Fabrication of stainless steel mesh supported zeolite Al-beta coatings for oil/water separation

SHANG Xizi; ZHANG Baoquan; LI Yun

doi:10.11949/0438-1157.20190355

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Fabrication of stainless steel mesh supported zeolite Al-beta coatings for oil/water separation

Separation engineering | 更新时间：2026-07-24

- Fabrication of stainless steel mesh supported zeolite Al-beta coatings for oil/water separation
- CIESC Journal Vol. 70, Issue 10, Pages: 3994-4001(2019)
- 作者机构：
  
  化学工程联合国家重点实验室，天津大学化工学院，天津 300350
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20190355
  CLC： TQ 028.8
- Received：08 April 2019，
  
  Revised：2019-06-19，
  
  Online First：24 July 2026，
  
  Published：05 October 2019
- 稿件说明：
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尚茜子, 张宝泉, 李雲. 不锈钢网负载Al-beta分子筛涂层的制备及其在油水分离中的应用[J]. 化工学报, 2019, 70(10): 3994-4001

SHANG Xizi, ZHANG Baoquan, LI Yun. Fabrication of stainless steel mesh supported zeolite Al-beta coatings for oil/water separation[J]. CIESC Journal, 2019, 70(10): 3994-4001
尚茜子, 张宝泉, 李雲. 不锈钢网负载Al-beta分子筛涂层的制备及其在油水分离中的应用[J]. 化工学报, 2019, 70(10): 3994-4001 DOI： 10.11949/0438-1157.20190355.

SHANG Xizi, ZHANG Baoquan, LI Yun. Fabrication of stainless steel mesh supported zeolite Al-beta coatings for oil/water separation[J]. CIESC Journal, 2019, 70(10): 3994-4001 DOI： 10.11949/0438-1157.20190355.

摘要

使用二次生长法在不锈钢网表面制备了Al-beta分子筛涂层，并通过扫描电镜、X射线衍射和接触角检测对其进行了表征。Al-beta分子筛晶粒以球形呈现在不锈钢网表面，并相互交联而构成微纳双级粗糙结构，Al-beta涂层表现出超亲水和水中超疏油性质。将不锈钢网负载Al-beta分子筛涂层用于分离一系列油水混合物，并考察了其耐久性和稳定性。实验结果表明，不锈钢网负载Al-beta分子筛涂层在重复使用100次后其正己烷/水分离效率仍保持在97.1%以上，酸、碱和超声等处理对其形貌和油水分离效率几乎没有影响，具备优异的耐久性、自清洁性和稳定性，在实际油水分离过程中有很大应用潜力。

Abstract

The zeolite Al-beta coating was fabricated on the stainless steel mesh by secondary growth method. Scanning electron microscopy (SEM)

X-ray diffraction (XRD) and contact angle (CA) measurements were used to characterize the zeolite Al-beta coatings. The cross-linked zeolite Al-beta crystals with spherical morphology on the stainless steel mesh constituted a micro/nanoscale hierarchical structure. The as-synthesized stainless steel mesh supported zeolite Al-beta coatings exhibited superhydrophilic and underwater superoleophobic characteristics. The stainless steel mesh supported zeolite Al-beta coating was applied to the separation of various oil/water mixtures. It could maintain the high separation efficiency above 97.1% after 100 separation cycles. The stability of zeolite Al-beta coatings was checked by using corrosive and ultrasonic treatments. The treated stainless steel mesh supported zeolite Al-beta coatings exhibited almost the same surface morphologies and separation efficiencies as the untreated sample. In addition

the zeolite Al-beta coating displayed a strong attachment to the stainless steel mesh surface. Self-cleaning stainless steel mesh supported zeolite Al-beta coatings with superior durability and stability would show great application potentials in actual oil/water separation processes.

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references

Chan Y J , Chong M F , Law C L , et al . A review on anaerobic–aerobic treatment of industrial and municipal wastewater [J ] . Chemical Engineering Journal , 2009 , 155 ( 1 ): 1 - 18 .

Singh V , Purkait M K , Das C . Cross-flow microfiltration of industrial oily wastewater: experimental and theoretical consideration [J ] . Separation Science and Technology , 2011 , 46 ( 8 ): 1213 - 1223 .

Xue Z X , Cao Y Z , Liu N , et al . Special wettable materials for oil/water separation [J ] . Journal of Materials Chemistry A , 2014 , 2 ( 8 ): 2445 - 2460 .

Ma Q L , Cheng H F , Fane A G , et al . Recent development of advanced materials with special wettability for selective oil/water separation [J ] . Small , 2016 , 12 ( 16 ): 2186 - 2202 .

袁腾 , 陈卓 , 周显宏 , 等 . 基于超亲水超疏油原理的网膜及其在油水分离中的应用 [J ] . 化工学报 , 2014 , 65 ( 6 ): 1943 - 1951 .

Yuan T , Chen Z , Zhou X H , et al . Coated mesh film based on superhydrophilic and superoleophobic principle and its application in oil-water separation [J ] . CIESC Journal , 2014 , 65 ( 6 ): 1943 - 1951 .

Dunderdale G J , England M W , Sato T , et al . Programmable oil/water separation meshes: water or oil selectivity using contact angle hysteresis [J ] . Macromolecular Materials and Engineering , 2016 , 301 ( 9 ): 1032 - 1036 .

Xiong L , Guo W , Alameda B M , et al . Rational design of superhydrophilic/superoleophobic surfaces for oil-water separation via thiol-acrylate photopolymerization [J ] . ACS Omega , 2018 , 3 ( 8 ): 10278 - 10285 .

Huang K T , Yeh S B , Huang C J . Surface modification for superhydrophilicity and underwater superoleophobicity: applications in antifog, underwater self-cleaning, and oil–water separation [J ] . ACS Applied Materials & Interfaces , 2015 , 7 ( 38 ): 21021 - 21029 .

Chen X L , Zhai Y D , Han X , et al . Surface chemistry-dominated underwater superoleophobic mesh with mussel-inspired zwitterionic coatings for oil/water separation and self-cleaning [J ] . Applied Surface Science , 2019 , 483 : 399 - 408 .

Liu J , Li P , Chen L , et al . Superhydrophilic and underwater superoleophobic modified chitosan-coated mesh for oil/water separation [J ] . Surface and Coatings Technology , 2016 , 307 : 171 - 176 .

Yang J , Yin L T , Tang H , et al . Polyelectrolyte-fluorosurfactant complex-based meshes with superhydrophilicity and superoleophobicity for oil/water separation [J ] . Chemical Engineering Journal , 2015 , 268 : 245 - 250 .

Wen N , Miao X R , Yang X J , et al . An alternative fabrication of underoil superhydrophobic or underwater superoleophobic stainless steel meshes for oil-water separation: originating from one-step vapor deposition of polydimethylsiloxane [J ] . Separation and Purification Technology , 2018 , 204 : 116 - 126 .

Cao Y Z , Liu N , Fu C K , et al . Thermo and pH dual-responsive materials for controllable oil/water separation [J ] . ACS Applied Materials & Interfaces , 2014 , 6 ( 3 ): 2026 - 2030 .

Su M J , Liu Y , Li S H , et al . A rubber-like, underwater superoleophobic hydrogel for efficient oil/water separation [J ] . Chemical Engineering Journal , 2019 , 361 : 364 - 372 .

Li J , Li D M , Li W J , et al . Facile f abrication of underwater superoleophobic SiO 2 coated meshes for separation of polluted oils from corrosive and hot water [J ] . Separation and Purification Technology , 2016 , 168 : 209 - 214 .

Liu Y Q , Zhang Y L , Fu X Y , et al . Bioinspired underwater superoleophobic membrane based on a graphene oxide coated wire mesh for efficient oil/water separation [J ] . ACS Applied Materials & Interfaces , 2015 , 7 ( 37 ): 20930 - 20936 .

Lin X , Lu F , Chen Y N , et al . One-step breaking and separating emulsion by tungsten oxide coated mesh [J ] . ACS Applied Materials & Interfaces , 2015 , 7 ( 15 ): 8108 - 8113 .

Tian D L , Zhang X F , Tian Y , et al . Photo-induced water-oil separation based on switchable superhydrophobicity-superhydrophilicity and underwater superoleophobicity of the aligned ZnO nanorod array-coated mesh films [J ] . Journal of Materials Chemistry , 2012 , 22 ( 37 ): 19652 - 19657 .

Gondal M A , Sadullah M S , Dastageer M A , et al . Study of factors governing oil–water separation process using TiO 2 films prepared by spray deposition of nanoparticle dispersions [J ] . ACS Applied Materials & Interfaces , 2014 , 6 ( 16 ): 13422 - 13429 .

Gunatilake U B , Bandara J . Efficient removal of oil from oil contaminated water by superhydrophilic and underwater superoleophobic nano/micro structured TiO 2 nanofibers coated mesh [J ] . Chemosphere , 2017 , 171 : 134 - 141 .

Peng Y B , Wen G , Gou X L , et al . Bioinspired fish-scale-like stainless steel surfaces with robust underwater anti-crude-oil-fouling and self-cleaning properties [J ] . Separation and Purification Technology , 2018 , 202 : 111 - 118 .

Zhang X J , Zhao Y X , Mu S J , et al . UiO-66-coated mesh membrane with underwater superoleophobicity for high-efficiency oil–water separation [J ] . ACS Applied Materials & Interfaces , 2018 , 10 ( 20 ): 17301 - 17308 .

Li Y , Shang X Z , Zhang B Q . One-step fabrication of the pure-silica zeolite beta coating on stainless steel mesh for efficient oil/water separation [J ] . Industrial & Engineering Chemistry Research , 2018 , 57 ( 51 ): 17409 - 17416 .

Wen Q , Di J C , Jiang L , et al . Zeolite-coated mesh film for efficient oil–water separation [J ] . Chemical Science , 2013 , 4 ( 2 ): 591 - 595 .

Liu R C , Dangwal S , Shaik I , et al . Hydrophilicity-controlled MFI-type zeolite-coated mesh for oil/water separation [J ] . Separation and Purification Technology , 2018 , 195 : 163 - 169 .

Liu R C , Young S , Dangwal S , et al . Boron substituted MFI-type zeolite-coated mesh for oil-water separation [J ] . Colloids and Surfaces A: Physicochemical and Engineering Aspects , 2018 , 550 : 108 - 114 .

Zeng J W , Guo Z G . Superhydrophilic and underwater superoleophobic MFI zeolite-coated film for oil/water separation [J ] . Colloids and Surfaces A: Physicochemical and Engineering Aspects , 2014 , 444 : 283 - 288 .

Lew C M , Cai R , Yan Y S . Zeolite thin films: from computer chips to space stations [J ] . Accounts of Chemical Research , 2010 , 43 ( 2 ): 210 - 219 .

Mitra A , Wang Z B , Cao T G , et al . Synthesis and corrosion resistance of high-silica zeolite MTW, BEA, and MFI coatings on steel and aluminum [J ] . Journal of the Electrochemical Society , 2002 , 150 ( 1 ): B472 -B 478 .

陈涛 , 刘秀凤 , 张宝泉 . 含氟体系优化合成Al-Beta分子筛膜 [J ] . 化学工业与工程 , 2016 , 33 ( 4 ): 38 - 48 .

Chen T , Liu X F , Zhang B Q . Synthesis of Al-beta zeolite membranes with an improved method in fluoride media [J ] . Chemical Industry and Engineering , 2016 , 33 ( 4 ): 38 - 48 .

Wolters L P , Bickelhaupt F M . Halogen bonding versus hydrogen bonding: a molecular orbital perspective [J ] . ChemistryOpen , 2012 , 1 ( 2 ): 96 - 105 .

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