Reaction Kinetics of Methanol Synthesis in the Presence of C301 Cu-Based Catalyst ( I ) Model of Intrinsic Kinetics

Song Weiduan; Zhu Bingchen; Wang Hongshi; Zhu Mingjiao; Sun Qiwen and Zhang Junli(East China University of Chemical Technology; Shanghai)

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Reaction Kinetics of Methanol Synthesis in the Presence of C301 Cu-Based Catalyst ( I ) Model of Intrinsic Kinetics

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- Reaction Kinetics of Methanol Synthesis in the Presence of C301 Cu-Based Catalyst ( I ) Model of Intrinsic Kinetics
- CIESC Journal Issue 4, (1988)
- 作者机构：
  
  华东化工学院,华东化工学院,华东化工学院,华东化工学院,华东化工学院,华东化工学院 ,上海,上海,上海,上海,上海,上海
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Online First：25 August 1988，
  
  Published：25 August 1988
- 稿件说明：
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Song Weiduan, Zhu Bingchen, Wang Hongshi, et al. Reaction Kinetics of Methanol Synthesis in the Presence of C301 Cu-Based Catalyst ( I ) Model of Intrinsic Kinetics[J]. CIESC Journal, 1988, (4).
DOI：

Song Weiduan, Zhu Bingchen, Wang Hongshi, et al. Reaction Kinetics of Methanol Synthesis in the Presence of C301 Cu-Based Catalyst ( I ) Model of Intrinsic Kinetics[J]. CIESC Journal, 1988, (4). DOI：

摘要

本文研究了C301型铜基催化剂上由一氧化碳、二氧化碳与氢合成甲醇的本征动力学.实验在合成甲醇工业操作条件下进行.选择由一氧化碳和由二氧化碳合成甲醇为该系统的两个独立反应

给出了这—对反应动力学模型

该模型的计算值与实验结果相当吻合.

Abstract

The intrinsic kinetics of the methanol synthesis from carbon monoxide

carbon dioxide and hydrogen over C301 commercial catalyst are studied. The investigation is performed under typical commercial conditions. The two independent reactions chosen in this work are the synthesis of methanol from both carbon monoxide and carbon dioxide in the reacting system. Reliable kinetic models which adequately describe the results are derived from the two reactions.

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