the radial effective conductivity ker and the wall heat transfer coefficient hw were estimated by means of non-linear least square. The two-dimensional pseudohomogeneous model was solved by using orthogonal collocation. A fixed bed packed with vanadium-phosphorous catalyst for oxidation of n-butane to maleic anhydride was studied. The temperatures at forty collocation points along the radial direction were measured by a multi-channel potential logger. The effects of bed height