Effect of Cu<sup>2+ </sup>concentration in cathode on power generation and copper removal of thermally regenerative ammonia-based battery

TANG Zhiqiang; ZHANG Liang; ZHU Xun; LI Jun; FU Qian; LIAO Qiang

doi:10.11949/0438-1157.20190643

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Effect of Cu²⁺concentration in cathode on power generation and copper removal of thermally regenerative ammonia-based battery

Energy and environmental engineering | 更新时间：2026-07-24

- Effect of Cu²⁺concentration in cathode on power generation and copper removal of thermally regenerative ammonia-based battery
- CIESC Journal Vol. 70, Issue 12, Pages: 4804-4810(2019)
- 作者机构：
  
  1. 低品位能源利用技术及系统教育部重点实验室，重庆 400030
  2. 重庆大学工程热物理研究所，重庆 400030
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20190643
  CLC： X 703.1
- Received：10 June 2019，
  
  Revised：2019-09-02，
  
  Online First：09 June 2020，
  
  Published：05 December 2019
- 稿件说明：
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唐志强, 张亮, 朱恂, 李俊, 付乾, 廖强. 不同Cu²⁺浓度下热再生氨电池产电及Cu²⁺去除特性[J]. 化工学报, 2019, 70(12): 4804-4810 DOI: 10.11949/0438-1157.20190643.

TANG Zhiqiang, ZHANG Liang, ZHU Xun, LI Jun, FU Qian, LIAO Qiang. Effect of Cu²⁺concentration in cathode on power generation and copper removal of thermally regenerative ammonia-based battery[J]. CIESC Journal, 2019, 70(12): 4804-4810 DOI: 10.11949/0438-1157.20190643.
唐志强, 张亮, 朱恂, 李俊, 付乾, 廖强. 不同Cu²⁺浓度下热再生氨电池产电及Cu²⁺去除特性[J]. 化工学报, 2019, 70(12): 4804-4810 DOI: 10.11949/0438-1157.20190643. DOI：

TANG Zhiqiang, ZHANG Liang, ZHU Xun, LI Jun, FU Qian, LIAO Qiang. Effect of Cu²⁺concentration in cathode on power generation and copper removal of thermally regenerative ammonia-based battery[J]. CIESC Journal, 2019, 70(12): 4804-4810 DOI: 10.11949/0438-1157.20190643. DOI：

摘要

热再生氨电池（thermally regenerative ammonia-based battery，TRAB）在废弃资源回收方面展现出独特优势和良好应用前景。通过构建TRAB来处理含Cu

废液并回收电能和铜资源，实验中研究了不同Cu

浓度对电池产电性能和废液Cu

去除效果的影响。研究结果表明，当阴极废液Cu

浓度低于0.2 mol/L时，随着Cu

浓度的增加，电池最大输出功率不断增加，电池输出电压和产电周期不断增加，促使批次获得电量和能量密度也不断增加。同时采用TRAB技术去除废液中铜离子具有较高的去除效率，而且去除率随着废液中铜离子浓度的增加而增加。后续研究采用TRAB结合电凝法的两步处理法有望进一步提高处理效果，具有较好的经济性和应用前景。

Abstract

The thermally regenerative ammonia-based battery (TRAB) exhibits unique advantages and good application prospects in the recycling of waste resources. By constructing TRAB to treat Cu

-containing waste liquid and recovering electric energy and copper resources

the effects of different Cu

concentrations on battery power generation performance and Cu

removal of waste liquid were studied. The results showed that

with the increasing Cu

concentration less than 0.2 mol/L

the maximal power

the total charge

and the energy density and copper removal rate increased during the discharging. A very-low final concentration and a high removal rate of Cu

indicated that TRAB is feasible for the treatment of was

te water containing Cu

. The two-step treatment method using TRAB combined with electrocoagulation method in the follow-up study is expected to further improve the treatment effect

and has good economic and application prospects.

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Keywords

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⁰

Effect of Cu2+ concentration in cathode on power generation and copper removal of thermally regenerative ammonia-based battery

DOI：10.11949/0438-1157.20190643

摘要

Abstract

关键词

Keywords

references

Effect of Cu²⁺concentration in cathode on power generation and copper removal of thermally regenerative ammonia-based battery