Physicochemical properties and pyrolysis characteristics of heavy bio-oil

LUO Zejun; HU Yonghua; WANG Yusong; ZHU Xiefei; ZHU Xifeng

doi:10.11949/0438-1157.20190320

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Physicochemical properties and pyrolysis characteristics of heavy bio-oil

更新时间：2026-07-24

- Physicochemical properties and pyrolysis characteristics of heavy bio-oil
- CIESC Journal Vol. 70, Issue 8, Pages: 3196-3201(2019)
- 作者机构：
  
  1.中国科学技术大学工程科学学院，安徽合肥 230026
  2.安徽中烟工业有限责任公司烟草化学安徽省重点实验室，安徽合肥 230026
  3.中国科学技术大学合肥微尺度物质科学国家研究中心，安徽合肥 230026
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20190320
  CLC： TK 6
- Received：01 April 2019，
  
  Revised：2019-05-07，
  
  Online First：24 July 2026，
  
  Published：05 August 2019
- 稿件说明：
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罗泽军, 胡永华, 王雨松, 朱谢飞, 朱锡锋. 重质生物油理化性质及其热解特性研究[J]. 化工学报, 2019, 70(8): 3196-3201

LUO Zejun, HU Yonghua, WANG Yusong, ZHU Xiefei, ZHU Xifeng. Physicochemical properties and pyrolysis characteristics of heavy bio-oil[J]. CIESC Journal, 2019, 70(8): 3196-3201
罗泽军, 胡永华, 王雨松, 朱谢飞, 朱锡锋. 重质生物油理化性质及其热解特性研究[J]. 化工学报, 2019, 70(8): 3196-3201 DOI： 10.11949/0438-1157.20190320.

LUO Zejun, HU Yonghua, WANG Yusong, ZHU Xiefei, ZHU Xifeng. Physicochemical properties and pyrolysis characteristics of heavy bio-oil[J]. CIESC Journal, 2019, 70(8): 3196-3201 DOI： 10.11949/0438-1157.20190320.

摘要

利用核磁共振波谱仪（NMR）与气相色谱/质谱联用仪（GC/MS）对重质生物油理化性质进行表征，并应用热重分析仪（ TG-DTG）与热裂解仪-气相色谱/质谱联用仪（Py-GC/MS）对重质生物油热解特性进行研究。结果表明：重质生物油主要由芳香族化合物和糖类物质组成。重质生物油在N

氛围下热解主要分为三个阶段: 室温~300℃为蒸发段，300～520℃为热解段，520～800℃为成焦段。重质生物油经不同温度热解后，产物种类有明显差异：中温段（低于500℃）热解时，产物种类随温度的升高逐渐增加；高温段（高于500℃）热解时，随着热解温度的提高，产物种类逐渐趋于稳定。

Abstract

The physicochemical properties of heavy bio-oil were characterized by NMR and GC/MS

and thermogravimetric analyzer (TG-DTG) and pyrolysis instrument-gas chromatography/mass spectrometry (Py-GC/MS) was used to study the pyrolysis characteristics of heavy bio-oil. The results indicate that the heavy bio-oil consists of aromatic compounds and saccharides. The first stage is the volatilization of light compounds from ambient temperature to 300℃. The second stage is the pyrolysis

oxidation and polymerization of the heavy compounds at higher temperature (300—520℃). The last stage is the formation of coke (520—800℃). When the pyrolysis temperature is lower than 500℃

the species of products gradually increases with increasing temperature. When the temperature is higher than 500℃

the species of products tends to be stable with increasing temperature.

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Keywords

references

Czernik S , Bridgwater A V . Overview of applications of biomass fast pyrolysis oil [J ] . Energy & Fuels , 2004 , 18 ( 2 ): 590 - 598 .

马善为 , 李明 , 陈怡欣 , 等 . 毛竹热解制备高附加值化学品 [J ] . 化工学报 , 2014 , 65 ( 8 ): 3237 - 3242 .

Ma S W , Li M , Chen Y X , et al . Pyrolysis of pubescens for high value-added chemicals [J ] . CIESC Journal , 2014 , 65 ( 8 ): 3237 - 3242 .

王超 , 陈冠益 , 兰维娟 , 等 . 生物质快速热解制油试验及流程模拟 [J ] . 化工学报 , 2014 , 65 ( 2 ): 679 - 683 .

Wang C , Chen G Y , Lan W J , et al . Experimental research and process simulation on biomass fast pyrolysis for production of bio-oil [J ] . CIESC Journal , 2014 , 65 ( 2 ): 679 - 683 .

Zhang L , Liu R , Yin R , et al . Upgrading of bio-oil from biomass fast pyrolysis in China: a review [J ] . Renewable and Sustainable Energy Reviews , 2013 , 24 : 66 - 72 .

Ren S , Ye X P . Stability of crude bio-oil and its water-extracted fractions [J ] . Journal of Analytical and Applied Pyrolysis , 2018 , 132 : 151 - 162 .

Hu H S , Wu Y L , Yang M D . Fractionation of bio-oil produced from hydrothermal liquefaction of microalgae by liquid-liquid extraction [J ] . Biomass & Bioenergy , 2018 , 108 : 487 - 500 .

闫彩辉 , 赵炜 , 盛晨 , 等 . 柱层析法在生物油分离方面应用的研究进展 [J ] . 林产化学与工业 , 2011 , 31 ( 4 ): 123 - 126 .

Yan C H , Zhao W , Sheng C , et al . Research progress for separation of bio-oil by column chromatography [J ] . Chemistry and Industry of Forest Products , 2011 , 31 ( 4 ): 123 - 126 .

王誉蓉 , 王树荣 , 王相宇 , 等 . 不同蒸馏压力下的生物油分子蒸馏分离特性研究 [J ] . 燃料化学学报 , 2013 , 41 ( 2 ): 177 - 182 .

Wang Y R , Wang S R , Wang X Y , et al . Molecular distillation separation characteristic of bio-oil under different pressures [J ] . Journal of Fuel Chemistry and Technology , 2013 , 41 ( 2 ): 177 - 182 .

隋海清 , 李攀 , 王贤华 , 等 . 生物质热解气分级冷凝对生物油特性的影响 [J ] . 化工学报 , 2015 , 66 ( 10 ): 4138 - 4144 .

Sui H Q , Li P , Wang X H , et al . Influence on bio-oil by fractional condensation of biomass pyrolysis vapor [J ] . CIESC Journal , 2015 , 66 ( 10 ): 4138 - 4144 .

陈爱苹 . 生物油轻质组分水相重整制氢的研究 [D ] . 杭州 : 浙江大学 , 2017 .

Chen A P . Study on aqueous-phase reforming of low-boiling fraction of bio-oil for hydrogen production [D ] . Hangzhou : Zhejiang University , 2017 .

Peng J , Chen P , Lou H , et al . Catalytic upgrading of bio-oil by HZSM-5 in sub- and super-critical ethanol [J ] . Bioresource Technology , 2009 , 100 ( 13 ): 3415 - 3418 .

阮仁祥 , 李文志 , 张颖 , 等 . 生物油轻组分的催化氢化与酯化 [J ] . 中国科技论文在线 , 2010 , 5 ( 3 ): 217 - 223 .

Ruan R X , Li W Z , Zhang Y , et al . Experimental research on catalytic hydrogenation and esterification of light fraction of bio-oil [J ] . China Sciencepaper , 2010 , 5 ( 3 ): 217 - 223 .

徐莹 , 龙金星 , 张丽敏 , 等 . Raney-Ni催化生物油轻质组分加氢制备含氧燃料 [J ] . 农业工程学报 , 2014 , 30 ( 24 ): 252 - 258 .

Xu Y , Long J X , Zhang L M , et al . Prepare of oxygenated biofuels by catalytic hydrogenation using Raney-Ni catalyst [J ] . Transactions of the Chinese Society of Agricultural Engineering , 2014 , 30 ( 24 ): 252 - 258 .

Zhu X , Li S , Luo Z , et al . Combined with fractional condensation to upgrade the liquid products derived from the co-pyrolysis of bio-oil distillation residue and bituminous coal [J ] . Energy Conversion and Management , 2019 , 185 : 586 - 592 .

许细薇 , 李治宇 , 庄文俞 , 等 . 生物油及其重质组分乳化提质研究 [J ] . 农业机械学报 , 2017 , ( 5 ): 1 - 8 .

Xu X W , Li Z Y , Zhuang W Y , et al . Study on emulsification and quality improvement of bio-oil and its heavy components [J ] . Transactions of the Chinese Society of Agricultural Machinery , 2017 , ( 5 ): 1 - 8 .

Xiao R , Zhang S , Peng S , et al . Use of heavy fraction of bio-oil as fuel for hydrogen production in iron-based chemical looping process [J ] . International Journal of Hydrogen Energy , 2014 , 39 ( 35 ): 19955 - 19969 .

Zhang X , Tang W , Zhang Q , et al . Production of hydrocarbon fuels from heavy fraction of bio-oil through hydrodeoxygenative upgrading with Ru-based catalyst [J ] . Fuel , 2018 , 215 : 825 - 834 .

Guo X , Wang S , Guo Z , et al . Pyrolysis characteristics of bio-oil fractions separated by molecular distillation [J ] . Applied Energy , 2010 , 87 ( 9 ): 2892 - 2898 .

吕微 , 张琦 , 王铁军 , 等 . 生物油重质组分模型物热解行为及其动力学研究 [J ] . 燃料化学学报 , 2013 , 41 ( 2 ): 198 - 206 .

Lyu W , Zhang Q , Wang T J , et al . Study on the pyrolysis behavior and kinetics of heavy oil model components in bio-oil [J ] . Journal of Fuel Chemistry and Technology , 2013 , 41 ( 2 ): 198 - 206 .

王储 , 朱锡锋 . 分级冷凝生物油组分富集与组分稳定性研究 [J ] . 燃料化学学报 , 2018 , 46 ( 11 ): 1315 - 1322 .

Wang C , Zhu X F . Study on component enrichment and storage stability of bio-oils obtained from fractional condensation [J ] . Journal of Fuel Chemistry and Technology , 2018 , 46 ( 11 ): 1315 - 1322 .

Choi Y S , Elkasabi Y , Tarves P C , et al . Co-cracking of bio-oil distillate bottoms with vacuum gas oil for enhanced production of light compounds [J ] . Journal of Analytical and Applied Pyrolysis , 2018 , 132 : 65 - 71 .

Xiong Z , Han H , Azis M M , et al . Formation of the heavy tar during bio-oil pyrolysis: a study based on Fourier transform ion cyclotron resonance mass spectrometry [J ] . Fuel , 2019 , 239 : 108 - 116 .

Garcia-Perez M , Chaala A , Pakdel H , et al . Characterization of bio-oils in chemical families [J ] . Biomass and Bioenergy , 2007 , 31 ( 4 ): 222 - 242 .

朱谢飞 , 李凯 , 马善为 , 等 . 生物油蒸馏残渣理化性质及热失重研究 [J ] . 燃料化学学报 , 2017 , 45 ( 1 ): 29 - 33 .

Zhu X F , Li K , Ma S W , et al . Study on physicochemical properties and thermal weight loss of bio-oil distillation residues [J ] . Journal of Fuel Chemistry and Technology , 2017 , 45 ( 1 ): 29 - 33 .

丁浩植 , 马善为 , 张一鸣 , 等 . 生物油热失重特性研究 [J ] . 太阳能学报 , 2017 , 38 ( 10 ): 2698 - 2704 .

Ding H Z , Ma S W , Zhang Y M , et al . Study on the thermal weight loss characteristics of bio-oil [J ] . Acta Energia Sinica , 2017 , 38 ( 10 ): 2698 - 2704 .

Xiong Z , Wang Y , Syed-Hassan S S A , et al . Effects of heating rate on the evolution of bio-oil during its pyrolysis [J ] . Energy Conversion and Management , 2018 , 163 : 420 - 427 .

Xiong Z , Syed-Hassan S S A , Hu X , et al . Effects of the component interaction on the formation of aromatic structures during the pyrolysis of bio-oil at various temperatures and heating rates [J ] . Fuel , 2018 , 233 : 461 - 468 .

Zhang L , Li K , Zhu X . Study on two-step pyrolysis of soybean stalk by TG-FTIR and Py-GC/MS [J ] . Journal of Analytical and Applied Pyrolysis , 2017 , 127 : 91 - 98 .

Cai W , Liu Q , Shen D , et al . Py-GC/MS analysis on product distribution of two-staged biomass pyrolysis [J ] . Journal of Analytical and Applied Pyrolysis , 2019 , 138 : 62 - 69 .

陆强 , 张栋 , 朱锡锋 . 四种金属氯化物对纤维素快速热解的影响(Ⅰ): Py-GC/MS实验 [J ] . 化工学报 , 2010 , 61 ( 4 ): 1018 - 1024 .

Lu Q , Zhang D , Zhu X F . Catalytic effects of four metal chlorides on fast pyrolysis of cellulose (Ⅰ): Py-GC/MS experiments [J ] . CIESC Journal , 2010 , 61 ( 4 ): 1018 - 1024 .

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