Preparation of composite nanofiltration membrane with β-cyclodextrin as aqueous monomer and dye rejection properties

LIU Lixue; ZHANG Shaofeng; ZHAO Changwei; BAOLE Erhu; YU Ling; WANG Jun

doi:10.11949/0438-1157.20190919

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Preparation of composite nanofiltration membrane with β-cyclodextrin as aqueous monomer and dye rejection properties

Material science and engineering\, nanotechnology | 更新时间：2026-07-24

- Preparation of composite nanofiltration membrane with β-cyclodextrin as aqueous monomer and dye rejection properties
- CIESC Journal Vol. 71, Issue 2, Pages: 889-898(2020)
- 作者机构：
  
  1. 河北工业大学化工学院，天津 300130
  2. 中国科学院生态环境研究中心，环境水质学国家重点实验室，北京 100085
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20190919
  CLC： TQ 028.8
- Received：12 August 2019，
  
  Revised：2019-12-12，
  
  Online First：14 August 2020，
  
  Published：05 February 2020
- 稿件说明：
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刘丽雪, 张少峰, 赵长伟, 宝乐尔呼, 俞灵, 王军. β-环糊精为水相单体的复合纳滤膜制备及染料截留性能[J]. 化工学报, 2020, 71(2): 889-898

LIU Lixue, ZHANG Shaofeng, ZHAO Changwei, BAOLE Erhu, YU Ling, WANG Jun. Preparation of composite nanofiltration membrane with β-cyclodextrin as aqueous monomer and dye rejection properties[J]. CIESC Journal, 2020, 71(2): 889-898
刘丽雪, 张少峰, 赵长伟, 宝乐尔呼, 俞灵, 王军. β-环糊精为水相单体的复合纳滤膜制备及染料截留性能[J]. 化工学报, 2020, 71(2): 889-898 DOI： 10.11949/0438-1157.20190919.

LIU Lixue, ZHANG Shaofeng, ZHAO Changwei, BAOLE Erhu, YU Ling, WANG Jun. Preparation of composite nanofiltration membrane with β-cyclodextrin as aqueous monomer and dye rejection properties[J]. CIESC Journal, 2020, 71(2): 889-898 DOI： 10.11949/0438-1157.20190919.

摘要

采用β-环糊精(β-CD)作为水相单体，均苯三甲酰氯(TMC)为油相单体，通过界面聚合法制备高通量的β-CD/TMC复合纳滤膜，利用细孔模型和静电排斥-立体位阻模型探究染料分离机理。采用红外光谱仪、场发射电子显微镜、接触角测量仪及Zeta电位分析仪进行分析表征。结果表明，红外光谱中出现了酯基官能团的特征峰；Zeta电位分析表明所制备的复合纳滤膜表面荷负电；SEM图像结构和接触角数值表明β-CD浓度为4.0%时，膜表面出现大量褶皱，膜的亲水性更好，0.2 MPa压力下，纯水通量可达207.81 L·m

-2

·h

-1

，对染料刚果红(CR)、孟加拉玫瑰红(RB)、活性艳红X-3B、亚甲基蓝(MB)的截留率分别为100%、99.05%、97.65%、32.92%；6 h连续运行实验，通量呈现先下降后稳定的趋势，对染料活性艳红X-3B的截留率始终高于97%。

Abstract

Using β-cyclodextrin (β-CD) as the aqueous phase monomer and trimesyl chloride (TMC) as the oil phase monomer

a high-throughput β-CD/TMC composite nanofiltration membrane was prepared by the interfacial polymerization method. The pore model and electrostatic repulsion-steric hindrance model were used to explore the mechanism of dye separation. Infrared spectrometer

field emission electron microscope

contact angle measuring instrument and Zeta potential analyzer were used for analysis and characterization. The results showed that the peak of ester group which is generated by IP appeared in the FT-IR. Zeta potential analysis indicated that the surface of composite NF membrane was negatively charged. SEM images structure and contact angle values showed that when the concentration of β-CD was 4.0%

a lot of folds appeared on the membrane surface and the membrane was more hydrophilic. At the pressure of 0.2 MPa

the pure water flux can reach 207.81 L·m

-2

·h

-1

the rejection of the Congo red

the Bengal rose

the reactive brilliant red X-3B and the methylene blue was 100%

99.05%

97.65% and 32.92%

respectively. Th

e 6 h operation can effectively reject the dye reactive brilliant red X-3B with rejection higher than 97% flux goes down and then keeps the tendency of stable.

关键词

Keywords

references

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