Volumetric and viscosity properties of binary mixtures containing asymmetrical Gemini ionic liquid

Xuzhao YANG; Jun WANG; Yun FANG

doi:10.11949/0438-1157.20190470

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Volumetric and viscosity properties of binary mixtures containing asymmetrical Gemini ionic liquid

Thermodynamics | 更新时间：2020-06-24

- Volumetric and viscosity properties of binary mixtures containing asymmetrical Gemini ionic liquid
- CIESC Journal Vol. 70, Issue 11, Pages: 4131-4142(2019)
- 作者机构：
  
  1.Key Laboratory of Synthetic and Biological Colloids，Ministry of Education, School of Chemical and Material Engineering，Jiangnan University，Wuxi 214122, Jiangsu, China
  2.Zhengzhou Key Laboratory of Fine Chemicals, School of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, Henan, China
  江南大学化学与材料工程学院，合成与生物胶体教育部重点实验室，江苏无锡 214122
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20190470
  CLC： TQ 013.1
- Received：06 May 2019，
  
  Revised：2019-08-15，
  
  Published：05 November 2019
- 稿件说明：
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杨许召, 王军, 方云. 含非对称Gemini离子液体二元混合体系的体积和黏度性质[J]. 化工学报, 2019, 70(11): 4131-4142

YANG Xuzhao, WANG Jun, FANG Yun. Volumetric and viscosity properties of binary mixtures containing asymmetrical Gemini ionic liquid[J]. CIESC Journal, 2019, 70(11): 4131-4142
杨许召, 王军, 方云. 含非对称Gemini离子液体二元混合体系的体积和黏度性质[J]. 化工学报, 2019, 70(11): 4131-4142 DOI： 10.11949/0438-1157.20190470.

YANG Xuzhao, WANG Jun, FANG Yun. Volumetric and viscosity properties of binary mixtures containing asymmetrical Gemini ionic liquid[J]. CIESC Journal, 2019, 70(11): 4131-4142 DOI： 10.11949/0438-1157.20190470.

摘要

在温度分别为293.15、303.15、313.15、323.15和333.15 K及大气压下，系统测定了非对称Gemini离子液体，1-(3-(三甲基铵)丙-1-基)-3-甲基咪唑

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810649&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810656&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810653&type=

3.17499995

3.09033346

双氰胺盐([N

111

MIM][N(CN)

]

)，分别与乙腈(MeCN)、甲醇(MeOH)、乙醇(EtOH)所组成的二元混合物的密度和黏度。由密度和黏度值分别计算了二元混合物的超额摩尔体积(

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810294&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810292&type=

3.47133350

)和超额黏度(Δ

)。

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810301&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810298&type=

3.47133350

和Δ

随组成的变化关系由Redlich-Kister方程进行了回归，得到方程参数。结果表明，

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810307&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810304&type=

3.47133350

和Δ

值与理想溶液间为负偏差，且存在最小值，说明二元体系中[N

111

MIM][N(CN)

]

和溶剂分子间相互作用力更强，同时与所研究分子的大小和形状的差异有关。同时，

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810321&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810311&type=

3.47133350

和Δ

随温度的变化关系表明，温度对研究混合物中的分子间相互作用有很大影响。

Abstract

Densities and dynamic viscosities of binary solutions containing asymmetrical Gemini ionic liquid (GIL)

1-(3-(trimethylammonio)prop-1-yl)-3-methylimidazolium bis(dicyanamide) ([N

111

MIM][N(CN)

]

) with acetonitrile (MeCN)

methanol (MeOH) or ethanol (EtOH) over the entire mole fraction range have been measured from 293.15 K to 333.15 K under atmospheric pressure. Excess molar volumes (

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810327&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810323&type=

3.89466667

4.06400013

) and excess viscosities (Δ

) of the solutions were calculated based on the experimental density and

viscosity

values of pure [N

111

MIM][N(CN)

]

molecular solvents

and their binary mixtures. The values of

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810336&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810332&type=

3.89466667

4.06400013

and Δ

were fitted by using the Redlich–Kister equations and the optimal ﬁtting parameters were obtained. The results indicate that

the values of

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810345&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810340&type=

3.89466667

4.06400013

and Δ

reveal negative deviations from ideal solutions. There exists a minimum excess values. Negative values of

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810352&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810349&type=

3.89466667

4.06400013

and Δ

for all the binary mixtures indicate

compared to pure [N

111

MIM][N(CN)

]

and molecular solvents

stronger interactions between [N

111

MIM][N(CN)

]

and MeCN

MeOH or EtOH. These negative values are also related to the difference in size and shape of the molecules studied. Moreover

the variation of

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810359&type=

http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=810355&type=

3.89466667

4.06400013

and Δ

on temperature suggests that temperature has an enormous inﬂuence on the intermolecular interactions between [N

111

MIM][N(CN)

]

and molecular solvents.

关键词

Keywords

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