Calculating Liquid-Liquid Equilibrium ot Binary System by M-H Equation of State

胡望明; 侯虞钧

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Calculating Liquid-Liquid Equilibrium ot Binary System by M-H Equation of State

更新时间：2025-12-16

- Calculating Liquid-Liquid Equilibrium ot Binary System by M-H Equation of State
- CIESC Journal Issue 1, (1989)
- 作者机构：
  
  浙江大学化工系,浙江大学化工系 ,杭州,杭州
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Online First：25 February 1989，
  
  Published：25 February 1989
- 稿件说明：
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胡望明, 侯虞钧. Calculating Liquid-Liquid Equilibrium ot Binary System by M-H Equation of State[J]. CIESC Journal, 1989, (1).
DOI：

胡望明, 侯虞钧. Calculating Liquid-Liquid Equilibrium ot Binary System by M-H Equation of State[J]. CIESC Journal, 1989, (1). DOI：

摘要

本文将马丁-侯状态方程用于LLE数据关联.对二元体系

使用两个二元相互作用参数.在较大温度范围

参数处理成温度函数;温度差范围在30-40℃之内

参数可作为常数

取得良好的关联结果.基于二元LLE数据推算了二元低压VLE

结果与实验值符合较好.

Abstract

The Martin-Hou equation of state is applied to liquid-liquid equilibrium. Excellent results are obtained for binary systems by using two binary Interaction parameters

which are temperature-dependent over a wide temperature range

but can be taken as constant over the narrow temperature range of 30 to 40 degrees. The prediction of VLE for binary systems at low pressures based on LLE data of binary systems are demonstrated. The results thus calculated agree with those determined experimentally.

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