A Study on the Metastable Zone in Solution of Potassium Chloride
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A Study on the Metastable Zone in Solution of Potassium Chloride
CIESC JournalIssue 3, (1983)
作者机构:
天津大学化工系,天津大学化工系
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Online First:25 September 1983,
Published:25 September 1983
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Chen Li aud Zhang YuanmouDepartment of Chemical Engineering, Tianjin University. A Study on the Metastable Zone in Solution of Potassium Chloride[J]. CIESC Journal, 1983, (3).
DOI:
Chen Li aud Zhang YuanmouDepartment of Chemical Engineering, Tianjin University. A Study on the Metastable Zone in Solution of Potassium Chloride[J]. CIESC Journal, 1983, (3).DOI:
A Study on the Metastable Zone in Solution of Potassium Chloride
The widths of metastable zone for aqueous solution of potassium chloride were determined in a constant cooling rate set. Under the seeded and unseeded conditions
two unparallel log b-log △θmax lines were obtained. The slope of the line of seeded was less than that of the unseeded. The width of metastable zone is dependent not only on the rate of cooling
but also on the retention time. Based on three groups of experimental data of different conditions
an empirical correlation of metastable zone width (△θmax)
cooling rate( b )
and retention time(τ) has been found: b = 0.443 △θmax3.167(τ+1)0.904 The rate of agitation of the apparatus was determined by Laser Doppler Velocimeter (LDV). A prelimenary study of the effect of the rate of agitation on metastable zone was made.