High efficient corrosion inhibition of steel by nano-micro aggregates of <italic style="font-style: italic">Sapindus mukorossi Gaertn</italic> peel extracts

Xue LUO; Haijun HUANG; Ziping LUO; Zhiyong WANG; Xiaojing MU; Hongru LI; Xinchao WANG; Shengtao ZHANG; Fang GAO

doi:10.11949/0438-1157.20200065

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High efficient corrosion inhibition of steel by nano-micro aggregates of Sapindus mukorossi Gaertn peel extracts

Surface and interface engineering | 更新时间：2025-11-25

- High efficient corrosion inhibition of steel by nano-micro aggregates of Sapindus mukorossi Gaertn peel extracts
- CIESC Journal Vol. 71, Issue 10, Pages: 4760-4772(2020)
- 作者机构：
  
  1.重庆大学化学化工学院，重庆 400044
  2.菏泽学院药学院，山东菏泽 274015
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20200065
  CLC： TG 178
- Received：16 January 2020，
  
  Revised：2020-04-13，
  
  Published：05 October 2020
- 稿件说明：
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罗雪, 黄海军, 罗自萍, 王治永, 穆小静, 李红茹, 王新潮, 张胜涛, 高放. 无患子果皮提取物的纳微米聚集体对钢的高效缓蚀[J]. 化工学报, 2020, 71(10): 4760-4772

LUO Xue, HUANG Haijun, LUO Ziping, WANG Zhiyong, MU Xiaojing, LI Hongru, WANG Xinchao, ZHANG Shengtao, GAO Fang. High efficient corrosion inhibition of steel by nano-micro aggregates of Sapindus mukorossi Gaertn peel extracts[J]. CIESC Journal, 2020, 71(10): 4760-4772
罗雪, 黄海军, 罗自萍, 王治永, 穆小静, 李红茹, 王新潮, 张胜涛, 高放. 无患子果皮提取物的纳微米聚集体对钢的高效缓蚀[J]. 化工学报, 2020, 71(10): 4760-4772 DOI： 10.11949/0438-1157.20200065.

LUO Xue, HUANG Haijun, LUO Ziping, WANG Zhiyong, MU Xiaojing, LI Hongru, WANG Xinchao, ZHANG Shengtao, GAO Fang. High efficient corrosion inhibition of steel by nano-micro aggregates of Sapindus mukorossi Gaertn peel extracts[J]. CIESC Journal, 2020, 71(10): 4760-4772 DOI： 10.11949/0438-1157.20200065.

摘要

为寻求绿色、可持续与具备大规模应用潜能的天然植物提取物作为缓蚀剂，选择具有表面活性剂性质的无患子果皮提取物作为研究对象。通过简便乙醇回流萃取获得无患子果皮提取物。在室温条件下，无患子果皮提取物在DMF（

，

-二甲基甲酰胺）/HCl水溶液的混合溶液（体积比50/50，1.0 mol/L HCl 溶液）中能够发生自组装产生有序的纳微米聚集材料。傅里叶变换红外光谱（FT-IR）与X射线光电子能谱（XPS）研究表明了无患子果皮提取物聚集体能够对Q235钢表面产生化学吸附作用。利用电化学方法研究了无患子果皮提取物聚集体吸附在钢表面后，在1.0 mol/L盐酸水溶液中的缓蚀性能。结果表明无患子果皮提取物聚集体能够有效抑制钢被盐酸腐蚀，最大缓蚀效率达到90%以上。

Abstract

To seek green

sustainable and natural plant extracts with the potential for large-scale application as corrosion inhibitors

this article selects the extracts of the

Sapindus mukorossi Gaertn

peels with surfactant properties as the research object. Hence

this article uses

Sapindus mukorossi Gaertn

peel extracts (SMGPE) with surfactant properties as the study candidate. This survey presents efficient extraction of

Sapindus mukorossi Gaertn

peels by simply refluxing ethanol solution. It is shown that SMGPE can process orderly nano-micro meters aggregation in DMF/HCl (volume ratio: 50/50

1.0 mol/L HCl solution) mixed solution through self-organization at the room temperature.The results show that the predominantly strong chemical adsorption of formed SMGPE aggregates on the studied Q235 steel specimens is suggested through the detection of FT-IR

Raman as well as XPS spectroscopy. This study further determines the corrosion inhibition effect of the stable SMGPE aggregates for the studied steel specimens in 1.0 mol/L HCl aqueous solution based on electrochemical method. The results suggest that the SMGPE aggregates can inhibit corrosion of the steel specimens in HCl solution efficiently

and the greatest corrosion inhibition efficiency is over 90%.

关键词

Keywords

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⁰

High efficient corrosion inhibition of steel by nano-micro aggregates of Sapindus mukorossi Gaertn peel extracts

DOI：10.11949/0438-1157.20200065

摘要

Abstract

关键词

Keywords

references