Preparation of O<sub>3</sub> by O<sub>2</sub> DBD microplasma

WANG Baowei; SU Huijuan; YAO Shumei

doi:10.11949/0438-1157.20191068

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Preparation of O₃ by O₂ DBD microplasma

Energy and environmental engineering | 更新时间：2026-07-24

- Preparation of O₃ by O₂ DBD microplasma
- CIESC Journal Vol. 71, Issue 2, Pages: 746-754(2020)
- 作者机构：
  
  天津大学化工学院, 绿色合成与转化教育部重点实验室, 天津 300072
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20191068
  CLC： TQ 123.2
- Received：23 September 2019，
  
  Revised：2019-11-28，
  
  Online First：14 August 2020，
  
  Published：05 February 2020
- 稿件说明：
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王保伟, 苏会娟, 姚淑美. O₂介质阻挡放电微等离子体制备O₃[J]. 化工学报, 2020, 71(2): 746-754 DOI: 10.11949/0438-1157.20191068.

WANG Baowei, SU Huijuan, YAO Shumei. Preparation of O₃ by O₂ DBD microplasma[J]. CIESC Journal, 2020, 71(2): 746-754 DOI: 10.11949/0438-1157.20191068.
王保伟, 苏会娟, 姚淑美. O₂介质阻挡放电微等离子体制备O₃[J]. 化工学报, 2020, 71(2): 746-754 DOI: 10.11949/0438-1157.20191068. DOI：

WANG Baowei, SU Huijuan, YAO Shumei. Preparation of O₃ by O₂ DBD microplasma[J]. CIESC Journal, 2020, 71(2): 746-754 DOI: 10.11949/0438-1157.20191068. DOI：

摘要

介质阻挡放电(DBD)是工业生产臭氧(O

)最有效的方法。研究以O

为原料气采用DBD微等离子体放电制备O

，研究了放电间距、放电长度、放电功率以及停留时间对产生O

的影响。此外，通过向正弦AC等离子体电源中叠加调制脉冲，探讨了脉冲占空比与调制频率对O

生成的影响。结果表明：O

浓度与DBD反应器的放电间距呈负相关，与O

的停留时间呈正相关，放电功率及有效放电长度对O

浓度的影响呈现火山形变化趋势。综合考虑O

浓度及能量产率确定了适宜的参数。与普通正弦交流电源相比，在其基础上叠加脉冲调制电源有利于O

的产生，而能量产率与占空比呈正相关，与调制频率呈负相关，据此确定了合适的占空比与调制频率。

Abstract

Dielectric barrier discharge (DBD) is considered to be the most efficient method for industrial production of ozone (O

). O

was prepared by using DBD microplasma discharge with O

as the raw material gas. The effects of the discharge interval

discharge length

discharge power and residence time on the production of O

were studied. In addition

the modulated pulse was added to the sinusoidal AC power supply

and studied the effect of pulse duty cycle and modulation frequency. The results showed that the concentration of O

decreased with the increase of discharge length

while the energy efficiency increased first and then decreased. At the discharge length of 0.75 mm

both were in a higher range. Excessive or too small discharge length was not conducive to

the formation of O

. The suitable discharge length was 80－90 mm. With the increase of discharge power

the concentration of O

rose first and then decreased

and the energy efficiency decreased almost linearly.The residence time of O

was positively correlated with the concentration of O

and negatively correlated with energy efficiency. The optimal discharge power was (6.7 ± 0.2) W

and the appropriate residence time was 1.0—1.4 s. It was found that the superposition of pulse modulation power supply on the basis of common sinusoidal alternating current is beneficial to the generation of O

and the energy efficiency decreased with the increase of the duty cycle

increased with the enhancement of the modulation frequency. The appropriate duty cycle and modulation frequency was 60%

800 Hz

respectively.

关键词

Keywords

references

王保伟 , 姚淑美 , 彭叶平 . 介质阻挡等离子体制备臭氧研究进展 [J ] . 现代化工 , 2018 , 38 ( 7 ): 31 - 35 .

Wang B W , Yao S M , Peng Y P . Progress on preparation of ozone by dielectric barrier plasma [J ] . Modern Chemical Industry , 2018 , 38 ( 7 ): 31 - 35 .

Nassour K , Brahami M , Nemmich S , et al . Comparative experimental study between surface and volume DBD ozone generator [J ] . Ozone: Science & Engineering , 2015 , 38 : 70 - 76 .

Jenei I , Kis P , Kiss E . The development of ozone generators with the analysis of the field distribution of the electrode arrangements [J ] . Ozone: Science & Engineering , 2007 , 29 : 215 - 220 .

Zhang X , Lee B J , Hong G I , et al . Ozone production with dielectric barrier discharge-effects of power source and humidity [J ] . IEEE Transactions on Plasma Science , 2016 , 44 ( 10 ): 2288 - 2296 .

Wei L S . Dong G P, Zhang Y F, et al . Effect of SF 6 on ozone generation using dielectric barrier discharge [J ] . High Voltage Engineering , 2013 , 39 ( 10 ): 2520 - 2525 .

魏林生 . 等离子体臭氧产生的实验与理论研究 [D ] . 杭州 : 浙江大学 , 2008 .

Wei L S . Theoretical and experimental research on ozone generation by gas discharge plasma [D ] . Hangzhou : Zhejiang University , 2008 .

Wei L S , Yuan D , Zhang Y , et al . An analysis of the effect of inert gases on ozone generation using dielectric barrier discharge in oxygen [J ] . The European Physical Journal D , 2014 , 68 ( 1 ): 17 .

Wei L S , Yuan D , Zhang Y , et al . The effect of inert gases on ozone generation using dielectric barrier discharge in dry air [J ] . Ozone: Science & Engineering , 2013 , 35 ( 6 ): 448 - 455 .

Chen H L , Lee H M , Chen S H , et al . Influence of Ar addition on ozone generation in nonthermal plasmas [J ] . Plasma Sources Science and Technology , 2010 , 19 ( 6 ): 692 - 701 .

Pekárek S . Asymmetric properties and ozone production of surface dielectric barrier discharge with different electrode configurations [J ] . The European Physical Journal D , 2013 , 67 ( 5 ): 94 .

Nassour K , Brahami M , Nemmich S , et al . New hybrid surface-volume dielectric barrier discharge reactor for ozone generation [J ] . IEEE Transactions on Industry Applications , 2017 , 53 ( 3 ): 2477 - 2484 .

Malik M A , Schoenbach K H , Heller R . Coupled surface dielectric barrier discharge reactor-ozone synthesis and nitric oxide conversion from air [J ] . Chemical Engineering Journal , 2014 , 256 : 222 - 229 .

Chebbah A , Hadjeri S , Nemmich S , et al . Development and experimental analysis of a new “serpentine-shape” surface-DBD ozone generator — comparison with a cylindrical volume-DBD ozone generator [J ] . Ozone: Science & Engineering , 2017 , 39 ( 3 ): 209 - 216 .

Andreev V V , Pichugin Y P , Telegin V G , et al . Combined barrier discharge in atmospheric-pressure air [J ] . Plasma Physics Reports , 2012 , 38 ( 13 ): 1046 - 1049 .

Jodpimai S , Boonduang S , Limsuwan P . Dielectric barrier discharge ozone generator using aluminum granules electrodes [J ] . Journal of Electrostatics , 2015 , 74 : 108 - 114 .

Gnapowski S , Yamabe C , Ihara S . Ozone generation characteristics of ozonizer with the rotating type electrode [J ] . IEEJ Transactions on Fundamentals and Materials , 2008 , 128 ( 10 ): 619 - 623 .

Zhang Z , Bai X , Bai M , et al . An ozone generator of miniaturization and modularization with the narrow discharge gap [J ] . Plasma Chemistry and Plasma Processing , 2003 , 23 ( 3 ): 559 - 568 .

商克峰 , 曹晓萌 , 王肖静 , 等 . 高压电极构型对DBD装置放电特性及臭氧生成的影响 [J ] . 高电压技术 , 2016 , 42 ( 5 ): 1394 - 1400 .

Shang K F , Cao X M , Wang X J , et al . Effect of high voltage electrode geometry on the discharge characteristics and the ozone generation of a DBD device [J ] . High Voltage Engineering , 2016 , 42 ( 5 ): 1394 - 1400 .

杨春 , 胡兆吉 , 魏林生 . 放电等离子体臭氧发生技术研究现状与进展 [J ] . 高压电器 , 2010 , 46 : 78 - 85 .

Yang C , Hu Z J , Wei L S . The research development of plasma discharge synthesis technology of ozone [J ] . High Voltage Apparatus , 2010 , 46 : 78 - 85 .

周立福 , 杨学昌 , 陈波 , 等 . 臭氧发生器用高介电硅橡胶复合材料特性及试验分析 [J ] . 高电压技术 , 2010 , 36 : 1258 - 1263 .

Zhou L F , Yang X C , Chen B , et al . Characteristics and experimental analysis of High-K MVQ functional composites for ozonizer [J ] . High Voltage Engineering , 2010 , 36 : 1258 - 1263 .

陈波 , 杨学昌 , 陶顺忠 . 等离子喷涂介质层提升臭氧发生器性能的试验研究 [J ] . 高电压技术 , 2013 , 39 : 1703 - 1709 .

Chen B , Yang X C , Tao S Z . Experimental study on plasma sprayed dielectric layer to improve ozone performance [J ] . High Voltage Engineering , 2013 , 39 : 1703 - 1709 .

王健 . 催化剂耦合介质阻挡放电制取臭氧的试验和模型研究 [D ] . 合肥 : 中国科学技术大学 , 2009 .

Wang J . Experimental and model study of ozone production via DBDs coupling with catalyst [D ] . Hefei : University of Science and Technology of China , 2009 .

Pekarek S , Mikes J , Pelikanova I B , et al . Effect of TiO 2 on various regions of active electrode on surface dielectric barrier discharge in air [J ] . Plasma Chemistry and Plasma Processing , 2016 , 36 ( 5 ): 1187 - 1200 .

Pekárek S . Experimental study of surface dielectric barrier discharge in air and its ozone production [J ] . Journal of Physics D: Applied Physics , 2012 , 45 ( 7 ): 075201 .

Huang W , Ren T , Xia W . Ozone generation by hybrid discharge combined with catalysis [J ] . Ozone: Science & Engineering , 2007 , 29 ( 2 ): 107 - 112 .

Dwivedi C , Toley M A , Dey G R , et al . Ozone generation from argon-oxygen mixtures in presence of different packing materials within dielectric barrier discharge gap [J ] . Ozone: Science & Engineering , 2013 , 35 ( 2 ): 134 - 145 .

Phelps database [ EB/OL ] . 2018-06-04, https: //fr. lxcat . net/data/set_type.php .

Yagi S , Kuzumoto M . Silent discharges in ozonisers and CO 2 lasers [J ] . Australian Journal of Physics , 1995 , 48 : 411 - 418 .

Homola T , Pongrác B , Zemánek M , et al . Efficiency of ozone production in coplanar dielectric barrier discharge [J ] . Plasma Chemistry and Plasma Processing , 2019 , 39 : 1227 - 1242 .

邵涛 , 严萍 . 大气压气体放电及其等离子体应用 [M ] . 北京 : 科学出版社 , 2015 .

Shao T , Yan P . Atmospheric Pressure Gas Discharge and Its Plasma Application [M ] . Beijing : Science Press , 2015 .

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⁰

Preparation of O3 by O2 DBD microplasma

DOI：10.11949/0438-1157.20191068

摘要

Abstract

关键词

Keywords

references

Preparation of O₃ by O₂ DBD microplasma