Construction of free binder V2O5 and Fe2O3 flexible electrode and its application in supercapacitor

Bingbing HU; Shu YANG; Yan LI; Chuanlan XU; Peng CHEN; Jingjing YU; Danmei YU; Changguo CHEN

doi:10.11949/0438-1157.20191307

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Construction of free binder V₂O₅ and Fe₂O₃ flexible electrode and its application in supercapacitor

Material science and engineering, nanotechnology | 更新时间：2025-11-25

- Construction of free binder V₂O₅ and Fe₂O₃ flexible electrode and its application in supercapacitor
- CIESC Journal Vol. 71, Issue 10, Pages: 4836-4846(2020)
- 作者机构：
  
  重庆大学化学化工学院，重庆 401331
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20191307
  CLC： TB 321;TQ 152
- Received：01 November 2019，
  
  Revised：2020-03-02，
  
  Published：05 October 2020
- 稿件说明：
移动端阅览
胡兵兵, 杨束, 李彦, 徐川岚, 陈鹏, 于晶晶, 余丹梅, 陈昌国. 免黏结剂V₂O₅和Fe₂O₃柔性电极的构建及在超级电容器中的应用[J]. 化工学报, 2020, 71(10): 4836-4846 DOI: 10.11949/0438-1157.20191307.

HU Bingbing, YANG Shu, LI Yan, XU Chuanlan, CHEN Peng, YU Jingjing, YU Danmei, CHEN Changguo. Construction of free binder V₂O₅ and Fe₂O₃ flexible electrode and its application in supercapacitor[J]. CIESC Journal, 2020, 71(10): 4836-4846 DOI: 10.11949/0438-1157.20191307.
胡兵兵, 杨束, 李彦, 徐川岚, 陈鹏, 于晶晶, 余丹梅, 陈昌国. 免黏结剂V₂O₅和Fe₂O₃柔性电极的构建及在超级电容器中的应用[J]. 化工学报, 2020, 71(10): 4836-4846 DOI: 10.11949/0438-1157.20191307. DOI：

HU Bingbing, YANG Shu, LI Yan, XU Chuanlan, CHEN Peng, YU Jingjing, YU Danmei, CHEN Changguo. Construction of free binder V₂O₅ and Fe₂O₃ flexible electrode and its application in supercapacitor[J]. CIESC Journal, 2020, 71(10): 4836-4846 DOI: 10.11949/0438-1157.20191307. DOI：

摘要

近年来，越来越多的研究致力于开发新型、超高能量密度、高法拉第反应活性的电极材料，尤其将其应用于新一代超级电容器储能系统。通过水热法直接在柔性基质碳布上生长海胆状V

纳米球和十四面体Fe

纳米盒子。V

微观结构和储能性能可通过改变水热时间进行调控。海胆状V

纳米球正极材料具有最高比容量535 F·g

-1

。以十四面体Fe

纳米盒子作为负极材料组装的新型结构V

-CC//Fe

-CC柔性超级电容器，在功率密度为699.49 W·kg

-1

时，能量密度可达46.06 W·h·kg

-1

。而且具有良好的机械柔韧性，在180°弯曲循环测试5000次，比容量保持率仍高达83.4%。研究为开发下一代超高能量密度、柔性电子器件提供了一种通用而有效的策略。

Abstract

In recent years

more and more research has been devoted to the development of new electrode materials with ultra-high energy density and high Faraday reaction activity

especially applying them to a new generation of supercapacitor energy storage systems. In this study

sea urchin-shaped V

nanospheres and tetrakaidecahedron Fe

nano boxes have been grown directly on flexible matrix carbon cloth by hydrothermal method. The hydrothermal time can control the microstructure of V

and the morphology determines the performance of energy storage

the positive electrode material of sea urchin-shaped V

nanosphere exhibits a maximum specific capacitance of 535 F·g

-1

. In addition

the tetrakaidecahedron Fe

nano box is used as the negative electrode

and a new structure V

//Fe

flexible supercapacitor is assembled. When the power density is 699.49 W·kg

-1

the energy density can reach 46.06 W·h·kg

-1

. Moreover

it also has good mechanical flexibility

and the specific capacity retention rate is still as high as 83.4% after 5000 times of 180° bending cycle tests. This work provides a general and effective strategy for developing the next generation flexible electronic devices with ultra-high energy density.

关键词

Keywords

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