for nanoscale and functional materials [J ] . Acc. Chem. Res. , 2014 , 47 ( 8 ): 2299 - 2308 .

Abbott A P , Capper G , Mckenzie K J , et al . Electrodeposition of zinc-tin alloys from deep eutectic solvents based on choline chloride [J ] . Electroanal. Chem. , 2007 , 599 ( 2 ): 288 - 294 .

Zhang K , Ren S H , Hou Y C , et al . Efficient absorption of SO 2 with low-partial pressures by environmentally benign functional deep eutectic solvents [J ] . J. Hazard. Mater. , 2017 , 324 : 457 - 463 .

Deng D S , Liu X B , Gao B . Physicochemical properties and investigation of azole-based deep eutectic solvents as efficient and reversible SO 2 absorbents [J ] . Ind. Eng. Chem. Res. , 2017 , 56 : 13850 - 13856 .

Ghaedi H , Ayoub M , Sufian S , et al . CO 2 capture with the help of phosphonium-based deep eutectic solvents [J ] . J. Mol. Liq. , 2017 , 243 : 564 - 571 .

Sun S Y , Niu Y X , Xu Q , et al . Efficient SO 2 absorptions by four kinds of deep eutectic solvents based on choline chloride [J ] . Ind. Eng. Chem. Res. , 2015 , 54 : 8019 - 8024 .

Liu F J , Chen W , Mi J X , et al . Thermodynamic and molecular insights into the absorption of H 2 S, CO 2 , and CH 4 in choline chloride plus urea mixtures [J ] . AIChE J. , 2019 , 65 ( 5 ): e16574 .

Akhmetshina A I , Petukhov A N , Mechergui A , et al . Evaluation of methanesulfonate-based deep eutectic solvent for ammonia sorption [J ] . J. Chem. Eng. Data , 2018 , 63 : 1896 - 1904 .

Duan X Z , Gao B , Zhang C , et al . Solubility and thermodynamic properties of NH 3 in choline chloride-based deep eutectic solvents [J ] . J. Chem. Thermodyn. , 2019 , 133 : 79 - 84 .

Zhong F Y , Huang K , Peng H L . Solubilities of ammonia in choline chloride plus urea at (298.2—353.2) K and (0—300) kPa [J ] . J. Chem. Thermodyn. , 2019 , 129 : 5 - 11 .

Li Y H , Ali M C , Yang Q W , et al . Hybrid deep eutectic solvents with flexible hydrogen-bonded supramolecular networks for highly efficient uptake of NH 3 [J ] . ChemSusChem , 2017 , 10 : 3368 - 3377 .

Zhong F Y , Peng H L , Tao D J , et al . Phenol-based ternary deep eutectic solvents for highly eﬃcient and reversible absorption of NH 3 [J ] . ACS Sustain. Chem. Eng. , 2019 , 7 : 3258 - 3266 .

Zhong F Y , Zhou L S , Shen J . et al . Rational design of azole-based deep eutectic solvents for highly efficient and reversible capture of ammonia [J ] . Sustain. Chem. Eng. , 2019 , 7 ( 16 ): 14170 - 14179 .

Li Z L , Zhong F Y , Zhou L S , et al . Deep eutectic solvents formed by N -methylacetamide and heterocyclic weak acids for highly efficient and reversible chemical absorption of ammonia [J ] . Ind. Eng. Chem. Res. , 2020 , 59 ( 5 ): 2060 - 2067 .

Deng D S , Gao B , Zhang C , et al . Investigation of protic NH 4 SCN-based deep eutectic solvents as highly efficient and reversible NH 3 absorbents [J ] . Chem. Eng. J. , 2019 , 358 : 936 - 943 .

Jiang W J , Zhong F Y , Liu Y , et al . Effective and reversible capture of NH 3 by ethylamine hydrochloride plus glycerol deep eutectic solvents [J ] . ACS Sustain. Chem. Eng. , 2019 , 7 : 10552 - 10560 .

Zhang J Y , Huang K . Densities and viscosities of, and NH 3 solubilities in deep eutectic solvents composed of ethylamine hydrochloride and acetamide [J ] . J. Chem. Thermodyn. , 2019 , 139 : 105883 .

Zhang J Y , Kong L Y , Huang K , et al . NH 3 solubilities and physical properties of ethylamine hydrochloride plus urea deep eutectic solvents [J ] . Journal of Chemical & Engineering Data , 2019 , 9 : 3821 - 3830 .

Jiang W J , Zhong F Y , Zhou L S , et al . Chemically dual-site capture of NH 3 by unprecedently low-viscous deep eutectic solvents [J ] . Chem. Commun. , 2020 , 56 ( 16 ): 2399 - 2402 .

Huang K , Zhang X M , Hu X B , et al . Hydrophobic protic ionic liquids tethered with tertiary amine group for highly efficient and selective absorption of H 2 S from CO 2 [J ] . AIChE J. , 2016 , 62 : 4480 - 4490 .

Huang K , Zhang X M , Zhou L S , et al . Highly efficient and selective absorption of H 2 S in phenolic ionic liquids: a cooperative result of anionic strong basicity and cationic hydrogen-bond donation [J ] . Chem. Eng. Sci. , 2017 , 173 : 253 - 263 .

曾少娟 , 尚大伟 , 余敏 , 等 . 离子液体在氨气分离回收中的应用及展望 [J ] . 化工学报 , 2019 , 70 ( 3 ): 791 - 800 .

Zeng S J , Shang D W , Yu M , et al . Applications and perspectives of NH 3 separation and recovery with ionic liquids [J ] . CIESC Journal , 2019 , 70 ( 3 ): 791 - 800 .

Li G H , Zhou Q , Zhang X P , et al . Solubilities of ammonia in basic imidazolium ionic liquids [J ] . Fluid Phase Equilibr. , 2010 , 297 ( 1 ): 34 - 39 .

Li Z J , Zhang X P , Dong H F , et al . Efficient absorption of ammonia with hydroxyl-functionalized ionic liquids [J ] . RSC Adv. , 2015 , 5 : 81362 - 81370 .

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Research progresses of CO2 absorbents and AI-assisted screening

Pumping performance of bubble pump with dual entrances and dual exits

Study on performance and mechanism of triethylene glycol dimethyl ether for capturing low concentration SO2

Molecular thermodynamics for solubility of gas in binary liquid

Heat transfer mechanisms, bottleneck identification and optimization in heat exchanger networks under variable operating conditions

Related Author

FEI Yiran

ZHANG Yuqi

ZHU Chunying

FU Taotao

MA Youguang

TANG Jingxuan

LIU Yilun

HE Wei

Related Institution

State Key Laboratory of Chemical Engineering and Low-carbon Technology, School of Chemical Engineering and Technology, Tianjin University

Institute of Refrigeration and Cryogenics, Zhejiang University

School of Chemistry and Chemical Engineering, Guizhou University

Key Laboratory of Green Chemical and Clean Energy Technology

School of Chemistry and Chemical Engineering, Nanjing University

⁰

Physical properties characterizations and NH3 capture performance investigation of novel phenol-based deep eutectic solvents

DOI：10.11949/0438-1157.20200796

摘要

Abstract

关键词

Keywords

references

Physical properties characterizations and NH₃ capture performance investigation of novel phenol-based deep eutectic solvents