Predication of Heat of Vaporization of Pure Compounds at Normal Boiling Point by Residual Function Method

王福安; 杨长生; 赵伟彪

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Predication of Heat of Vaporization of Pure Compounds at Normal Boiling Point by Residual Function Method

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- Predication of Heat of Vaporization of Pure Compounds at Normal Boiling Point by Residual Function Method
- CIESC Journal Issue 4, (1989)
- 作者机构：
  
  郑州工学院化工系,郑州工学院化工系,郑州工学院化工系郑州,郑州,郑州,现在化工部第六设计院工作,西安
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Online First：25 August 1989，
  
  Published：25 August 1989
- 稿件说明：
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王福安, 杨长生, 赵伟彪. Predication of Heat of Vaporization of Pure Compounds at Normal Boiling Point by Residual Function Method[J]. CIESC Journal, 1989, (4).
DOI：

王福安, 杨长生, 赵伟彪. Predication of Heat of Vaporization of Pure Compounds at Normal Boiling Point by Residual Function Method[J]. CIESC Journal, 1989, (4). DOI：

摘要

本文根据化工热力学原理把剩余函数概念扩展到用于纯物质的汽化热

引入Clapeyron方程式和Pitzer三参数对比状态普遍化关系式

再代入Edmister方程式

推导出纯物质常沸点汽化热的新计算方程式.应用该方程式

由最基本的物性数据T_b、T_c和P_c

预测了390种各类物质的常沸点汽化热

与文献实验值相比较

总的绝对平均误差为2.0%.

Abstract

A kind of equation which predicts heat of vaporization of pure compounds at normal boiling point has been developed by combining the concept of residual function with Clapeyron equation and Pitzers three-parameter general relation and the Edmister equation A° = 0.1664θ4.2-0.02587 A = 0.8940θ4.2- 1.097θ1.6- 0.056 Only the fundamental data Tb

Pc are involved in the equation. Vaporization heat data of 390 compounds were predicted with a mean deviation 2.0% compared with the experimental data. The equation is generally applicable for engineering calculation available.

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