Degradation of bisphenol A by peroxymonosulfate activated by MnFe<sub>2</sub>O<sub>4</sub> prepared by salt-assisted solution combustion synthesis

YUE Min; WANG Jing; HAN Yuze; ZHANG Ping

doi:10.11949/0438-1157.20200493

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Degradation of bisphenol A by peroxymonosulfate activated by MnFe₂O₄ prepared by salt-assisted solution combustion synthesis

Catalysis\, kinetics and reactors | 更新时间：2026-07-24

- Degradation of bisphenol A by peroxymonosulfate activated by MnFe₂O₄ prepared by salt-assisted solution combustion synthesis
- CIESC Journal Vol. 71, Issue 12, Pages: 5589-5598(2020)
- 作者机构：
  
  1.山东省水环境污染控制与资源化重点实验室，山东大学环境科学与工程学院，山东青岛266237
  2.《山东大学学报（哲社版）》编辑部，山东济南 250100
  3.山东城市建设职业学院，山东济南 250103
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20200493
  CLC： X 522
- Received：06 May 2020，
  
  Revised：2020-08-30，
  
  Online First：17 December 2020，
  
  Published：05 December 2020
- 稿件说明：
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岳敏, 王璟, 韩玉泽, 张萍. 盐助溶液燃烧法制备MnFe₂O₄催化过一硫酸盐降解双酚A[J]. 化工学报, 2020, 71(12): 5589-5598 DOI: 10.11949/0438-1157.20200493.

YUE Min, WANG Jing, HAN Yuze, ZHANG Ping. Degradation of bisphenol A by peroxymonosulfate activated by MnFe₂O₄ prepared by salt-assisted solution combustion synthesis[J]. CIESC Journal, 2020, 71(12): 5589-5598 DOI: 10.11949/0438-1157.20200493.
岳敏, 王璟, 韩玉泽, 张萍. 盐助溶液燃烧法制备MnFe₂O₄催化过一硫酸盐降解双酚A[J]. 化工学报, 2020, 71(12): 5589-5598 DOI: 10.11949/0438-1157.20200493. DOI：

YUE Min, WANG Jing, HAN Yuze, ZHANG Ping. Degradation of bisphenol A by peroxymonosulfate activated by MnFe₂O₄ prepared by salt-assisted solution combustion synthesis[J]. CIESC Journal, 2020, 71(12): 5589-5598 DOI: 10.11949/0438-1157.20200493. DOI：

摘要

采用盐助溶液燃烧法制备磁性铁酸锰（MnFe

），催化过一硫酸氢盐（PMS）氧化降解水溶液中的双酚A。通过XRD、BET等手段对制备的铁酸锰催化剂进行了表征。探究了MnFe

投加量、PMS投加量、溶液初始pH、淬灭剂、共存离子等因素对双酚A降解效果的影响，评估了MnFe

催化剂的循环利用性能。结果表明，MnFe

和PMS的最合理投加量分别为 0.3 g/L、0.3 mmol/L，初始pH为11.0时双酚A降解效果最好，60 min内的降解率可达99.3%。淬灭实验表明，催化体系中同时存在多种活性物质，

是主要活性物种。溶液中Cl

、HCO

和HPO

等共存离子的存在影响双酚A的降解。双酚A在60 min内的TOC去除率为34.9%，苯环断裂和开环反应是其主要降解路径。MnFe

催化剂循环使用三次后，双酚A的降解率仍保持在90.0%左右。

Abstract

Magnetic manganese ferrite (MnFe

) prepared by the salt-assisted solution combustion synthesis was used to activate peroxymonosulfate(PMS) to oxidize bisphenol A in aqueous solution. The prepared MnFe

catalyst was characterized by XRD and BET. The effects of MnFe

dosage

PMS dosage

initial pH of the solution

quencher

and co-existing ions on the degradation of bisphenol A were investigated. The reusability of the MnFe

catalyst was evaluated through cycling experiments. The results showed that the best dosages of MnFe

and PMS were 0.3 g/L and 0.3 mmol/L

respectively. When the initial pH was 11.0

the degradation rate of bisphenol A was 99.3% in 60 min. When putting some quenchers into the MnFe

/PMS catalytic system

all of them showed depression effects on degradation of bisphenol A

and the

was the main active species. The co-existing ions such as Cl

HCO

and HPO

in solution affected the degradation of bisphenol A. The TOC removal rate of bisphenol A within 60 min was 34.9%

the rupture and opening of benzene ring are the main reaction pathways. After the MnFe

catalyst was recycled three times

the degradation rate of bisphenol A remained at about 90.0%.

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references

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Degradation of bisphenol A by peroxymonosulfate activated by MnFe2O4 prepared by salt-assisted solution combustion synthesis

DOI：10.11949/0438-1157.20200493

摘要

Abstract

关键词

Keywords

references

Degradation of bisphenol A by peroxymonosulfate activated by MnFe₂O₄ prepared by salt-assisted solution combustion synthesis