Progress in pore size regulation of metal-organic frameworks

YUAN Ye; WANG Ming; ZHOU Yunqi; WANG Zhi; WANG Jixiao

doi:10.11949/0438-1157.20190801

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Progress in pore size regulation of metal-organic frameworks

Reviews and monographs | 更新时间：2026-07-24

- Progress in pore size regulation of metal-organic frameworks
- CIESC Journal Vol. 71, Issue 2, Pages: 429-450(2020)
- 作者机构：
  
  1. 天津大学化工学院化学工程研究所，天津市膜科学与海水淡化技术重点实验室，化学工程联合国家重点实验室（天津大学），天津化学化工协同创新中心，天津 300350
  2. 滨州学院化工与安全学院，山东省工业污水资源化工程技术研究中心，山东，滨州 256600
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20190801
  CLC： TQ 028.8
- Received：11 July 2019，
  
  Revised：2019-09-18，
  
  Online First：14 August 2020，
  
  Published：05 February 2020
- 稿件说明：
移动端阅览
原野, 王明, 周云琪, 王志, 王纪孝. 金属有机框架孔径调控进展[J]. 化工学报, 2020, 71(2): 429-450

YUAN Ye, WANG Ming, ZHOU Yunqi, WANG Zhi, WANG Jixiao. Progress in pore size regulation of metal-organic frameworks[J]. CIESC Journal, 2020, 71(2): 429-450
原野, 王明, 周云琪, 王志, 王纪孝. 金属有机框架孔径调控进展[J]. 化工学报, 2020, 71(2): 429-450 DOI： 10.11949/0438-1157.20190801.

YUAN Ye, WANG Ming, ZHOU Yunqi, WANG Zhi, WANG Jixiao. Progress in pore size regulation of metal-organic frameworks[J]. CIESC Journal, 2020, 71(2): 429-450 DOI： 10.11949/0438-1157.20190801.

摘要

金属有机框架(MOFs)以其可灵活调节的孔道结构、大孔隙率和大比表面积等特点受到广泛关注。设计并构建能够实现目标功能的、具有合适孔径分布的MOFs材料关系到MOFs材料在分离、催化以及质子传导等领域中的应用。综述了MOFs材料孔径的主要调控方法，包括原位合成调控、后合成修饰调控、穿插调控以及辅助合成调控，总结了四种调控方法的特点和不足，并对未来MOFs孔径调控的发展方向进行了展望。

Abstract

Metal-organic frameworks (MOFs) have attractecl wide attention due to their flexible pore structure

large porosity and specific surface area. Designing and constructing MOFs with suitable pore size distribution to achieve the desired function is related to the application of MOFs in the fields of separation

catalysis

proton conduction

etc

. In this paper

the main methods of regulating MOFs pore size are reviewed

including

situ

synthesis

post-synthesis modification

intercalation regulation and auxiliary synthesis. The characteristics and shortcomings of the four regulation methods are summarized

and the future direction of MOFs pore size regulation is also prospected.

关键词

Keywords

references

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