Pilot-scale application on dissipation of smoke plume from flue gas using ceramic membrane condensers

CAO Yu; WANG Le; JI Chao; HUANG Yanzhao; XUE Zhilei; LU Jianming; QI Hong

doi:10.11949/0438-1157.20181500

您当前的位置：

首页 >

文章列表页 >

Pilot-scale application on dissipation of smoke plume from flue gas using ceramic membrane condensers

Separation engineering | 更新时间：2026-07-24

- Pilot-scale application on dissipation of smoke plume from flue gas using ceramic membrane condensers
- CIESC Journal Vol. 70, Issue 6, Pages: 2192-2201(2019)
- 作者机构：
  
  1.南京工业大学膜科学技术研究所，材料化学工程国家重点实验室，江苏南京 210009
  2.中国石油化工股份有限公司科技部，北京 100728
  3.中石化炼化工程（集团）股份有限公司洛阳技术研发中心，河南洛阳 471003
  4.南京圣卡孚科技有限公司，江苏南京 210032
- 作者简介：
- 基金信息：
- DOI：10.11949/0438-1157.20181500
  CLC： TQ 174.9
- Received：21 December 2018，
  
  Revised：2019-04-01，
  
  Online First：15 June 2020，
  
  Published：05 June 2019
- 稿件说明：
移动端阅览
曹语, 王乐, 季超, 黄延召, 薛志磊, 陆剑鸣, 漆虹. 陶瓷膜冷凝器用于烟气脱白烟过程的中试研究[J]. 化工学报, 2019, 70(6): 2192-2201

CAO Yu, WANG Le, JI Chao, HUANG Yanzhao, XUE Zhilei, LU Jianming, QI Hong. Pilot-scale application on dissipation of smoke plume from flue gas using ceramic membrane condensers[J]. CIESC Journal, 2019, 70(6): 2192-2201
曹语, 王乐, 季超, 黄延召, 薛志磊, 陆剑鸣, 漆虹. 陶瓷膜冷凝器用于烟气脱白烟过程的中试研究[J]. 化工学报, 2019, 70(6): 2192-2201 DOI： 10.11949/0438-1157.20181500.

CAO Yu, WANG Le, JI Chao, HUANG Yanzhao, XUE Zhilei, LU Jianming, QI Hong. Pilot-scale application on dissipation of smoke plume from flue gas using ceramic membrane condensers[J]. CIESC Journal, 2019, 70(6): 2192-2201 DOI： 10.11949/0438-1157.20181500.

摘要

将平均孔径5、20和50 nm的管式陶瓷外膜制成膜冷凝器，并搭建膜面积0.3 m

的膜冷凝中试实验装置，开展陶瓷膜冷凝器在烟气水、余热资源回收及脱白烟领域的中试研究。对比采用不同排布方式的两级陶瓷膜冷凝器的水、热回收效果，考察进气相对湿度、进气温度、进气线速度等操作条件和不同孔径陶瓷膜的排布方式对膜冷凝器水通量及水回收率的影响。研究表明，在两级膜冷凝器中，烟气、冷却水均为串联流动时，可得到更高的水、热通量及回收率。过程水通量随进气相对湿度、进气温度、进气线速度的增加而增加；水回收率随进气相对湿度、进气温度的增加而增加，随着进气线速度的增加而降低。在三级膜冷凝器中，采用每级均填充平均孔径50 nm的管式陶瓷外膜的排布方式时，可获得最佳的水、热回收效果；不同孔径陶瓷膜的排布方式对膜冷凝器水回收效果影响明显，对热回收效果影响不大。在各实验工况下，三级膜冷凝器水通量及水回收率最高分别可达38.5 kg·m

–2

·h

–1

和50.6%。与传统换热器相比，陶瓷膜冷凝器不仅可实现水、余热的同时回收，且其总传热系数为415 W·m

–2

·℃

–1

，换热效果更佳，并能明显缓解“白色烟羽”等视觉污染。基于陶瓷膜的膜冷凝技术在中试实验阶段展现出良好的回收效果，在资源回收及脱白烟过程有广阔的应用前景。

Abstract

The tubular ceramic outer membrane with average pore diameters of 5

20 and 50 nm was made into a membrane condenser

and a membrane condensation pilot test device with a membrane area of 0.3 m

was set up to carry out t

he recovery of water and waste heat resource from flue gas using ceramic membrane condensers. The recovery performance of two-stage membrane condensers with different installation types was investigated. The effects of relative humidity of inlet gas

inlet gas temperature

inlet gas velocity and average pore size of membranes on mass and heat transfer performances were systematically studied. The results showed that the higher flux and recovery ratio can be achieved when the gas and water flowed within the membrane condenser in a tandem way. The water flux increased with the increasing of relative humidity

temperature and velocity of the inlet gas. The water recovery ratio can be enhanced by increasing relative humidity

temperature of the inlet gas and decreasing gas velocity. In addition

a three-stage condenser installed with 50 nm pore-sized ceramic membranes displayed a better water and heat recovery performances. The average pore size of ceramic membranes had remarkable impact on the mass transfer process rather than the heat transfer process. In this work

the highest water flux and recovery ratio of three-stage membrane condensers were 38.5 kg·m

–2

·h

–1

and 50.6%

respectively. Compared with conventional heat exchangers

ceramic membrane condensers can recover water and heat simultaneously

during which the overall heat transfer coefficient could reach as high as 415 W·m

–2

·℃

–1

. The ceramic membrane condensers can not only effectively relieve the visible pollution known as “smoke plume”

but also have great potential applications in the resources recycling and environmental protection.

关键词

Keywords

references

Ma S , Chai J , Jiao K , et al . Environmental influence and countermeasures for high humidity flue gas discharging from power plants [J ] . Renewable & Sustainable Energy Reviews , 2017 , 73 : 225 - 235 .

Xu G , Huang S , Yang Y , et al . Techno-economic analysis and optimization of the heat recovery of utility boiler flue gas [J ] . Applied Energy , 2013 , 112 ( 4 ): 907 - 917 .

Chen H P , Zhou Y N , Cao S T , et al . Heat exchange and water recovery experiments of flue gas with using nanoporous ceramic membranes [J ] . Applied Thermal Engineering , 2017 , 110 : 686 - 694 .

郭静娟 . 燃煤电站烟囱排放有色烟羽现象研究 [J ] . 华电技术 , 2017 , 39 ( 1 ): 73 - 74 .

Guo J J . Coal-fired power plant stack emission colored smoke plume study [J ] . Huadian Technology , 2017 , 39 ( 1 ): 73 - 74 .

邓骥 , 魏芳 . 湿法烟气脱硫过程白烟成因及防治措施分析 [J ] . 石油与天然气化工 , 2017 , 46 ( 2 ): 17 - 21 .

Deng J , Wei F . Analysis on the causes and prevention measures of white mist in wet flue gas desulfurization [J ] . Chemical Engineering of Oil & Gas , 2017 , 46 ( 2 ): 17 - 21

Wang D . Advanced Energy and water recovery technology from low grade waste heat [R ] . Office of Scientific & Technical Information Technical Reports , 2011 .

Wang D . Transport Membrane condenser for water and energy recovery from power plant flue gas [R ] . Office of Scientific & Technical Information Technical Reports , 2012 .

Kim J , Park A , Kim S J , et al . Harnessing clean water from power plant emissions using membrane condenser technology [J ] . ACS Sustainable Chemistry & Engineering , 2018 , 6 : 6425 - 6433 .

李云 , 胡浩威 . 润湿性对纳米多孔陶瓷膜输运性能的影响 [J ] . 化工学报 , 2017 , 68 ( 9 ): 3474 - 3481 .

Li Y , Hu H W . Effect of wettability on nanoporous ceramic membrane for condensate transport performance [J ] . CIESC Journal , 2017 , 68 ( 9 ): 3474 - 3481 .

Hu H W , Tang G H , Niu D . Wettability modified nanoporous ceramic membrane for simultaneous residual heat and condensate recovery [J ] . Scientific Reports , 2016 , 6 : 27274 .

Yang B , Chen H P , Ye C , et al . Experimental study on differences of heat and mass flux between 10- and 50-nm pore-sized nano-porous ceramic membranes [J ] . Journal of the Australian Ceramic Society , 2018 , ( 3 ): 1 - 12 .

Bao A , Wang D , Lin C X . Nanoporous membrane tube condensing heat transfer enhancement study [J ] . International Journal of Heat & Mass Transfer , 2015 , 84 : 456 - 462 .

Zhao S F , Yan S P , Wang D K , et al . Simultaneous heat and water recovery from flue gas by membrane condensation : experimental investigation [J ] . Applied Thermal Engineering , 2017 , 113 : 843 - 850 .

Wang T T , Yue M W , Qi H , et al . Transport membrane condenser for water and heat recovery from gaseous streams: performance evaluation [J ] . Journal of Membrane Science , 2015 , 484 : 10 - 17 .

Yue M W , Zhao S F , Feron P H M , et al . Multichannel tubular ceramic membrane for water and heat recovery from waste gas streams [J ] . Industrial & Engineering Chemistry Research , 2016 , 55 ( 9 ): 2615 - 2622 .

孟庆莹 , 曹语 , 黄延召 , 等 . 过程参数对采用多孔陶瓷超滤膜回收烟气中余热和水性能的影响 [J ] . 化工学报 , 2018 , 69 ( 6 ): 2519 - 2525 .

Meng Q Y , Cao Y , Huang Y Z , et al . Effects of process parameters on water and waste heat recovery from flue gas using ceramic ultrafiltration membranes [J ] . CIESC Journal , 2018 , 69 ( 6 ): 2519 - 2525 .

管国锋 , 赵汝溥 . 化工原理 [M ] . 3版. 化学工业出版社 , 2010 .

Guan G F , Zhao R P . Unite Operation of Chemical Engineering [M ] . 3rd ed . Beijing : Chemical Industry Press , 2010 : 171 - 172 .

Zhou Y , Chen H , Xie T , et al . Effect of mass transfer on heat transfer of microporous ceramic membranes for water recovery [J ] . International Journal of Heat & Mass Transfer , 2017 , 112 : 643 - 648 .

Colburn A P , Hougen O A . Design of cooler condensers for mixtures of vapors with noncondensing Gases [J ] . Indengchem , 1933 , 26 ( 11 ): 1178 - 1182 .

杨世铭 , 陶文铨 . 传热学 [M ] . 4版 . 北京：高等教育出版社 , 2006 .

Yang S M , Tao W S . Heat Transfer [M ] . 4th ed . Beijing : Higher Education Press , 2006 : 251 - 252 .

Wang D X , Bao A , Kunc W , et al . Coal power plant flue gas waste heat and water recovery [J ] . Applied Energy , 2012 , 91 ( 1 ): 341 - 348 .

Wroblewski W , Dykas S , Rulik S . Selection of the cooling system configuration for an ultra-critical coal-fired power plant [J ] . Energy Conversion & Management , 2013 , 76 ( 30 ): 554 - 560 .

梅雪莲 . 风力发电机组水冷却系统换热器串并联研究 [J ] . 制冷与空调 , 2012 , 12 ( 6 ): 40 - 43 .

Mei X L . Series and parallel connection research on heat exchangers of water-cooled system for wind turbine [J ] . Refrigeration and Air-Conditioning , 2012 , 12 ( 6 ): 40 - 43 .

袁晓军 , 于太增 , 邵丽萍 . 串/并联全热回收风冷式冷(热)水系统的性能分析 [J ] . 制冷与空调 , 2017 , 17 ( 6 ): 63 - 66 .

Yuan X J , Yu T Z , Shao L P . Performance analysis of air cooled heat pump (chiller) with series/parallel total heat recovery exchanger [J ] . Refrigeration and Air-Conditioning , 2017 , 17 ( 6 ): 63 - 66 .

Che D F , Da Y D , Zhuang Z N . Heat and mass transfer characteristics of simulated high moisture flue gases [J ] . Heat & Mass Transfer , 2005 , 41 ( 3 ): 250 - 256 .

Chen H P , Zhou Y N , Su X , et al . Experimental study of water recovery from flue gas using hollow micro-nano porous ceramic composite membranes [J ] . Journal of Industrial & Engineering Chemistry , 2018 , 57 : 349 - 355 .

Zolfaghari A , Dehghanpour H , Xu M . Water sorption behaviour of gas shales: II. Pore size distribution [J ] . International Journal of Coal Geology , 2017 , 179 : 187 - 195 .

Uhlhorn R J R , Keizer K , Burggraaf A J . Gas transport and separation with ceramic membranes. (Ⅰ): Multilayer diffusion and capillary condensation [J ] . Journal of Membrane Science , 2017 , 66 ( 2 ): 259 - 269 .

Horikawa T , Do D D , Nicholson D . Capillary condensation of adsorbates in porous materials [J ] . Adv. Colloid Interface Sci. , 2011 , 169 ( 1 ): 40 - 58 .

Xiong Y Y , Tan H Z , Wang Y B , et al . Pilot-scale study on water and latent heat recovery from flue gas using fluorine plastic heat exchangers [J ] . Journal of Cleaner Production , 2017 , 161 : 1416 - 1422 .

Shi X J , Che D F , Agnew B , et al . An investigation of the performance of compact heat exchanger for latent heat recovery from exhaust flue gases [J ] . International Journal of Heat & Mass Transfer , 2011 , 54 ( 1 ): 606 - 615 .

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Effects of process parameters on water and waste heat recovery from flue gas using ceramic ultrafiltration membranes

Thermodynamic performance of tower-type solar-assisted supercritical compression CO2 energy storage system

Design and experimental analysis for waste heat power generation system from aluminum reduction cell's sidewalls based on RC318 working fluid

Research on thermodynamic properties of supercritical compressed carbon dioxide energy storage system with waste heat recovery

Research on characteristics of compression-absorption refrigeration system driven by waste heat in liquid-cooled data center

Related Author

MENG Qingying

CAO Yu

HUANG Yanzhao

LI Li

NIU Shufeng

QI Hong

ZHANG Dong

LI Yueyi

Related Institution

Luoyang R & D Center of Technology Sinopec Engineering(Group) Co., Ltd.

Membrane Science and Technology Research Center, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University

School of Energy, Power and Mechanical Engineering, North China Electric Power University

School of Aerospace Engineering, Guizhou University of Science and Technology

School of Energy and Power Engineering, Lanzhou University of Technology

⁰