Preparation of oxygen defect vacancies MoO<sub>3-</sub><italic style="font-style: italic"><sub>x</sub></italic> and its adsorption properties

LIJIANG Wuji; ZHU Qiaoying; CHEN Lifang; CHENG Hongye; QI Zhiwen

doi:10.11949/0438-1157.20190648

您当前的位置：

首页 >

文章列表页 >

Preparation of oxygen defect vacancies MoO_3-_x and its adsorption properties

Catalysis\, kinetics and reactors | 更新时间：2026-07-24

- Preparation of oxygen defect vacancies MoO_3-_x and its adsorption properties
- CIESC Journal Vol. 70, Issue 10, Pages: 3956-3966(2019)
- 作者机构：
  
  华东理工大学化工学院，化学工程联合国家重点实验室，上海 200237
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20190648
  CLC： X 506
- Received：10 June 2019，
  
  Revised：2019-09-18，
  
  Online First：24 July 2026，
  
  Published：05 October 2019
- 稿件说明：
移动端阅览
李姜无忌, 朱巧影, 陈立芳, 成洪业, 漆志文. 氧缺陷位MoO_3-_x的制备及其吸附性能研究[J]. 化工学报, 2019, 70(10): 3956-3966 DOI: 10.11949/0438-1157.20190648.

LIJIANG Wuji, ZHU Qiaoying, CHEN Lifang, CHENG Hongye, QI Zhiwen. Preparation of oxygen defect vacancies MoO_3-_x and its adsorption properties[J]. CIESC Journal, 2019, 70(10): 3956-3966 DOI: 10.11949/0438-1157.20190648.
李姜无忌, 朱巧影, 陈立芳, 成洪业, 漆志文. 氧缺陷位MoO_3-_x的制备及其吸附性能研究[J]. 化工学报, 2019, 70(10): 3956-3966 DOI: 10.11949/0438-1157.20190648. DOI：

LIJIANG Wuji, ZHU Qiaoying, CHEN Lifang, CHENG Hongye, QI Zhiwen. Preparation of oxygen defect vacancies MoO_3-_x and its adsorption properties[J]. CIESC Journal, 2019, 70(10): 3956-3966 DOI: 10.11949/0438-1157.20190648. DOI：

摘要

纺织印染废水中的有机污染物如亚甲基蓝的高效吸附净化是环境领域的重要研究课题，三氧化钼独特的片层结构极具吸附应用潜力。通过微波一步法制备了不同氧空穴浓度的氧化钼，具有不同的表面电荷分布，利用氧空穴氧化钼表面所带负电荷选择性高效吸附阳离子偶氮染料亚甲基蓝。揭示了氧空穴浓度与吸附性能之间的关系，发现氧空穴浓度越高则氧化钼吸附速率越快；吸附过程符合Langmuir等温线模型和准二级动力学模型，表明该吸附过程属于单分子层吸附，并分析了其吸附机理。氧空穴氧化钼(MoO

)为金属氧化物在染料吸附领域的发展和应用提供一定的基础数据和理论基础。

Abstract

The high-efficiency adsorption purification of organic pollutants such as methylene blue in textile printing and dyeing wastewater is an important research topic in the environmental field. The unique lamellar structure of molybdenum oxides has great potential for adsorption application. Molybdenum oxides with different oxygen vacancies concentration were prepared by one-step microwave assisted hydrothermal method. The prepared molybdenum oxides with different negative surface charge distribution were applied to the efficient selective adsorption of organic pollutant cationic azo dye methylene blue. The relationship between oxygen vacancies concentration and adsorption performance was explored. It is found that molybdenum oxide with oxygen vacancies concentration is relative to its adsorption rate. The adsorption process conforms to Langmuir isotherm model and pseudo second order kinetic model

indicating that the adsorption process belongs to monomolecular adsorption. Therefore

it provides a potential for the development and application of metal oxides in the field of dye adsorption.

关键词

Keywords

references

Shannon M A , Bohn P W , Elimelech M , et al . Science and technology for water purification in the coming decades [J ] . Nature , 2008 , 452 ( 7185 ): 301 - 310 .

Ghasemi M , Mashhadi S , Asif M , et al . Microwave-assisted synthesis of tetraethylenepentamine functionalized activated carbon with high adsorption capacity for Malachite green dye [J ] . Journal of Molecular Liquids , 2016 , 213 ( 1 ): 317 - 325 .

任南琪 , 周显娇 , 郭婉茜 , 等 . 染料废水处理技术研究进展 [J ] . 化工学报 , 2013 , 64 ( 1 ): 84 - 94 .

Ren N Q , Zhou X J , Guo W Q , et al . A review on treatment methods of dye wastewater [J ] . CIESC Journal , 2013 , 64 ( 1 ): 84 - 94 .

Hoffmann M R , Martin S T , Choi W , et al . Environmental applications of semiconductor photocatalysis [J ] . Chemical Reviews , 1995 , 95 ( 1 ): 69 - 96 .

Pathania D , Sharma S , Singh P . Removal of methylene blue by adsorption onto activated carbon developed from Ficus carica bast [J ] . Arabian Journal of Chemistry , 2017 , 10 ( 1 ): S1445-S1451 .

Yagub M T , Sen T K , Ang H M . Equilibrium, kinetics, and thermodynamics of methylene blue adsorption by pine tree leaves [J ] . Water , Air , & Soil Pollution , 2012 , 223 ( 8 ): 5267 - 5282 .

Dabrowski A . Adsorption from theory to practice [J ] . Advances in Colloid and Interface Science , 2001 , 93 ( 1 ): 135 - 224 .

Ali I , Asim M , Khan T A . Low cost adsorbents for the removal of organic pollutants from wastewater [J ] . Journal of Environmental Management , 2012 , 113 ( 1 ): 170 - 183 .

Zhu Q , Wang Z , Chen L , et al . Ionic-liquid-controlled two-dimensional monolayer Bi 2 MoO 6 and its adsorption of azo molecules [J ] . ACS Applied Nano Materials , 2018 , 1 ( 9 ): 5083 - 5091 .

赵亚红 , 薛振华 , 王喜明 , 等 . 羧甲基纤维素/蒙脱土纳米复合材料对刚果红染料的吸附及解吸性能 [J ] . 化工学报 , 2012 , 63 ( 8 ): 2655 - 2660 .

Zhao Y H , Xue Z H , Wang X M , et al . Adsorption and desorption properties for Congo red dye of carboxymethylcellulose/montmorillonite nanocomposites [J ] . CIESC Journal , 2012 , 63 ( 8 ): 2655 - 2660 .

Allen S J , Koumanova B . Decolourisation of water/wastewater using adsorption [J ] . Journal of the University of Chemical Technology and Metallurgy , 2005 , 40 ( 3 ): 175 - 192 .

Gougoulias N , Papachatzis A , Kalorizou H . Role of acid blue 25 dye as active site for the adsorption of Cd 2+ , and Zn 2+ , using activated carbons [J ] . Dyes & Pigments , 2013 , 96 ( 2 ): 459 - 466 .

Sarkar M , Majumdar P . Application of response surface methodology for optimization of heavy metal biosorption using surfactant modified chitosan bead [J ] . Chemical Engineering Journal , 2011 , 175 ( 1 ): 376 - 387 .

Lee M Y , Hong K J , Kajiuchi T , et al . Synthesis of chitosan-based polymeric surfactants and their adsorption properties for heavy metals and fatty acids [J ] . International Journal of Biological Macromolecules , 2005 , 36 ( 3 ): 152 - 158 .

Liu S , Ding Y , Li P . Adsorption of the ani onic dye Congo red from aqueous solution onto natural zeolites modified with N, N -dimethyl dehydroabietylamine oxide [J ] . Chemical Engineering Journal , 2014 , 248 ( 1 ): 135 - 144 .

Nie L H , Tan Q , Zhu W . Fast adsorption removal of Congo red on hierarchically porous γ-Al 2 O 3 hollow microspheres prepared by microwave-assisted hydrothermal method [J ] . Acta Physico-Chimica Sinica , 2015 , 31 ( 9 ): 1815 - 1822 .

He Q , Ni Y , Ye S . Preparation of flowerlike BiOBr/Bi 2 MoO 6 composite superstructures and the adsorption behavior to dyes [J ] . Journal of Physics and Chemistry of Solids , 2017 , 104 ( 1 ): 286 - 292 .

汪泽华 , 蔡卫权 , 郭蕾 , 等 . P123辅助SB粉溶胶制备大孔径介孔γ-Al 2 O 3 及其对甲基蓝的强化吸附性能 [J ] . 化工学报 , 2012 , 63 ( 8 ): 2623 - 2628 .

Wang Z H , Cai W Q , Guo L , et al . P123-assisted synthesis of enlarged mesoporous γ-Al 2 O 3 from SB pseudoboehmite sol and its enhanced adsorption performance towards methyl blue [J ] . CIESC Journal , 2012 , 63 ( 8 ): 2623 - 2628 .

徐刚 , 郜洪文 . 甜菜碱OSB-12@高岭土杂化材料对染料吸附机理研究 [J ] . 化学学报 , 2012 , 70 ( 24 ): 2496 - 2500 .

Xu G , Gao H W . Betaine OSB-12@kaolin hybrid material synthesized for adsorption of dyes [J ] . Acta Chimica Sinica , 2012 , 70 ( 24 ): 2496 - 2500 .

Lou X W , Zeng H C . Hydrothermal synthesis of α-MoO 3 nanorods via acidification of ammonium heptamolybdate tetrahydrate [J ] . Chemistry of Materials , 2002 , 14 ( 11 ): 4781 - 4789 .

Sheehan P E , Lieber C M . Nanotribology and nanofabrication of MoO 3 structures by atomic force microscopy [J ] . Science , 1996 , 272 ( 5265 ): 1158 - 1161 .

Song J , Ni X , Gao L , et al . Synthesis of metastable h-MoO 3 by simple chemical precipitation [J ] . Materials Chemistry and Physics , 2007 , 102 ( 2 / 3 ): 245 - 248 .

Siciliano T , Tepore A , Filippo E , et al . Characteristics of molybdenum trioxide nanobelts prepared by thermal evaporation technique [J ] . Materials Chemistry and Physics , 2009 , 114 ( 2 / 3 ): 687 - 691 .

Schöllhorn R , Kuhlmann R , Besenhard J O . Topotactic redox reactions and ion exchange of layered MoO 3 bronzes [J ] . Materials Research Bulletin , 1976 , 11 ( 1 ): 83 - 90 .

Prasad A K , Kubinski D J , Gouma P I . Comparison of sol–gel and ion beam deposited MoO 3 thin film gas sensors for selective ammonia detection [J ] . Sensors and Actuators B: Chemical , 2003 , 93 ( 1 / 2 / 3 ): 25 - 30 .

Kim H S , Cook J B , Lin H , et al . Oxygen vacancies enhance pseudocapacitive charge storage properties of MoO 3- x [J ] . Nature Materials , 2017 , 16 ( 4 ): 454 .

Dieterle M , Weinberg G , Mestl G . Raman spectroscopy of molybdenum oxides (Ⅰ): Structural characterization of oxygen defects in MoO 3- x by DR UV/VIS, Raman spectroscopy and X-ray diffraction [J ] . Physical Chemistry Chemical Physics , 2002 , 4 ( 5 ): 812 - 821 .

Tao P , Xu Y , Zhou Y , et al . Nitrogen oxide (NO) gas-sensing properties of Bi 2 MoO 6 nanosheets synthesized by a hydrothermal method [J ] . Materials Research , 2017 , 20 ( 3 ): 786 - 790 .

Vasilopoulou M , Douvas A M , Georgiadou D G , et al . The influence of hydrogenation and oxygen vacancies on molybdenum oxides work function and gap states for application in organic optoelectronics [J ] . Journal of the American Chemical Society , 2012 , 134 ( 39 ): 16178 - 16187 .

Greiner M T , Chai L , Helander M G , et al . Transition metal oxide work functions: the influence of cation oxidation state and oxygen vacancies [J ] . Advanced Functional Materials , 2012 , 22 ( 21 ): 4557 – 4568 .

Kong X Y , Ng B J , Tan K H , et al . Simultaneous generation of oxygen vacancies on ultrathin BiOBr nanosheets during visible-light-driven CO 2 , photoreduction evoked superior activity and long-term stability [J ] . Catalysis Today , 2018 , 314 : 20 - 27 .

Zhang L , Wang W , Jiang D , et al . Photoreduction of CO 2 on BiOCl nanoplates with the assistance of photoinduced oxygen vacancies [J ] . Nano Research , 2015 , 8 ( 3 ): 821 - 831 .

Cervantes F J , Garciaespinosa A , Morenoreynosa M A , et al . Immobilized redox mediators on anion exchange resins and their role on the reductive decolorization of azo dyes [J ] . Environmental Science & Technology , 2010 , 44 ( 5 ): 1747 - 1753 .

Liu T , Li Y , Du Q , et al . Adsorption of methylene blue from aqueous solution by graphene [J ] . Colloids and Surfaces B- Biointerfaces , 2012 , 90 : 197 - 203 .

Haque E , Jun J W , Jhung S H . Adsorptive removal of methyl orange and methylene blue from aqueous solution with a metal-organic framework material, iron terephthalate (MOF-235) [J ] . Journal of Hazardous Materials , 2011 , 185 ( 1 ): 507 - 511 .

Li Y , Du Q , Liu T , et al . Comparative study of methylene blue dye adsorption onto activated carbon, graphene oxide, and carbon nanotubes [J ] . Chemical Engineering Research & Design: Transactions of the Institution of Chemical Engineers , 2013 , 91 ( 2 ): 361 - 368 .

Guo J Z , Li B , Liu L , et al . Removal of methylene blue from aqueous solutions by chemically modified bamboo [J ] . Chemosphere , 2014 , 111 : 225 - 231 .

Namasivayam A , Sumithra S . Removal of direct red 12B and methylene blue from water by adsorption onto Fe(Ⅲ)/Cr(Ⅲ) hydroxide, an industrial solid waste [J ] . Journal of Environmental Management , 2005 , 74 ( 3 ): 207 - 215 .

Dogan M , Alkan M , Onager Y . Adsorption of methylene blue from aqueous solution onto perlite [J ] . Water Air & Soil Pollution , 2000 , 120 ( 3 / 4 ): 229 - 248 .

Bagane M , Guiza S . Removal of a dye from textile effluents by adsorption [J ] . Annales de Chimie-Science des Materiaux , 2000 , 25 ( 8 ): 615 - 626 .

Tian P , Han X , Ning G , et al . Synthesis of porous hierarchical MgO and its superb adsorption properties [J ] . ACS Applied Materials & Interfaces , 2013 , 5 ( 23 ): 12411 - 12418 .

陈自正 , 沈卫华 , 陈立芳 , 等 . 纳米H 2 TiO 3 锂吸附剂的水热合成及其吸附性能 [J ] . 中国有色金属学报 , 2017 , 27 ( 3 ): 547 - 554 .

Chen Z Z , Shen W H , Chen L F , et al . Hydrothermal synthesis and adsorption properties of nano scale H 2 TiO 3 adsorbent [J ] . The Chinese Journal of Nonferrous Metals , 2017 , 27 ( 3 ): 547 - 554 .

Atia A A , Donia A M , Al-Amrani W A . Adsorption/desorption behavior of acid orange 10 on magnetic silica modified with amine groups [J ] . Chemical Engineering Journal , 2009 , 150 ( 1 ): 55 - 62 .

Senturk H B , Ozdes D , Gundogdu A , et al . Removal of phenol from aqueous solutions by adsorption onto organomodified Tirebolu bentonite: equilibrium, kinetic and thermodynamic study [J ] . Journal of Hazardous Materials , 2009 , 172 ( 1 ): 353 - 362 .

Zhang J , Xiao H , Yang Y . Preparation of hemicellulose-containing latex and its application as absorbent toward dyes [J ] . Journal of Materials Science , 2015 , 50 ( 4 ): 1673 - 1678 .

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Kinetic analysis of removal of methylene blue using fly ash assisted by ultrasound from aqueous solution

Preparation and adsorption properties of temperature sensitive poly(N-isopropylacrylamide) /monosodium glutamate/ chitosan composites

Preparation of ZIF-8 based porous liquid and its SO2 adsorption performance

Study on the properties of carbon with Se doping cobalt sulfide in lithium-sulfur batteries

Kinetic regulation strategies in lithium-sulfur batteries

Related Author

Lan CHEN

Yuheng QUAN

Zhiyong LI

Pengfei YUE

LYU Gaoying

MU Chaoqun

WANG Ting

HE Zhixian

Related Institution

Hebei Key Laboratory of Power Plant Flue Gas Multi-Pollutants Control

College of Environmental Science and Engineering, North China Electric Power University

School of Chemistry and Chemical Engineering, Xi'an University of Architecture and Technology

Department of Materials and Chemical Engineering, Zhengzhou University of Light Industry

School of Chemistry and Chemical Engineering, Xi’an University of Architecture and Technology

⁰

Preparation of oxygen defect vacancies MoO3-x and its adsorption properties

DOI：10.11949/0438-1157.20190648

摘要

Abstract

关键词

Keywords

references

Preparation of oxygen defect vacancies MoO_3-_x and its adsorption properties