Preparation of FePt/GC nanocatalysts and their electrocatalytic activities for ethanol oxidation
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Preparation of FePt/GC nanocatalysts and their electrocatalytic activities for ethanol oxidation
CIESC JournalIssue S1, (2010)
作者机构:
厦门大学固体表面物理化学国家重点实验室,化学化工学院化学系
作者简介:
基金信息:
DOI:
CLC:
Online First:29 June 2010,
Published:29 June 2010
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王洁莹. Preparation of FePt/GC nanocatalysts and their electrocatalytic activities for ethanol oxidation[J]. CIESC Journal, 2010, (S1).
DOI:
王洁莹. Preparation of FePt/GC nanocatalysts and their electrocatalytic activities for ethanol oxidation[J]. CIESC Journal, 2010, (S1).DOI:
Preparation of FePt/GC nanocatalysts and their electrocatalytic activities for ethanol oxidation
摘要
Abstract
Iron nanoparticles were uniformly deposited on glassy carbon electrode by electrochemical cyclic voltammetry,and the Fe core/Pt shell nanoparticles were further obtained through “galvanic replacement”.SEM observation illustrated that the cuboid nanoparticles dispersing uniformly on GC surface.The electrocatalytical properties for ethanol oxidation of the nano-Pt/GC,nano-FePt/GC were studied by cyclic voltammetry(CV).The nano-FePt/GC electrode shows high electrocatalytical activity.The catalytic activity is in the order of:nano-Pt/GC<nano-FePt/GC.The onset potential(Ei)of ethanol oxidation on nano-FePt/GC electrode is negatively shifted 0.044 V,and the steady oxidation current density(jp)is enhanced about 2.16 times,compared with nano-Pt/GC electrode.