Research progress of catalytic pyrolysis of biomass to yield levoglucosenone

QIAN Le; JIANG Liqun; YUE Yuanmao; ZHAO Zengli

doi:10.11949/0438-1157.20200596

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Research progress of catalytic pyrolysis of biomass to yield levoglucosenone

Reviews and monographs | 更新时间：2026-07-24

- Research progress of catalytic pyrolysis of biomass to yield levoglucosenone
- CIESC Journal Vol. 71, Issue 12, Pages: 5376-5387(2020)
- 作者机构：
  
  1.中国科学院可再生能源重点实验室，广东省新能源和可再生能源研究开发与应用重点实验室，中国科学院广州能源研究所，广东广州510640
  2.中国科学技术大学纳米科学技术学院，江苏苏州 215213
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20200596
  CLC： TQ 480.10
- Received：18 May 2020，
  
  Revised：2020-06-10，
  
  Online First：17 December 2020，
  
  Published：05 December 2020
- 稿件说明：
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钱乐, 蒋丽群, 岳元茂, 赵增立. 催化热解生物质生成左旋葡聚糖酮的研究进展[J]. 化工学报, 2020, 71(12): 5376-5387

QIAN Le, JIANG Liqun, YUE Yuanmao, ZHAO Zengli. Research progress of catalytic pyrolysis of biomass to yield levoglucosenone[J]. CIESC Journal, 2020, 71(12): 5376-5387
钱乐, 蒋丽群, 岳元茂, 赵增立. 催化热解生物质生成左旋葡聚糖酮的研究进展[J]. 化工学报, 2020, 71(12): 5376-5387 DOI： 10.11949/0438-1157.20200596.

QIAN Le, JIANG Liqun, YUE Yuanmao, ZHAO Zengli. Research progress of catalytic pyrolysis of biomass to yield levoglucosenone[J]. CIESC Journal, 2020, 71(12): 5376-5387 DOI： 10.11949/0438-1157.20200596.

摘要

左旋葡聚糖酮（LGO）在有机合成领域有巨大的应用价值，快速热解生物质制取左旋葡聚糖酮是生物质能开发与利用的研究热点。目前LGO的应用主要受到其产量的限制：一是没有较好的化学合成方法，二是常规热解生物质得到的产物中左旋葡聚糖酮的含量极低，使得LGO难以大量生产。催化热解可以显著提高左旋葡聚糖酮的产率，目前用于催化热解生物质制取左旋葡聚糖酮的各类催化剂，包括液体酸、固体酸、金属氯化物、离子液体等均取得了一定的成果，但效果差异明显，因此分析了不同催化剂间的优势与劣势，并对以后的工作进行了展望。

Abstract

Levoglucosenone (LGO) has great applicable value in the field of organic synthesis. The rapid pyrolysis of biomass to produce LGO is a research hotspot in the development and utilization of biomass energy. The application of LGO is mainly limited by its yield: first

it is difficult to prepare LGO by chemical synthesis

and second

the content of LGO in the products obtained by conventional pyrolysis biomass is extremely low

making LGO challenge to produce in large quantities. Catalytic pyrolysis can significantly increase the yield of LGO. Currently

various catalysts which used to prepare LGO

including liquid acid

solid acid

metal chloride and ionic liquid

have achieved evident results

but the effects are individually different. The difference in catalytic effect of various catalysts are analyzed

and a brief conclusion for the challenge in this topic is provided.

关键词

Keywords

references

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