Preparation and characterization of α-Al2O3 submicron powders synthesized at low temperature by sol-gel method
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Preparation and characterization of α-Al2O3 submicron powders synthesized at low temperature by sol-gel method
CIESC JournalIssue 12, (2010)
作者机构:
中国计量学院材料科学与工程学院,浙江,杭州,310018
作者简介:
基金信息:
DOI:
CLC:
Online First:05 December 2010,
Published:05 December 2010
稿件说明:
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王世锋. Preparation and characterization of α-Al2O3 submicron powders synthesized at low temperature by sol-gel method[J]. CIESC Journal, 2010, (12).
DOI:
王世锋. Preparation and characterization of α-Al2O3 submicron powders synthesized at low temperature by sol-gel method[J]. CIESC Journal, 2010, (12).DOI:
Preparation and characterization of α-Al2O3 submicron powders synthesized at low temperature by sol-gel method
摘要
Abstract
Using Al(NO3)3·9H2O
Cu(NO3)2·3H2O and Ti(OC4H9)4 as raw materials
Al2O3 submicron powders were synthesized at a low temperature by the sol-gel process
and the phase and microstructure of powders were investigated.By doping Cu(NO3)2·3H2O and Ti(OC4H9)4 into alumina sol
a blue gel was obtained through placing the sol at 80℃ for a long time.Calcining the blue gel at 950℃ for 2 h produced amorphous Al2O3 powder with only a little γ-Al2O3 crystal phase
while α-Al2O3 nanopowders with a diameter of 80—100 nm were formed at the calcining temperature of 1000℃.As the calcining temperature increased to 1050℃
the grains grew to 200—400 nm.These results indicated that the synthesis temperature of α