Absorption Kinetics of Carbonyl Sulfide in Aqueous Solution of Fe(Ⅲ)-EDTA

朱建华; 方文骥

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Absorption Kinetics of Carbonyl Sulfide in Aqueous Solution of Fe(Ⅲ)-EDTA

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- Absorption Kinetics of Carbonyl Sulfide in Aqueous Solution of Fe(Ⅲ)-EDTA
- CIESC Journal Issue 4, (1990)
- 作者机构：
  
  郑州工学院化工系,郑州工学院化工系郑州,天津大学化工系,郑州
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Online First：25 August 1990，
  
  Published：25 August 1990
- 稿件说明：
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朱建华, 方文骥. Absorption Kinetics of Carbonyl Sulfide in Aqueous Solution of Fe(Ⅲ)-EDTA[J]. CIESC Journal, 1990, (4).
DOI：

朱建华, 方文骥. Absorption Kinetics of Carbonyl Sulfide in Aqueous Solution of Fe(Ⅲ)-EDTA[J]. CIESC Journal, 1990, (4). DOI：

摘要

在合成氨原料气中

羰基硫(COS)占有机硫的80%左右

天然气中COS亦高达500ppm

为了经济有效地脱除COS

作者经过筛选实验发现乙二胺四乙酸络合铁(Fe(Ⅲ)-EDTA)可以脱除COS

故对Fe(Ⅲ)-EDTA吸收COS的动力学进行了研究

揭示了该过程的控制步骤

建立了其数学模型

并提出了对该方法进行改进的可行性方案.

Abstract

The absorption kinetics of carbonyl sulfide in aqueous solution of Fe(Ⅲ)-EDTA was studied by using a gas-liquid double mixing gradientiess contactor. The effects of absorption temperature

interface concentration of carbonyl sulfide

the pH of solution and the concentration of Fe(Ⅲ)-EDTA on the absorption rate of carbonyl sulfide in aqueous solution of Fe(Ⅲ)-EDTA were examined. The experimental results showed that the absorption rate was controlled by the hydrolysis reaction rate of carbonyl sulfide in liquid phase. Under the experimental conditions

the absorption rate can be expressed by the following equation: where the dimension of NA is mol/(m2·s). According to the experimental results and Pearsons general principle of reaction for soft and hard acids and bases

feasible plans for improving the performance of carbonyl sulfide absorption in aqueous solution of Fe(Ⅲ)- EDTA were proposed.

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