INTENSIFICATION OF OXIDATION PROCESS OF PARAFFIN——THE FOAM OXIDATION METHOD

Ku PO-EH and Wu CHEN-SHIO (Research Section on Proceeding Solid Fuel; Peking Institute of Petroleum Technology)

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INTENSIFICATION OF OXIDATION PROCESS OF PARAFFIN——THE FOAM OXIDATION METHOD

更新时间：2025-12-16

- INTENSIFICATION OF OXIDATION PROCESS OF PARAFFIN——THE FOAM OXIDATION METHOD
- CIESC Journal Issue 1, (1960)
- 作者机构：
  
  北京石油学院固体燃料加工研究室,北京石油学院固体燃料加工研究室
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Online First：25 June 1960，
  
  Published：25 June 1960
- 稿件说明：
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Ku PO-EH and Wu CHEN-SHIO (Research Section on Proceeding Solid Fuel, Peking Institute of Petroleum Technology). INTENSIFICATION OF OXIDATION PROCESS OF PARAFFIN——THE FOAM OXIDATION METHOD[J]. CIESC Journal, 1960, (1).
DOI：

Ku PO-EH and Wu CHEN-SHIO (Research Section on Proceeding Solid Fuel, Peking Institute of Petroleum Technology). INTENSIFICATION OF OXIDATION PROCESS OF PARAFFIN——THE FOAM OXIDATION METHOD[J]. CIESC Journal, 1960, (1). DOI：

摘要

强化石腊氧化过程的关键在于创造对传质、传热以及氧化链锁反应（主要是链的引发）有利的条件。提出了强化过程的有效措施:首先是改善氧化链锁反应的引发条件（包括加入催化剂的条件及热激发的条件）

使氧化过程得到很大加强;此外在整个氧化过程中均采用了化工上的新技术——泡沫法

创造了进行此种多相、链锁反应同时又是放热反应的有利条件

使泡沫法在氧化工业中发挥了其独特的效应。继之提出了在较高温度下的泡沫循环氧化法

进一步提高了氧化反应器的体积强度

同时氧化反应速度以及产品产率和品质也得到进一步的改善。确定了液体石腊可以用泡沫循环连续氧化的方法进行处理

在获得脂肪酸的同时尚可获得脂肪醇类。

Abstract

The success-fulness of intensification oxidation of Paraffin depends on the creations for mass and heat transfer and for chain oxidation reaction (chiefly for the induction of the reaction). The effective measures for intensifying the process are indicated. To improve the conditions for induction of chain oxidation reaction (including the addition of catalysts and thermal impulsion) greatly intensifies the oxidation process. Besides

foam method

a new technique in chemical industry

is adopted in the whole process. Conditions for this heterogeneous chain reaction (and at the sametime

exothermic) are recommended

and this makes the foam method to play a particular role in oxidation industry. Circulating foam oxidation method at higher temperature is subsequently suggested

which promotes the volume intensity of the reactor for oxidation process

and further

increases the reaction rate and improves the oxidation products both in quantity and in quality. Jt is confirmed that continuous circulating foam oxidation is effective for obtaining fatty acids

and that alcohols are obtained simultaneously.

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