Effect of space velocity in syngas reduction on performance of Fe/Cu/K/SiO2 catalyst for slurry phase Fischer-Tropsch synthesis
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Effect of space velocity in syngas reduction on performance of Fe/Cu/K/SiO2 catalyst for slurry phase Fischer-Tropsch synthesis
CIESC JournalVol. 57, Issue 2, (2006)
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Online First:25 February 2006,
Published:2006
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HAO Qinglan, BAI Liang, XIANG Hongwei, et al. Effect of space velocity in syngas reduction on performance of Fe/Cu/K/SiO2 catalyst for slurry phase Fischer-Tropsch synthesis[J]. CIESC Journal, 2006, 57(2).
DOI:
HAO Qinglan, BAI Liang, XIANG Hongwei, et al. Effect of space velocity in syngas reduction on performance of Fe/Cu/K/SiO2 catalyst for slurry phase Fischer-Tropsch synthesis[J]. CIESC Journal, 2006, 57(2).DOI:
Effect of space velocity in syngas reduction on performance of Fe/Cu/K/SiO2 catalyst for slurry phase Fischer-Tropsch synthesis
The effects of space velocity in syngas reduction on the reaction performance of the Fischer-Tropsch synthesis (FTS)over a spray-dried spherical Fe/Cu/K/SiO2 catalyst and on the bulk compositions of the reduced and used catalysts were investigated in a continuous stirred slurry reactor under reaction conditions of 250—280 ℃
1.5 MPa
H2/CO=0.67 and 2.0 L8226;(g cat)-18226;h-1. The results showed that the BET surface area of the reduced catalysts decreased with the increase of the space velocity in reduction
and the reverse trend for the average pore diameter was observed. The space velocity in syngas reduction did affect the reduction process. The catalyst was easier to be reduced at a higher space velocity. The higher partial pressure of CO2 in slurry reactor during reduction could partially oxidize the iron carbide. And the content of Fe3+(spm) was higher in the reduced catalyst. The space velocity in syngas reduction had no obvious effect on the hydrocarbon selectivity
and the effect of the space velocity in syngas reduction on the catalyst activity and stability was significant. The deactivation rate of the catalyst was higher at both lower and higher space velocity. The appropriate space velocity in syngas reduction was 1.0—2.0 L8226;(g cat)-18226;h-1.