Efficient SO<sub>2</sub> capture by ether-containing anion-functionalized ionic liquids

XIAO Qiaoxin; LIN Wenjun; LI Haoran; WANG Congmin

doi:10.11949/0438-1157.20191261

您当前的位置：

首页 >

文章列表页 >

Efficient SO₂ capture by ether-containing anion-functionalized ionic liquids

Energy and environmental engineering | 更新时间：2026-07-24

- Efficient SO₂ capture by ether-containing anion-functionalized ionic liquids
- CIESC Journal Vol. 71, Issue 1, Pages: 361-367(2020)
- 作者机构：
  
  浙江大学化学系，浙江杭州 310029
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20191261
  CLC： TQ 013.1
- Received：23 October 2019，
  
  Revised：2019-11-20，
  
  Online First：12 August 2020，
  
  Published：05 January 2020
- 稿件说明：
移动端阅览
肖俏欣, 林文俊, 李浩然, 王从敏. 含醚阴离子功能化离子液体高效捕集SO₂[J]. 化工学报, 2020, 71(1): 361-367 DOI: 10.11949/0438-1157.20191261.

XIAO Qiaoxin, LIN Wenjun, LI Haoran, WANG Congmin. Efficient SO₂ capture by ether-containing anion-functionalized ionic liquids[J]. CIESC Journal, 2020, 71(1): 361-367 DOI: 10.11949/0438-1157.20191261.
肖俏欣, 林文俊, 李浩然, 王从敏. 含醚阴离子功能化离子液体高效捕集SO₂[J]. 化工学报, 2020, 71(1): 361-367 DOI: 10.11949/0438-1157.20191261. DOI：

XIAO Qiaoxin, LIN Wenjun, LI Haoran, WANG Congmin. Efficient SO₂ capture by ether-containing anion-functionalized ionic liquids[J]. CIESC Journal, 2020, 71(1): 361-367 DOI: 10.11949/0438-1157.20191261. DOI：

摘要

发展高效、经济、绿色的SO

吸收剂不但具有较强的学术价值，而且有良好的应用前景。设计并制备了一系列含醚的阴离子功能化离子液体，系统地研究了阴离子上引入醚基团对离子液体SO

吸收容量的影响。结果表明，在阴离子的苯环上引入甲氧基，对离子液体的吸收容量有明显提升。当阳离子为摩尔质量更小的三丁基乙基磷[P

4442

]

时，所得离子液体的吸收容量没有明显下降，20℃、10

Pa SO

下，[P

4442

]

[2-CH

OPhCOO

]

有效吸收量为每摩尔离子液体吸收3.32 mol SO

，有效质量吸收量是每克离子液体吸收0.56 g SO

。六次吸收解吸循环，表明[P

4442

]

[2-CH

OPhCOO

]

可以高效可逆地捕集SO

。基于含醚阴离子功能化离子液体的加强效应进行气体捕集的方法，可进一步应用于分离、催化等领域。

Abstract

The development of high efficient

economic and green SO

absorbers not only has a strong academic value

but also has a good application prospect. Herein

a series of ether-containing anion-functionalized ionic liquids were designed and prepared. The effect of ether on SO

absorption was investigated. The results indicated that SO

capacity increased significantly when ether was introduced on the anion. Furthermore

absorption capacity of SO

did not decrease obviously when the cation with a smaller molar mass tributyl ethyl phosphorus [P

4442

]

was used. The effective absorption capacity of [P

4442

]

[2-CH

OPhCOO

]

was 3.32 mol SO

per 1 mol IL at 20℃ and 10

with the effective mass absorption of 0.56 g SO

per 1 g IL. The cycles of six absorption and desorption showed that SO

capture by [P

4442

]

[2-CH

OPhCOO

]

was efficient and reversible. The method introducing ether to improve gas capture may be useful for other fields such as separation

catalyst and so on.

关键词

Keywords

references

Wu W , Han B , Gao H , et al . Desulfurization of flue gas: SO 2 absorption by an ionic liquid [J ] . Angew . Chem . Int . Ed . , 2004 , 43 : 2415 - 2417 .

Nickolay A K , Chris A M , Li C , et al . Streets aura OMI observations of regional SO 2 and NO 2 pollution changes from 2005 to 2015 [J ] . Atmos. Chem. Phys ., 2016 , 16 : 4605 - 4629 .

Bao J , Yang X , Zhao Z , et al . The spatial-temporal characteristics of air pollution in China from 2001—2014 [J ] . Int . J . Environ . Res . Public Health , 2015 , 12 : 15875-15887 .

Hu H , Yang Q , Lu X , et al . Air pollution and control in different areas of China [J ] . Critical Reviews in Environmental Science and Technology , 2010 , 40 ( 6 ): 452 - 518 .

Ma X , Takao K , Tsutomu T , et al . Use of limestone for SO 2 removal from flue gas in the semidry FGD process with a powder-particle spouted bed [J ] . Chemical Engineering Science , 2000 , 55 : 4643 - 4652 .

Tilly J . Flue gas desulfurization: cost and functional analysis of large scale proven plants [D ] . Massachusetts : Massachusetts Institute of Technology , 1983 .

Hirofumi K , Takanori N , Masanori M , et al . New wet FGD process using granular limestone [J ] . Ind . Eng . Chem . Res . , 2002 , 41 ( 12 ): 3028 - 3036 .

Han D H , Sohn H Y . Calcined calcium magnesium acetate as a superior SO 2 sorbent (Ⅰ): Thermal decomposition [J ] . AIChE J ., 2002 , 48 : 2971 - 2977 .

Sohn H Y , Han D H . Ca-Mg acetate as dry SO 2 sorbent (Ⅱ): Sulfation of CaO in calcination product [J ] . AIChE J . , 2002 , 48 : 2978 - 2984 .

Sohn H Y , Han D H . Ca-Mg acetate as dry SO 2 sorbent(Ⅲ): Sulfation of MgO + CaO [J ] . AIChE J . , 2002 , 48 : 2985 - 2991 .

Blanchard L A , Hancu D , Beckman E J , et al . Green processing using ionic liquids and CO 2 [J ] . Nature , 1999 , 399 ( 6731 ): 28 - 29 .

Bausach M , Pera-Titus M , Fite C , et al . Kinetic modeling of the reaction between hydrated lime and SO 2 at low temperature [J ] . AIChE J ., 2005 , 51 : 1455 - 1466 .

Zhao T , Hu X , Wu D , et al . Direct synthesis of dimethyl carbonate from carbon dioxide and methanol at room temperature using imidazolium hydrogen carbonate ionic liquid as a recyclable catalyst and dehydrant [J ] . ChemSusChem , 2017 , 10 : 2046 - 2052 .

Xu Y . CO 2 absorption behavior of azole-based protic ionic liquids: influence of the alkalinity and physicochemical properties [J ] . Journal of CO 2 Utilization , 2017 , 19 : 1 - 8 .

Liu X , Gao B , Deng D . SO 2 absorption/desorption performance of renewable phenol-based deep eutectic solvents [J ] . Separation Science and Technology , 2018 , 53 ( 14 ): 2150 - 2158 .

Gurkan B E , De la fuente J C , Mindrup E M , et al . Equimolar CO 2 absorption by anion-functionalized ionic liquids [J ] . J. Am. Chem. Soc ., 2010 , 132 : 2116 - 2117 .

Joan F B , Burcu E G . Ionic liquids for CO 2 capture and emission reduction [J ] . J. Phys. Chem. Lett ., 2010 , 1 ( 24 ): 3459 - 3464 .

Brett F G , Juan C F , Burcu E G , et al . Experimental measurements of amine-functionalized anion-tethered ionic liquids with carbon dioxide [J ] . Ind. Eng. Chem. Res ., 2011 , 50 : 111 - 118 .

Goodrich B F , de la Fuente J C , Gurkan B E , et al . Effect of water and temperature on absorption of CO 2 by amine-functionalized anion-tethered ionic liquids [J ] . J. Phys. Chem. B , 2011 , 115 : 9140 - 9150 .

Lin W , Zhou X , Cai J , et al . Anion-functionalized pillararenes for efficient sulfur dioxide capture: significant effect of the anion and the cavity [J ] . Chem. Eur. J ., 2017 , 23 : 14143-14148 .

Huang K , Zhang X , Hu X , et al . Hydrophobic protic ionic liquids tethered with tertiary amine group for highly efficient and selective absorption of H 2 S from CO 2 [J ] . AIChE J ., 2016 , 62 ( 12 ): 4480 - 4490 .

Eleanor D B , Rebecca D M , Ioanna N , et al . CO 2 capture by a task-specific ionic liquid [J ] . J. Am. Chem. Soc . , 2002 , 124 ( 6 ): 926 - 927 .

Kenta F , Masahiro Y , Hiroyuki O . Room temperature ionic liquids from 20 natural amino acids [J ] . J. Am. Chem. Soc . , 2005 , 127 ( 8 ): 2398 - 2399 .

Shiflett M B , Yokozeki A . Chemical absorption of sulfur dioxide in room-temperature ionic liquids [J ] . Ind. Eng. Chem. Res ., 2010 , 49 ( 3 ): 1370 - 1377 .

Lin W , Cai Z , Lv X , et al . Significantly enhanced carbon dioxide capture by anion-functionalized liquid pillar[5]arene through multiple-site interactions [J ] . Ind. Eng. Chem. Res ., 2019 , 58 : 16894-16900 .

Gurkan B , Goodrich B F , Mindrup E M , et al . Molecular design of high capacity, low viscosity, chemically tunable ionic liquids for CO 2 capture [J ] . J. Phys. Chem. Lett ., 2010 , 1 ( 24 ): 3494 - 3499 .

Wang C , Luo H , Li H , et al . Tuning the physicochemical properties of diverse phenolic ionic liquids for equimolar CO 2 capture by the substituent on the anion [J ] . Chem. Eur. J . , 2012 , 18 : 2153 - 2160 .

Zhang Y Q , Zhang S J , Lu X M , et al . Dual amino-functionalised phosphonium ionic liquids for CO 2 capture [J ] . Chem. Eur. J ., 2009 , 15 : 3003 - 3011 .

Lin W , Pan M , Xiao Q , et al . Tuning the capture of CO 2 through entropic effect induced by reversible trans-cis isomerization of light-responsive ionic liquids [J ] . J. Phys. Chem. Lett . , 2019 , 10 : 3346 - 3351 .

Jiang Y , Liu X , Deng D . Absorption of SO 2 in fuloroate ionic liquids/PEG200 mixtures and thermodynamic analysis [J ] . J. Chem. Eng. Data , 2018 , 63 : 259 - 268 .

Stewart A F , Jennifer M P , Douglas R M . Ionic liquids—an overview [J ] . Aust . J . Chem ., 2004 , 57 : 113 .

Wang C , Luo X , Luo X , et al . Tuning the basicity of ionic liquids for equimolar CO 2 capture [J ] . Angew . Chem ., 2011 , 123 : 5020 .

Craig M T , Dai S , Jiang D . Computational investigation of reactive to nonreactive capture of carbon dioxide by oxygen-containing Lewis bases [J ] . J . Phys . Chem . A, 2 010 , 114 : 11761 .

Cui G , Zheng J , Luo X , et al . Tuning anion-functionalized ion ic liquids for improved SO 2 capture [J ] . Angew . Chem . , 2013 , 125 : 10814-10818 .

Cui G , Wang C , Zheng J , et al . Highly efficient SO 2 capture by dual functionalized ionic liquids through a combination of chemical and physical absorption [J ] . Chem. Commun ., 2012 , 48 : 2633 - 2635 .

Chen K , Lin W , Yu X , et al . Designing of anion-functionalized ionic liquids for efficient capture of SO 2 from flue gas [J ] . AIChE J ., 2015 , 61 : 2028 - 2034 .

Cui G , Zheng J , Luo X , et al . Tuning anion-functionalized ionic liquids for improved SO 2 capture [J ] . Angew . Chem . , 2013 , 125 : 10814-10818 .

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Advances in silicon-based ionic liquid microparticle enhanced gas capture and conversion

Research progress of ionic liquids in separation of aromatics/alkanes and olefins/alkanes

Preparation of ZIF-8 based porous liquid and its SO2 adsorption performance

Study on dissolution of cellulose by [Emim]Ac-[Emim]OH-DMSO ternary system

Mechanism and regulation of supercooling behavior in imidazolium-based ionic liquids

Related Author

CHEN Meisi

CHEN Weida

LI Xinyao

LI Shangyu

WU Youting

ZHANG Feng

ZHANG Zhibing

WU Youting

Related Institution

School of Chemistry and Chemical Engineering, Nanjing University

State Key Laboratory of Heavy Oil Processing, China University of Petroleum

School of Chemistry and Chemical Engineering, Xi’an University of Architecture and Technology

Key Laboratory of Green Development and Utilization of Nonferrous Metal Resources in Shaanxi Province

College of Materials Engineering, Fujian Agriculture and Forestry University

⁰

Efficient SO2 capture by ether-containing anion-functionalized ionic liquids

DOI：10.11949/0438-1157.20191261

摘要

Abstract

关键词

Keywords

references

Efficient SO₂ capture by ether-containing anion-functionalized ionic liquids