Multicomponent Diffusion Model for Effectiveness Factors of Porous Catalysts (Ⅱ) Effectiveness factors of high-temperature shift reaction catalyst B109
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Multicomponent Diffusion Model for Effectiveness Factors of Porous Catalysts (Ⅱ) Effectiveness factors of high-temperature shift reaction catalyst B109
CIESC JournalIssue 1, (1984)
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Online First:25 March 1984,
Published:25 March 1984
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朱炳辰, 宋维端, 房鼎业, et al. Multicomponent Diffusion Model for Effectiveness Factors of Porous Catalysts (Ⅱ) Effectiveness factors of high-temperature shift reaction catalyst B109[J]. CIESC Journal, 1984, (1).
DOI:
朱炳辰, 宋维端, 房鼎业, et al. Multicomponent Diffusion Model for Effectiveness Factors of Porous Catalysts (Ⅱ) Effectiveness factors of high-temperature shift reaction catalyst B109[J]. CIESC Journal, 1984, (1).DOI:
Multicomponent Diffusion Model for Effectiveness Factors of Porous Catalysts (Ⅱ) Effectiveness factors of high-temperature shift reaction catalyst B109
According to the multicomponent diffusion model for effectiveness factors of porous catalysts and its numerical computing method proposed by the authors in the first part of this paper
the effectiveness factors of high-temperature shift reaction catalyst B109 have been calculated in the second part
and they are compared with the experimentally observed values. The porosity
pore-size distribution
tortuosity factor and intrinsic kinetics at atmospheric pressure of shift catalyst B109 have been measured
and the global reaction rates only taking account of the intraparticle diffusion in 9.8×8.3mm cylindrical pellets of catalyst B109 under various conditions of gaseous compositions and temperature at atmospheric pressure have been investigated in an internal recycle gradientless reactor. The experimentally observed values of effectiveness factors obtained therefrom under sixteen conditions are from 0.142 to 0.455
and the relative errors of model prediction values with respect to experimentally observed values under the same reaction conditions are in the range of -0.25 to 0.06. The results of comparison are satisfactory.