Behaviour of Inhibitors in Emulsion Polymerization( I ): Case Ⅱ Kinetics

霍炳培; A.Penlidis

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Behaviour of Inhibitors in Emulsion Polymerization( I ): Case Ⅱ Kinetics

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- Behaviour of Inhibitors in Emulsion Polymerization( I ): Case Ⅱ Kinetics
- CIESC Journal Issue 4, (1989)
- 作者机构：
  
  广州市化工研究所,MIPPT McMaster Univ 广州,Canada
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Online First：25 August 1989，
  
  Published：25 August 1989
- 稿件说明：
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霍炳培, A.Penlidis. Behaviour of Inhibitors in Emulsion Polymerization( I ): Case Ⅱ Kinetics[J]. CIESC Journal, 1989, (4).
DOI：

霍炳培, A.Penlidis. Behaviour of Inhibitors in Emulsion Polymerization( I ): Case Ⅱ Kinetics[J]. CIESC Journal, 1989, (4). DOI：

摘要

本文研究了水溶性和油溶性阻聚剂对第Ⅱ类动力学乳液聚合的影响(以苯乙烯乳液聚合为例).实验结果表明阻聚剂对胶粒的形成及增长有明显的影响.推导出反映这些影响的数学模型

并对阻聚剂的影响进行了模拟研究

指出阻聚剂的这些行为在工业乳液聚合中的严重性.

Abstract

The effect of water soluble and monomer soluble inhibitors on the kinetics of emulsion polymerization of monomer following Case II kinetics (e. g. styrene) has been investigated. Experimental studies reveal that inhibitors can bave an appreciable effect on both polymer particle nucleation and growth. A mathematical model showing these effects has been developed and simulation studies have been made. The simulation results imply that the behaviour of monomer soluble inhibitors may be severe in industrial emulsion polymerization.

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