Simulation study on CO<sub>2</sub> capture from dry flue gas by temperature vacuum swing adsorption

JIANG Nan; LIU Bing; TANG Zhongli; ZHANG Donghui; LI Guobing

doi:10.11949/0438-1157.20190725

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Simulation study on CO₂ capture from dry flue gas by temperature vacuum swing adsorption

Energy and environmental engineering | 更新时间：2026-07-24

- Simulation study on CO₂ capture from dry flue gas by temperature vacuum swing adsorption
- CIESC Journal Vol. 70, Issue 10, Pages: 4032-4042(2019)
- 作者机构：
  
  天津大学化工学院化学工程研究所，化学工程联合国家重点实验室，天津 300350
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20190725
  CLC： TQ 028.1
- Received：26 June 2019，
  
  Revised：2019-07-31，
  
  Online First：24 July 2026，
  
  Published：05 October 2019
- 稿件说明：
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江南, 刘冰, 唐忠利, 张东辉, 李国兵. 真空变温吸附捕集干烟道气中CO₂的模拟研究[J]. 化工学报, 2019, 70(10): 4032-4042 DOI: 10.11949/0438-1157.20190725.

JIANG Nan, LIU Bing, TANG Zhongli, ZHANG Donghui, LI Guobing. Simulation study on CO₂ capture from dry flue gas by temperature vacuum swing adsorption[J]. CIESC Journal, 2019, 70(10): 4032-4042 DOI: 10.11949/0438-1157.20190725.
江南, 刘冰, 唐忠利, 张东辉, 李国兵. 真空变温吸附捕集干烟道气中CO₂的模拟研究[J]. 化工学报, 2019, 70(10): 4032-4042 DOI: 10.11949/0438-1157.20190725. DOI：

JIANG Nan, LIU Bing, TANG Zhongli, ZHANG Donghui, LI Guobing. Simulation study on CO₂ capture from dry flue gas by temperature vacuum swing adsorption[J]. CIESC Journal, 2019, 70(10): 4032-4042 DOI: 10.11949/0438-1157.20190725. DOI：

摘要

为减缓气候变化，减少CO

的排放，对真空变温吸附(TVSA)从干烟道气中捕集CO

进行了系统的研究。以沸石13X为吸附剂，设计了实验室规模的4塔连续进料的TVSA工艺，并建立数学模型进行数值模拟。模拟结果表明，通过四塔TVSA可获得纯度为97.54%，回收率为96.79%的CO

产品气，其产率为1.7 mol·

https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=113938074&type=

https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=113938073&type=

10.24466705

2.96333337

-1

·h

-1

，能耗为3.1

https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=113938103&type=

https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=113938110&type=

18.96533394

4.14866638

。此外，考察了进料量、循环回流步骤时间、真空度对产品气纯度、回收率、吸附剂产率和工艺能耗的影响，并且分析了塔内压力与温度变化，详细探讨了塔内气固相浓度随轴向的分布。良好的工艺效果表明，TVSA有潜力成为一种能够生产高纯度高回收率的CO

产品气，并具有良好经济效益的捕碳工艺。

Abstract

To mitigate climate change and reduce CO

emissions

a systematic study on the capture of CO

from dry flue gas by temperature vacuum swing adsorption (TVSA) was conducted. With zeolite 13X as adsorbent

a four-bed TVSA with continuous feeding was designed

and a mathematical model was established for numerical simulation. Results showed that with the productivity of 1.7 mol·(kg ads)

-1

·h

-1

and energy consumption of 3.14 MJ·

https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=113938107&type=

https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=113938077&type=

15.49400043

4.82599974

purity of 97.54% and CO

recovery of 96.79% can be obtained by the four-bed TVSA process. The effect of feed flowrate

recycle time and vacuum level on purity

recovery

productivity and energy consumption was investigated. Additionally

the pressure and temperature behaviors in the column were analyzed

and the distribution of gas phase and adsorbed phase concentration in the axial direction was discussed in detail. The good performance indicated that TVSA will have the potential to be a cost-effective process capable of producing high purity and high recovery CO

product.

关键词

Keywords

references

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⁰

Simulation study on CO2 capture from dry flue gas by temperature vacuum swing adsorption

DOI：10.11949/0438-1157.20190725

摘要

Abstract

关键词

Keywords

references

Simulation study on CO₂ capture from dry flue gas by temperature vacuum swing adsorption