Study on catalytic reforming of tar at low temperature to produce hydrogen-rich gas by tire pyrolysis char

YANG Diancai; PAN Yuhan; HUANG Qunxing; JIANG Xuguang; WANG Fei; YAN Jianhua

doi:10.11949/0438-1157.20190831

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Study on catalytic reforming of tar at low temperature to produce hydrogen-rich gas by tire pyrolysis char

Catalysis\, kinetics and reactors | 更新时间：2026-07-24

- Study on catalytic reforming of tar at low temperature to produce hydrogen-rich gas by tire pyrolysis char
- CIESC Journal Vol. 71, Issue 2, Pages: 642-650(2020)
- 作者机构：
  
  1.浙江大学热能工程研究所，能源清洁利用国家重点实验室，浙江杭州 310027
  2.青岛万龙高新科技集团有限公司，山东青岛 266000
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20190831
  CLC： TE 992.3
- Received：22 July 2019，
  
  Revised：2019-09-09，
  
  Online First：14 August 2020，
  
  Published：05 February 2020
- 稿件说明：
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杨殿才, 潘宇涵, 黄群星, 蒋旭光, 王飞, 严建华. 废轮胎热解炭低温催化焦油重整制备富氢气体的研究[J]. 化工学报, 2020, 71(2): 642-650

YANG Diancai, PAN Yuhan, HUANG Qunxing, JIANG Xuguang, WANG Fei, YAN Jianhua. Study on catalytic reforming of tar at low temperature to produce hydrogen-rich gas by tire pyrolysis char[J]. CIESC Journal, 2020, 71(2): 642-650
杨殿才, 潘宇涵, 黄群星, 蒋旭光, 王飞, 严建华. 废轮胎热解炭低温催化焦油重整制备富氢气体的研究[J]. 化工学报, 2020, 71(2): 642-650 DOI： 10.11949/0438-1157.20190831.

YANG Diancai, PAN Yuhan, HUANG Qunxing, JIANG Xuguang, WANG Fei, YAN Jianhua. Study on catalytic reforming of tar at low temperature to produce hydrogen-rich gas by tire pyrolysis char[J]. CIESC Journal, 2020, 71(2): 642-650 DOI： 10.11949/0438-1157.20190831.

摘要

以全钢型废旧轮胎为原料，通过热解、活化、浸渍、焙烧的流程制备了三种热解炭催化剂，分别为轮胎热解炭（Raw char）、轮胎热解活性炭（AC）和负载Zn的活性炭（Zn/AC）。采用N

吸/脱附、SEM、EDS、XRD等表征方法对催化剂进行了一系列表征和分析，发现CO

O活化可显著提高催化剂BET比表面积，最高可达380 m

·g

-1

，有效改善催化剂表面结构性质，同时浸渍法使催化剂表面负载大量ZnO活性位。对三种催化剂在纤维素热解焦油重整制氢过程中的催化性能进行了研究，发现Raw char（600℃）具有最佳催化效果，相较于空白组（500℃），热解气中H

体积分数提高了12.4%，达到19.3%，其次为Zn/AC（500℃）组的17.8%，实现了低温下催化纤维素焦油热解制得高产率H

。

Abstract

Three pyrolysis carbon catalysts were prepared by pyrolysis

activation

impregnation and calcination using all-steel waste tires as raw materials

namely Raw char

raw pyrolytic activated carbon (AC) and Zn modified activated carbon (Zn/AC). The catalysts were characterized by N

adsorption/desorption

SEM

EDS

XRD and other characterization methods. It was found that CO

O activation significantly increase the BET specific surface area of the catalyst up to 380 m

·g

-1

effectively improving the surface structure of the catalyst. Meanwhile

a large number of ZnO was loaded onto the surface by impregnation method. The catalytic performance of three catalysts was studied in the process of cellulose pyrolysis tar reforming to produce hydrogen. Results indicated that Raw char (600℃) has the best catalytic effect compared with the blank group (500℃). The volume fraction of H

in gas production increased by 12.4% to 19.3%

followed by 17.8% of the Zn/AC (500℃) group

which achieved high yield of H

by catalyzing cellulose tar at low temperatures.

关键词

Keywords

references

Chintala V . Production, upgradation and utilization of solar assisted pyrolysis fuels from biomass — a technical review [J ] . Renewable and Sustainable Energy Reviews , 2018 , 90 : 120 - 130 .

Sutton D , Kelleher B , Ross J R H . Review of literature on catalysts for biomass gasification [J ] . Fuel Processing Technology , 2001 , 73 ( 3 ): 155 - 173 .

McKendry P . Energy production from biomass (part 1): Overview of biomass [J ] . Bioresource Technology , 2002 , 83 ( 1 ): 37 - 46 .

Salam M A , Ahmed K , Akter N , et al . A review of hydrogen production via biomass gasification and its prospect in Bangladesh [J ] . International Journal of Hydrogen Energy , 2018 , 43 ( 32 ): 14944 - 14973 .

Abu El-Rub Z , Bramer E A , Brem G . Review of catalysts for tar elimination in biomass gasification processes [J ] . Industrial & Engineering Chemistry Research , 2004 , 43 ( 22 ): 6911 - 6919 .

Bridgwater A V . The technical and economic feasibility of biomass gasification for power generation [J ] . Fuel , 1995 , 74 ( 5 ): 631 - 653 .

Arregi A , Amutio M , Lopez G , et al . Evaluation of thermochemical routes for hydrogen production from biomass: a review [J ] . Energy Conversion and Management , 2018 , 165 : 696 - 719 .

Guan G , Kaewpanha M , Hao X , et al . Catalytic steam reforming of biomass tar: prospects and challenges [J ] . Renewable and Sustainable Energy Reviews , 2016 , 58 : 450 - 461 .

Hamad M A , Radwan A M , Heggo D A , et al . Hydrogen rich gas production from catalytic gasification of biomass [J ] . Renewable Energy , 2016 , 85 : 1290 - 1300 .

Machin E B , Pedroso D T , de Carvalho J A . Energetic valorization of waste tires [J ] . Renewable and Sustainable Energy Reviews , 2017 , 68 : 306 - 315 .

胡国华 , 张一帆 , 张立群 . 废橡胶裂解研究进展 [J ] . 高分子通报 , 2017 , ( 12 ): 1 - 13 .

Hu G H , Zhang Y F , Zhang L Q . Research progress on waste rubber cracking [J ] . Polymer Notification , 2017 , ( 12 ): 1 - 13 .

Martínez J D , Puy N , Murillo R , et al . Waste tyre pyrolysis — a review [J ] . Renewable and Sustainable Energy Reviews , 2013 , 23 : 179 - 213 .

Min Z , Yimsiri P , Asadullah M , et al . Catalytic reforming of tar during gasification (Part II): Char as a catalyst or as a catalyst support for tar reforming [J ] . Fuel , 2011 , 90 ( 7 ): 2545 - 2552 .

史训旺 , 李建芬 , 辛馨 , 等 . 轮胎热解焦镍催化剂的制备及在秸秆热解燃气重整中的应用 [J ] . 化学工程师 , 2018 , 32 ( 1 ): 1 - 6 .

Shi X W , Li J F , Xin X , et al . Preparation of tire pyrolysis coking nickel catalyst and its application in straw pyrolysis gas reforming [J ] . Chemical Engineer , 2018 , 32 ( 1 ): 1 - 6 .

Hu M , Laghari M , Cui B , et al . Catalytic cracking of biomass tar over char supported nickel catalyst [J ] . Energy , 2018 , 145 : 228 - 237 .

Al-Rahbi A S , Williams P T . Hydrogen-rich syngas production and tar removal from biomass gasification using sacrificial tyre pyrolysis char [J ] . Applied Energy , 2017 , 190 : 501 - 509 .

Raveendran K , Ganesh A , Khilar K C . Influence of mineral matter on biomass pyrolysis characteristics [J ] . Fuel , 1995 , 74 ( 12 ): 1812 - 1822 .

Zhang Z , Liu L , Shen B , et al . Preparation, modification and development of Ni-based catalysts for catalytic reforming of tar produced from biomass gasification [J ] . Renewable and Sustainable Energy Reviews , 2018 , 94 : 1086 - 1109 .

Kannari N , Oyama Y , Takarada T . Catalytic decomposition of tar derived from biomass pyrolysis using Ni-loaded chicken dropping catalysts [J ] . International Journal of Hydrogen Energy , 2017 , 42 ( 15 ): 9611 - 9618 .

Han J , Li W , Liu D , et al . Pyrolysis characteristic and mechanism of waste tyre: a thermogravimetry-mass spectrometry analysis [J ] . Journal of Analytical and Applied Pyrolysis , 2018 , 129 : 1 - 5 .

Wang Y , Li X , Mourant D , et al . Formation of aromatic structures during the pyrolysis of bio-oil [J ] . Energy & Fuels , 2012 , 26 ( 1 ): 241 - 247 .

Sing K . The use of nitrogen adsorption for the characterisation of porous materials [J ] . Colloids and Surfaces A: Physicochemical and Engineering Aspects , 2001 , 187/188 : 3 - 9 .

Wang J , Sun C , Lin B C , et al . Micro- and mesoporous-enriched carbon materials prepared from a mixture of petroleum-derived oily sludge and biomass [J ] . Fuel Processing Technology , 2018 , 171 : 140 - 147 .

Lu P , Huang Q , Chi Y , et al . Preparation of high catalytic activity biochar from biomass waste for tar conversion [J ] . Journal of Analytical and Applied Pyrolysis , 2017 , 127 : 47 - 56 .

闫大海 . 废轮胎回转窑中试热解产物应用及热解机理和动力学模型研究 [D ] . 杭州 : 浙江大学 , 2006 .

Yan D H . Application of pyrolysis products and pyrolysis mechanism and kinetic model of waste tire rotary kiln [D ] . Hangzhou : Zhejiang University , 2006 .

Lu P , Qian X , Huang Q , et al . Catalytic cracking of toluene as a tar model compound using sewage-sludge-derived char [J ] . Energy & Fuels , 2016 , 30 ( 10 ): 8327 - 8334 .

陈志宏 . 我国轮胎行业的发展及对钴盐粘合剂的需求 [C ] // 第六届全国橡胶工业新材料技术论坛暨2006年橡胶助剂专业委员会会员大会论文集 . 浙江温州 , 2006 : 137 - 143 .

Chen Z H . The development of China s tire industry and the demand for cobalt salt binders [C ] // Proceedings of the 6th National Rubber Industry New Materials Technology Forum and the 2006 Rubber Additives Professional Committee . Wenzhou, Zhejiang , 2006 : 137 - 143 .

汤锌锌 , 黄正 . 过渡金属分子催化的烷烃转化进展 [J ] . 科学通报 , 2018 , 63 ( 14 ): 1349 - 1360+8 .

Tang X X , Huang Z . Transition metal molecule catalyzed alkane conversion progress [J ] . Chinese Science Bulletin , 2018 , 63 ( 14 ): 1349 - 1360+8 .

孙立 . 生物质热解制氢机理和实验研究 [D ] . 天津 : 天津大学 , 2008 .

Sun L . Hydrogen production mechanism and experimental study of biomass pyrolysis [D ] . Tianjin : Tianjin University , 2008 .

Yan F , Luo S Y , Hu Z Q , et al . Hydrogen-rich gas production by steam gasification of char from biomass fast pyrolysis in a fixed-bed reactor: Influence of temperature and steam on hydrogen yield and syngas composition [J ] . Bioresource Technology , 2010 , 101 ( 14 ): 5633 - 5637 .

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