

浏览全部资源
扫码关注微信
1.School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001, Henan, China
2.Vatti Co., Ltd., Zhongshan 528415, Guangdong, China
Received:11 April 2019,
Revised:2019-07-03,
Published:05 November 2019
移动端阅览
张林生, 刘周明, 李光耀, 陈婷婷, 薛冰. 吸附过程强化对提升高温热泵蒸汽生成性能的影响[J]. 化工学报, 2019, 70(11): 4172-4180
ZHANG Linsheng, LIU Zhouming, LI Guangyao, CHEN Tingting, XUE Bing. Effect of adsorption process intensification for high-temperature steam generation in adsorption heat pump[J]. CIESC Journal, 2019, 70(11): 4172-4180
张林生, 刘周明, 李光耀, 陈婷婷, 薛冰. 吸附过程强化对提升高温热泵蒸汽生成性能的影响[J]. 化工学报, 2019, 70(11): 4172-4180 DOI: 10.11949/0438-1157.20190378.
ZHANG Linsheng, LIU Zhouming, LI Guangyao, CHEN Tingting, XUE Bing. Effect of adsorption process intensification for high-temperature steam generation in adsorption heat pump[J]. CIESC Journal, 2019, 70(11): 4172-4180 DOI: 10.11949/0438-1157.20190378.
在基于直接接触换热法的开式吸附热泵系统中,引入预吸附过程或预设传质通道,考察其对蒸汽生成和系统性能的影响。实验结果表明,预吸附蒸汽压力为0.0680 MPa(饱和温度=89.2℃),系统生成高温蒸汽的平均温度为203℃,系统整体温升为98.4℃,相对于无预吸附系统,生成蒸汽的时间和质量分别增加52.2%和27.0%,系统制热系数和制热功率分别提升28.2%和27.2%。预置树枝状传质通道后,生成蒸汽的时间和质量分别增加了17.8%和8.75%,系统制热系数和制热功率分别提升8.16%和9.05%。预吸附过程使吸附床较快达到整体吸附和热力平衡,缩短蒸汽到达床层出口的时间。预吸附压力越高,系统到达整体吸附平衡的用时越短,蒸汽生成时间越早。传质通道促进吸附床局部平衡的达成,减小局部传质阻力,使部分蒸汽可迅速到达出口。整体和局部吸附平衡的快速达成,均强化了蒸汽的动态生成过程,提升系统整体性能。
In the open adsorption heat pump system based on direct contact heat transfer method
a pre-adsorption process or a preset mass transfer channel is introduced to investigate its influence on steam generation and system performance. In this paper
experimental working principle of high-temperature steam generation from hot water is described as a comparison. Then cyclic test with pre-adsorption units (saturation temperature=74.0℃ and 89.2℃) and mass transfer channels (branch shape and coiler shape) are conducted. The results show that after adding the pre-adsorption process(saturation temperature=89.2℃)
the average temperature of the generated steam is 203 ̊C and GTL (gross temperature lift) of the system is 98.4 ̊C. Steam generation time was 131 s earlier than the comparative experiment
effective time ratio for steam generation is elevated by 52.2% and mass of generated steam is raised by 27.0%. COP
h
(heating coefficient of performance) and SHP
s
(specific heating power for steam generation)are improved by 28.2% and 27.2%
respectively. When presetting branch shape channel inside the adsorption bed
effective time ratio for steam generation is elevated by 17.8% and mass of generated steam is raised by 8.75%. COP
h
and SHP
s
are increased by 8.16%and 9.05%
respectively.The pre-adsorption process allows the adsorption bed to reach the entire adsorption and thermal equilibrium faster. As a result
the generated high temperature steam arrives the top exit earlier. Besides
the local adsorption equilibrium is promoted on account of the mass transfer channel
which also reduces the local mass transfer resistance and makes a part of generated steam leave the pocked bed quickly. These results indicate that with the rapidly achievement of the entire and local adsorption equilibrium
the dynamic steam generation process is successfully intensified and the system performance is significantly improved.
胡山鹰 , 陈定江 , 金涌 , 等 . 化学工业绿色发展战略研究: 基于化肥和煤化工行业的分析 [J]. 化工学报 , 2014 , 65 ( 7 ): 2704 - 2709 .
Hu S Y , Chen D J , Jin Y , et al . Green development strategies for chemical industry in China: based on analysis of fertilizer industry and coal chemical industry [J]. CIESC Journal , 2014 , 65 ( 7 ): 2704 - 2709 .
Xu Z Y , Wang R Z , Yang C . Perspectives for low-temperature waste heat recovery [J]. Energy , 2019 , 176 : 1037 - 1043 .
Shao L , Ma X , Wei X , et al . Design and experimental study of a small-sized organic Rankine cycle system under various cooling conditions [J]. Energy , 2017 , 130 : 236 - 245 .
Zhang H , Zhao H , Li Z , et al . Optimization potentials for the waste heat recovery of a gas-steam combined cycle power plant based on absorption heat pump [J]. Journal of Thermal Science , 2018 , 28 ( 4 ): 283 - 293 .
João M S D , Vítor A F C . Adsorption heat pumps for heating applications: a review of current state, literature gaps and development challenges [J]. Renewable and Sustainable Energy Reviews , 2018 , 98 : 317 - 327 .
王如竹 . 吸附式制冷新技术 [J]. 化工学报 , 2000 , 51 ( 4 ): 435 - 442 .
Wang R Z . New technology of adsorption refrigeration [J]. Journal of Chemical Industry and Engineering(China) , 2000 , 51 ( 4 ): 435 - 442 .
Kayal S , Sun B , Saha B B . Adsorption characteristics of AQSOA zeolites and water for adsorption chillers [J]. International Journal of Heat & Mass Transfer , 2016 , 92 : 1120 - 1127 .
Meunier F . Second law analysis of a solid adsorption heat pump operating on reversible cascade cycles: application to the zeolite-water pair [J]. Journal of Heat Recovery Systems , 1985 , 5 ( 2 ): 133 - 141 .
Sultan M , Miyazaki T , Koyama S , et al . Optimization of adsorption isotherm types for desiccant air-conditioning applications [J]. Renewable Energy , 2018 , 121 : 441 - 450 .
Xu S Z , Lemington , Wang R Z , et al . A zeolite 13X/magnesium sulfate-water sorption thermal energy storage device for domestic heating [J]. Energy Conversion and Management , 2018 , 171 : 98 - 109 .
Pal A , Shahrom M S R , Moniruzzaman M , et al . Ionic liquid as a new binder for activated carbon based consolidated composite adsorbents [J]. Chemical Engineering Journal , 2017 , 326 : 980 - 986 .
Bonaccorsi L , Calabrese L , Alioto S , et al . Surface silanation of alumina-silica zeolites for adsorption heat pumping [J]. Renewable Energy , 2017 , 110 : 79 - 86 .
Bonaccorsi L , Proverbio E . Synthesis of thick zeolite 4A coatings on stainless steel [J]. Microporous & Mesoporous Materials , 2004 , 74 ( 1/2/3 ): 221 - 229 .
Schnabel L , Tatlier M , Schmidt F , et al . Adsorption kinetics of zeolite coatings directly crystallized on metal supports for heat pump applications (adsorption kinetics of zeolite coatings) [J]. Applied Thermal Engineering , 2010 , 30 ( 11/12 ): 1409 - 1416 .
Ammann J , Michel B , Studart A R , et al . Sorption rate enhancement in SAPO-34 zeolite by directed mass transfer channels [J]. International Journal of Heat and Mass Transfer , 2019 , 130 : 25 - 32 .
徐敬玉 . 流态化吸附制冷技术的理论及实验研究 [D]. 杭州 : 浙江大学 , 2007 .
Xu J Y . Theoretical and experimental research on fluidized adsorption refrigeration technology [D]. Hangzhou : Zhejiang University , 2007 .
Pan Q W , Wang R Z . Experimental study on operating features of heat and mass recovery processes in adsorption refrigeration [J]. Energy , 2017 , 135 : 361 - 369 .
徐圣知 , 王丽伟 , 王如竹 . 回质回热吸附式制冷循环的热力学分析与方案优选 [J]. 化工学报 , 2016 , 67 ( 6 ): 2202 - 2210 .
Xu S Z , Wang L W , Wang R Z . Thermodynamic analysis of mass and heat recovery adsorption refrigeration cycles and scheme selection [J]. CIESC Journal , 2016 , 67 ( 6 ): 2202 - 2210 .
Metcalf S J , Critoph R E , Tamainot-Telto Z . Optimal cycle selection in carbon-ammonia adsorption cycles [J]. International Journal of Refrigeration , 2012 , 35 ( 3 ): 571 - 580 .
Pan Q W , Wang R Z , Vorayos N , et al . A novel adsorption heat pump cycle: cascaded mass recovery cycle [J]. International Journal of Refrigeration , 2018 , 95 : 21 - 27 .
Tsoa C Y , Chana K C , Chao C Y H . Experimental performance analysis on an adsorption cooling system using zeolite 13X/CaCl 2 adsorbent with various operation sequences [J]. International Journal of Heat and Mass Transfer , 2015 , 85 : 343 - 355 .
高娇 , 王丽伟 , 周志松 , 等 . 多盐复合吸附剂的非平衡吸附/解吸特性 [J]. 化工学报 , 2016 , 67 ( S2 ): 184 - 189 .
Gao J , Wang L W , Zhou Z S , et al . Nonequilibrium adsorption/desorption characteristics of multisalt complex adsorbents [J]. CIESC Journal , 2016 , 67 ( S2 ): 184 - 189 .
Yang P Z . Heat and mass transfer in adsorbent bed with consideration of non-equilibrium adsorption [J]. Applied Thermal Engineering , 2009 , 29 ( 14/15 ): 3198 - 3203 .
Hauer A . Open adsorption system for an energy efficient dishwasher [J]. Chemie Ingenieur Technik - CIT , 2011 , 83 ( 1/2 ): 61 - 66 .
Xue B , Iwama Y , Tanaka Y , et al . Cyclic steam generation from a novel zeolite–water adsorption heat pump using low-grade waste heat [J]. Experimental Thermal and Fluid Science , 2013 , 46 : 54 - 63 .
薛冰 , 姚志敏 , 盛遵荣 , 等 . 颗粒分布对吸附热变换器内传热传质的影响 [J]. 化工学报 , 2016 , 67 ( S1 ): 174 - 180 .
Xue B , Yao Z M , Sheng Z R , et al . Effect of particle distribution on heat and mass transfer inside adsorption heat transformer [J]. CIESC Journal , 2016 , 67 ( S1 ): 174 - 180 .
Oktariani E , Tahara K , Nakashima K , et al . Experimental investigation on the adsorption process for steam generation using a zeolite-water system [J]. Journal of Chemical Engineering of Japan , 2012 , 45 ( 5 ): 355 - 362 .
Xue B , Meng X R , Wei X L , et al . Dynamic study of steam generation from low-grade waste heat in a zeolite-water adsorption heat pump [J]. Applied Thermal Engineering , 2015 , 88 : 451 - 458 .
Clausen L R . Energy efficient thermochemical conversion of very wet biomass to biofuels by integration of steam drying, steam electrolysis and gasification [J]. Energy , 2017 , 125 : 327 - 336 .
Hohenwarter K , Prammer W , Aichinger W , et al . An evaluation of different steam disinfection protocols for cystic fibrosis nebulizers [J]. Journal of Cystic Fibrosis , 2016 , 15 : 78 - 84 .
盛遵荣 , 姚志敏 , 薛冰 , 等 . 操作参数对吸附热变换器生成高温蒸汽的性能影响分析 [J]. 高校化学工程学报 , 2017 , 31 ( 2 ): 299 - 307 .
Sheng Z R , Yao Z M , Xue B , et al . Sensitivity analysis of operation parameters on high-temperature steam generation of an adsorption heat transformer [J]. Journal of Chemical Engineering of Chinese Universities , 2017 , 31 ( 2 ): 299 - 307 .
Xue B , Ye S , Zhang L S , et al . High-temperature steam generation from low-grade waste heat from an adsorptive heat transformer with composite zeolite-13X/CaCl 2 [J]. Energy Conversion and Management , 2019 , 186 : 93 - 102 .
0
Views
0
下载量
0
CSCD
Publicity Resources
Related Articles
Related Author
Related Institution
京公网安备11010102001995号