Catalytic Kinetics of Low Pressure Methanol Synthesis from CO/CO_2/H_2 over Copper-based Catalyst

赖海明; 曾树林; 阎泽群; 李成岳

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Catalytic Kinetics of Low Pressure Methanol Synthesis from CO/CO_2/H_2 over Copper-based Catalyst

更新时间：2025-12-16

- Catalytic Kinetics of Low Pressure Methanol Synthesis from CO/CO_2/H_2 over Copper-based Catalyst
- CIESC Journal Issue 6, (1989)
- 作者机构：
  
  北京化工学院化学工程系,北京化工学院化学工程系,北京化工学院化学工程系,北京化工学院化学工程系 ,北京,北京,北京,北京
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Online First：25 December 1989，
  
  Published：25 December 1989
- 稿件说明：
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赖海明, 曾树林, 阎泽群, et al. Catalytic Kinetics of Low Pressure Methanol Synthesis from CO/CO_2/H_2 over Copper-based Catalyst[J]. CIESC Journal, 1989, (6).
DOI：

赖海明, 曾树林, 阎泽群, et al. Catalytic Kinetics of Low Pressure Methanol Synthesis from CO/CO_2/H_2 over Copper-based Catalyst[J]. CIESC Journal, 1989, (6). DOI：

摘要

在接近工业操作的条件下

对在国产V-203铜系催化剂上由CO/CO_2/H_2合成甲醇的动力学进行了实验研究

提出了反映CO_2促进作用的合成甲醇总速率方程式.当CO_2大约为6.0%(摩尔)时

合成甲醇的总速率达到极大值.

Abstract

The kinetic study of methanol synthesis from syn gas containing some CO2 was carried out over a copper-based catalyst developed in China. The significant promotional effect of CO2 on the synthesis of methanol was observed and experimental data could be fitted very well to the following overall rate expression which implied the optimal concentration of CO2 to be about 6.0%.

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