Design, synthesis and application of high-performance carbon-based energy storage materials

WANG Xiaobo; ZHAO Qingshan; CHENG Zhinian; ZHANG Haoran; HU Han; WANG Luhai; WU Mingbo

doi:10.11949/0438-1157.20200508

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Design, synthesis and application of high-performance carbon-based energy storage materials

Reviews and monographs | 更新时间：2026-07-24

- Design, synthesis and application of high-performance carbon-based energy storage materials
- CIESC Journal Vol. 71, Issue 6, Pages: 2660-2677(2020)
- 作者机构：
  
  1.中国石油大学(华东)化学工程学院，重质油国家重点实验室，山东青岛 266580
  2.中国石油大学（华东）石大兖矿新能源学院，山东青岛 266580
  3.中国石油石油化工研究院，北京 100084
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20200508
  CLC： TQ 028.8
- Received：07 May 2020，
  
  Revised：2020-05-18，
  
  Online First：18 June 2020，
  
  Published：05 June 2020
- 稿件说明：
移动端阅览
王晓波, 赵青山, 程智年, 张浩然, 胡涵, 王路海, 吴明铂. 高性能碳基储能材料的设计、合成与应用[J]. 化工学报, 2020, 71(6): 2660-2677

WANG Xiaobo, ZHAO Qingshan, CHENG Zhinian, ZHANG Haoran, HU Han, WANG Luhai, WU Mingbo. Design, synthesis and application of high-performance carbon-based energy storage materials[J]. CIESC Journal, 2020, 71(6): 2660-2677
王晓波, 赵青山, 程智年, 张浩然, 胡涵, 王路海, 吴明铂. 高性能碳基储能材料的设计、合成与应用[J]. 化工学报, 2020, 71(6): 2660-2677 DOI： 10.11949/0438-1157.20200508.

WANG Xiaobo, ZHAO Qingshan, CHENG Zhinian, ZHANG Haoran, HU Han, WANG Luhai, WU Mingbo. Design, synthesis and application of high-performance carbon-based energy storage materials[J]. CIESC Journal, 2020, 71(6): 2660-2677 DOI： 10.11949/0438-1157.20200508.

摘要

电化学储能器件的性能很大程度上决定于其电极材料。碳材料具有来源广泛、化学稳定性好、易于调控、环境友好等优点，被广泛应用于各类能量存储系统，但仍存在能量密度低、倍率性能差等问题。本文从碳材料孔结构调控、杂原子掺杂、与金属氧化物复合三个角度，综述了构建高性能碳基储能材料的设计合成策略，介绍了其在锂/钠离子二次电池、超级电容器等领域的研究进展，对几种方法策略的优缺点进行了总结，并对未来的研究方向进行了展望。本文对高性能碳基储能电极材料的设计开发具有积极意义。

Abstract

The performance of electrochemical energy storage device mainly depends on the electrode materials. Carbon materials have been widely applied in various energy storage systems due to their multitudinous advantages such as wide availability

excellent chemical stability

easy to modulate

and environmental friendliness. However

traditional carbon materials still suffer from problems such as low capacity density and poor rate performance. This review focuses on the design strategies for high-performance carbon-based energy storage materials

including pore structure regulation

heteroatomic doping

and combination with metal oxides. Their applications in lithium/sodium ion secondary batteries and supercapacitors are introduced. The advantages and disadvantages of these strategies are summarized

and the future research direction is also prospected. It has positive significance for the design and development of high-performance carbon-based energy storage electrode materials.

关键词

Keywords

references

Simon P , Gogoysi Y . Materials for electrochemical capacitors [J ] . Nature Materials , 2008 , 7 ( 11 ): 845 - 854 .

Liu C , Li F , Ma L P , et al . Advanced materials for energy storage [J ] . Advanced Materials , 2010 , 22 ( 8 ): 28 - 62 .

Arico A S , Bruce P G , Scrosti B , et al . Nanostructured materials for advanced energy conversion and storage devices [J ] . Nature Materials , 2005 , 4 ( 5 ): 366 - 377 .

Bruce P G , Freunberger S A , Hardwick L J , et al . Li-O 2 and Li-S batteries with high energy storage [J ] . Nature Materials , 2011 , 11 ( 1 ): 19 - 29 .

Wen L , Li F , Luo H Z , et al . Graphene for Flexible Lithium-ion Batteries: Development and Prospects [M ] . John , Wiley & Sons , Ltd. , 2015 .

Li P , Liu J Y , Wang Y W , et al . Synthesis of ultrathin hollow carbon shell from petroleum asphalt for high-performance anode material in lithium-ion batteries [J ] . Chemical Engineering Journal , 2016 , 286 : 632 - 639 .

Wang Y W , Xiao N , Wang Z Y , et al . Rational design of high-performance sodium-ion battery anode by molecular engineering of coal tar pitch [J ] . Chemical Engineering Journal , 2018 ， 342 : 52 - 60 .

Zhu C Y , Akiyama T . Cotton derived porous carbon via an MgO template method for high performance lithium ion battery anodes [J ] . Green Chemistry , 2016 , 18 ( 7 ): 2106 - 2114 .

Stein A , Wang Z Y , Fierke M A , et al . Functionalization of porous carbon materials with designed pore architecture [J ] . Advanced Materials , 2009 , 21 ( 3 ): 265 - 293 .

Kim Y I , Lee Y J , Yoo J , et al . High-capacitance activated bio-carbons with controlled pore size distribution for sustainable energy storage [J ] . Journal of Power Sources , 2019 , 438 : 226969 - 226978 .

He X J , Wang J X , Xu G H , et al . Synthesis of microporous carbon/graphene composites for high-performance supercapacitors [J ] . Diamond and Related Materials , 2016 , 66 : 119 - 125 .

Zhang F , Liu T Y , Hou G H , et al . Hierarchically porous carbon foams for electric double layer capacitors [J ] . Nano Research , 2016 , 9 ( 10 ): 2875 - 2888 .

He X J , Ling P H , Yu M X , et al . Rice husk-derived porous carbons with high capacitance by ZnCl 2 activation for supercapacitors [J ] . Electrochimica Acta , 2013 , 105 ( 105 ): 635 - 641 .

Olivaresmarin M , Fernandezgonzalez C , Maciasgarcia A , et al . Preparation of activated carbon from cherry stones by chemical activation with ZnCl 2 [J ] . Applied Surface Science , 2006 , 252 ( 17 ): 5967 - 5971 .

Kim S , Lee J , Jaewook L . Hierarchical porous carbon from algae biomass by peroxide-assisted microwave activation for dye adsorption [J ] . Journal of Advanced Engineering and Technology , 2019 , 12 ( 3 ): 143 - 148 .

Guo Y P , Qi J R , Jiang Y Q , et al . Performance of electrical double layer capacitors with porous carbons derived from rice husk [J ] . Materials Chemistry and Physics , 2003 , 80 ( 3 ): 704 - 709 .

Zhang W F , Huang Z H , Guo Z , et al . Porous carbons prepared from deoiled asphalt and their electrochemical properties for supercapacitors [J ] . Materials Letters , 2010 , 64 ( 17 ): 1868 - 1870 .

Lupul I , Yperman J , Carleer R , et al . Tailoring of porous texture of hemp stem-based activated carbon produced by phosphoric acid activation in steam atmosphere [J ] . Journal of Porous Materials , 2015 , 22 ( 1 ): 283 - 289 .

Liu S L , Wang Y N , Lu K , et al . Preparation and pore characterization of activated carbon from Ma bamboo ( Dendrocalamus latiflorus ) by H 3 PO 4 chemical activation [J ] . Journal of Porous Materials , 2014 , 21 ( 4 ): 459 - 466 .

He X J , Li R C , Qiu J S , et al . Synthesis of mesoporous carbons for supercapacitors from coal tar pitch by coupling microwave-assisted KOH activation with a MgO template [J ] . Carbon , 2012 , 50 ( 13 ): 4911 - 4921 .

He X J , Zhao N , Qiu J S , et al . Synthesis of hierarchical porous carbons for supercapacitors from coal tar pitch with nano-Fe 2 O 3 as template and activation agent coupled with KOH activation [J ] . Journal of Materials Chemistry , 2013 , 1 ( 33 ): 9440 - 9448 .

Pan L , Li X X , Wang Y X , et al . 3D interconnected honeycomb-like and high rate performance porous carbons from petroleum asphalt for supercapacitors [J ] . Applied Surface Science , 2018 , 444 ( 30 ): 739 - 746 .

Sun Q Y . Porous carbon material based on biomass prepared by MgO template method and ZnCl 2 activation method as electrode for high performance supercapacitor [J ] . International Journal of Electrochemical Science , 2019 , 14 : 1 - 14 .

Paraknowitsch J P , Thomas A . Doping carbons beyond nitrogen: an overview of advanced heteroatom doped carbons with boron, sulphur and phosphorus for energy applications [J ] . Energy and Environmental Science , 2013 , 6 ( 10 ): 2839 - 2855 .

Wood K N , Ohayre R , Pylypenko S , et al . Recent progress on nitrogen/carbon structures designed for use in energy and sustainability applications [J ] . Energy and Environmental Science , 2014 , 7 ( 4 ): 1212 - 1249 .

Zhu Y P , Guo C X , Zheng Y , et al . Surface and interface engineering of noble-metal-free electrocatalysts for efficient energy conversion processes [J ] . Accounts of Chemical Research , 2017 , 50 ( 4 ): 915 - 923 .

Tian W , Liu J L , Wang Y X , et al . Substrate-assisted in situ confinement pyrolysis of zeolitic imidazolate frameworks to nitrogen-doped hierarchical porous carbon nanoframes with superior lithium storage [J ] . ACS Applied Materials & Interfaces , 2017 , 9 ( 49 ): 42845 - 42855 .

Qie L , Chen W M , Xiong X Q , et al . Sulfur-doped carbon with enlarged interlayer distance as a high-performance anode material for sodium-ion batteries [J ] . Advanced Science , 2015 , 2 ( 12 ): 1500195 - 1500200 .

Yi J N , Qing Y , Wu C T , et al . Lignocellulose-derived porous phosphorus-doped carbon as advanced electrode for supercapacitors [J ] . Journal of Power Sources , 2017 , 351 : 130 - 137 .

Geng Z , Li B , Liu H Z , et al . Oxygen-doped carbon host with enhanced bonding and electron attraction abilities for efficient and stable SnO 2 /carbon composite battery anode [J ] . Science China-Materials , 2018 , 61 ( 8 ): 1067 - 1077 .

Rodriguez E , Camean I , Garcia R , et al . Graphitized boron-doped carbon foams: performance as anodes in lithium-ion batteries [J ] . Electrochimica Acta , 2011 , 56 ( 14 ): 5090 - 5094 .

Peng Y Y , Zhang Y Y , Huang J X , et al . Nitrogen and oxygen dual-doped hollow carbon nanospheres derived from catechol/polyamine as sulfur hosts for advanced lithium sulfur batteries [J ] . Carbon , 2017 , 124 : 23 - 33 .

Zhou J , Shen H L , Li Z H , et al . Porous carbon materials with dual N, S-doping and uniform ultra-microporosity for high performance supercapacitors [J ] . Electrochimica Acta , 2016 , 209 : 557 - 564 .

Jin C B , Zhang W K , Zhuang Z Z , et al . Enhanced sulfide chemisorption using boron and oxygen dually doped multi-walled carbon nanotubes for advanced lithium-sulfur batteries [J ] . Journal of Materials Chemistry , 2017 , 5 ( 2 ): 632 - 640 .

Wang L , Wang Y Q , Wu M G , et al . Nitrogen, fluorine, and boron ternary doped carbon fibers as cathode electrocatalysts for zinc–air batteries [J ] . Small , 2018 , 14 ( 20 ): 1800737 - 1800744 .

Liu J Y , Liu Y , Li P , et al . Fe-N-doped porous carbon from petroleum asphalt for highly efficient oxygen reduction reaction [J ] . Carbon , 2018 , 126 : 1 - 8 .

Ni D , Sun W , Wang Z H , et al . Heteroatom‐doped mesoporous hollow carbon spheres for fast sodium storage with an ultralong cycle life [J ] . Advanced Energy Materials , 2019 , 9 ( 19 ): 1900036 - 1900046 .

Li Z T , Wang Y K , Chen Y , et al . Controllable growth of MnO x dual-nanocrystals on N-doped graphene as lithium-ion battery anode [J ] . RSC Advances , 2017 , 7 ( 11 ): 6396 - 6402 .

Li Z H , Cui Y H , Chen J , et al . Fabrication of (Co, Mn) 3 O 4 /rGO composite for lithium ion battery anode by a one-step hydrothermal process with H 2 O 2 as additive [J ] . Plos One , 2016 , 11 ( 10 ): 164657 - 164668 .

Feng J Z , Dong Y F , Yan Y C , et al . Extended lattice space of TiO 2 hollow nanocubes for improved sodium storage [J ] . Chemical Engineering Journal , 2019 , 373 : 565 - 571 .

Wang D , Zhou W W , Zhang R , et al . MOF-derived Zn-Mn mixed oxides@carbon hollow disks with robust hierarchical structure for high-performance lithium-ion batteries [J ] . Journal of Materials Chemistry A , 2018 , 6 ( 7 ): 2974 - 2983 .

Ning H , Xie H , Zhao Q S , et al . Electrospinning ZnO/carbon nanofiber as binder-free and self-supported anode for Li-ion batteries [J ] . Journal of Alloys and Compounds , 2017 , 722 : 716 - 720 .

Zhang C Y , Su L , Huang L N , et al . A facile synthesis of Cu-MnO/CNF by electrospinning method and its electrochemical performance for supercapacitor application [J ] . International Journal of Electrochemical Science , 2019 , 14 ( 12 ): 11358 - 11366 .

Nayak P K , Yang L T , Brehm W , et al . From lithium‐ion to sodium-ion batteries: advantages, challenges, and surprises [J ] . Angewandte Chemie , 2018 , 57 ( 1 ): 102 - 120 .

Nitta N , Wu F X , Lee J , et al . Li-ion battery materials: present and future [J ] . Materials Today , 2015 , 18 ( 5 ): 252 - 264 .

Visstrom H , Ddvidsson S , Hook M . Lithium availability and future production outlooks [J ] . Applied Energy , 2013 , 110 ( 10 ): 252 - 266 .

张伶俐 . 石墨烯及过渡金属氧化物在锂/钠离子电池负极材料中的应用 [D ] . 南宁 : 广西大学 , 2018 .

Zhang L L . Application of graphene and transition metal oxides for anode materials of lithium/sodium ion batteries [D ] . Nanning : Guangxi University , 2018 .

Tarascon J M , Armand M . Issues and challenges facing rechargeable lithium batteries [J ] . Nature , 2001 , 414 ( 6861 ): 359 - 367 .

Armand M , Tarascon J M . Building better batteries [J ] . Nature , 2008 , 451 ( 7179 ): 652 - 657 .

Scrosati B , Garche J . Lithium batteries: status, prospects and future [J ] . Journal of Power Sources , 2010 , 195 ( 9 ): 2419 - 2430 .

Hwang J Y , Myung S , Sun Y . Sodium-ion batteries: present and future [J ] . Chemical Society Reviews , 2017 , 46 ( 12 ): 3529 - 3614 .

Peters J , Buchholz D , Passerini S , et al . Life cycle assessment of sodium-ion batteries [J ] . Energy and Environmental Science , 2016 , 9 ( 5 ): 1744 - 1751 .

Yabuuchi N , Kubota K , Dahbi M , et al . Research development on sodium-ion batteries [J ] . Chemical Reviews , 2014 , 114 ( 23 ): 11636 - 11682 .

Hong S Y , Kim Y J , Park Y , et al . Charge carriers in rechargeable batteries: Na ions vs . Li ions [J ] . Energy and Environmental Science , 2013 , 6 ( 7 ): 2067 - 2081 .

Luo W , Shen F , Bommier C , et al . Na-ion battery anodes: materials and electrochemistry [J ] . Accounts of Chemical Research , 2016 , 49 ( 2 ): 231 - 240 .

Bresser D , Passerini S , Scrosati B , et al . Leveraging valuable synergies by combining alloying and conversion for lithium-ion anodes [J ] . Energy and Environmental Science , 2016 , 9 ( 11 ): 3348 - 3367 .

Wang Y X , Tian W , Wang L H , et al . A tunable molten-salt route for scalable synthesis of ultrathin amorphous carbon nanosheets as high-performance anode materials for lithium-ion batteries [J ] . ACS Applied Materials & Interfaces , 2018 , 10 ( 6 ): 5577 - 5585 .

Wang Y X , Wang Y W , Liu J Y , et al . Preparation of carbon nanosheets from petroleum asphalt via recyclable molten-salt method for superior lithium and sodium storage [J ] . Carbon , 2017 , 122 : 344 - 351 .

Gao C , Feng J Z , Dai J R , et al . Manipulation of interlayer spacing and surface charge of carbon nanosheets for robust lithium/sodium storage [J ] . Carbon , 2019 , 153 : 372 - 380 .

Li Z T , Wu G L , Deng S Z , et al . Combination of uniform SnO 2 nanocrystals with nitrogen doped graphene for high-performance lithium-ion batteries anode [J ] . Chemical Engineering Journal , 2016 , 283 : 1435 - 1442 .

Tian W , Hu H , Wang Y X , et al . Metal–organic frameworks mediated synthesis of one-dimensional molybdenum-based/carbon composites for enhanced lithium storage [J ] . ACS Nano , 2018 , 12 ( 2 ): 1990 - 2000 .

Zhao Q S , Liu J L , Li X X , et al . Graphene oxide-induced synthesis of button-shaped amorphous Fe 2 O 3 /rGO/CNFs films as flexible anode for high-performance lithium-ion batteries [J ] . Chemical Engineering Journal , 2019 , 369 : 215 - 222 .

Kou T Y , Yao B , Liu T Y , et al . Recent advances in chemical methods for activating carbon and metal oxide based electrodes for supercapacitors [J ] . Journal of Materials Chemistry , 2017 , 5 ( 33 ): 17151 - 17173 .

Bonaccorso F , Colombo L , Yu G H , et al . Graphene, related two-dimensional crystals, and hybrid systems for energy conversion and storage [J ] . Science , 2015 , 347 : 1246501 - 1246510 .

Pan L , Wang Y X , Hu H , et al . 3D self-assembly synthesis of hierarchical porous carbon from petroleum asphalt for supercapacitors [J ] . Carbon , 2018 , 134 : 345 - 353 .

Guan L , Pan L , Peng T Y , et al . Green and scalable synthesis of porous carbon nanosheet-assembled hierarchical architectures for robust capacitive energy harvesting [J ] . Carbon , 2019 , 152 : 537 - 544 .

Gao F , Shao G H , Qu J Y , et al . Tailoring of porous and nitrogen-rich carbons derived from hydrochar for high-performance supercapacitor electrodes [J ] . Electrochimica Acta , 2015 , 155 : 201 - 208 .

Guan L , Pan L , Peng T Y , et al . Synthesis of biomass-derived nitrogen-doped porous carbon nanosheests for high-performance supercapacitors [J ] . ACS Sustainable Chemistry & Engineering , 2019 , 7 ( 9 ): 8405 - 8412 .

Xia L C , Huang H , Fan Z , et al . Hierarchical macro-/meso-/microporous oxygen-doped carbon derived from sodium alginate: A cost-effective biomass material for binder-free supercapacitors [J ] . Materials & Design , 2019 , 182 : 108048 - 108056 .

Glenis S , Nelson A J , Labes M M , et al . Sulfur doped graphite prepared via arc discharge of carbon rods in the presence of thiophenes [J ] . Journal of Applied Physics , 1999 , 86 ( 8 ): 4464 - 4466 .

Kuper C A , Labes M M . A new method of doping pyrolytic graphite utilizing laser heating in the presence of organic heteroatomic vapors [J ] . Chemistry of Materials , 1999 , 11 ( 2 ): 408 - 411 .

Lei W , Zhang H J , Liu D Z , et al . Fabrication of nitrogen and sulfur co-doped carbon nanofibers with three-dimensional architecture for high performance supercapacitors [J ] . Applied Surface Science , 2019 , 495 : 143572 - 143580 .

肖谧 , 宿玉鹏 , 杜伯学 . 超级电容器研究进展 [J ] . 电子元件与材料 , 2019 , ( 9 ): 1 - 12 .

Xiao M , Su Y P , Du B X . Research advance of supercapacitors [J ] . Electronic Components and Materials , 2019 , ( 9 ): 1 - 12 .

Pandolfo A , Hollenkamp A F . Carbon properties and their role in supercapacitors [J ] . Journal of Power Sources , 2006 , 157 ( 1 ): 11 - 27 .

杨波 , 伍俊霖 , 刘文宝 , 等 . 商业化石墨烯材料在超级电容器中的应用研究 [J ] . 化工新型材料 , 2019 , 47 ( 8 ): 220 - 223 .

Yang B , Wu J L , Liu W B , et al . Application of commercialized graphene material for supercapacitor [J ] . New Chemical Materials , 2019 , 47 ( 8 ): 220 - 223 .

Li J E , Wang Y W , Xu W N , et al . Porous Fe 2 O 3 nanospheres anchored on activated carbon cloth for high-performance symmetric supercapacitors [J ] . Nano Energy , 2019 , 57 : 379 - 387 .

Ji H M , Liu X L , Liu Z J , et al . In situ preparation of sandwich MoO 3 /C hybrid nanostructures for high‐rate and ultralong‐life supercapacitors [J ] . Advanced Functional Materials , 2015 , 25 ( 12 ): 1886 - 1894 .

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