Computer aided solvent scanning for separation of diphenyl and 4-phenylacetophenone

赵跃强

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Computer aided solvent scanning for separation of diphenyl and 4-phenylacetophenone

更新时间：2025-12-10

- Computer aided solvent scanning for separation of diphenyl and 4-phenylacetophenone
- CIESC Journal Issue 12, (2010)
- 作者机构：
  
  淮海工学院化工系，江苏省海洋生物技术重点建设实验室,江苏,连云港,222005
- 作者简介：
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- Online First：05 December 2010，
  
  Published：05 December 2010
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赵跃强. Computer aided solvent scanning for separation of diphenyl and 4-phenylacetophenone[J]. CIESC Journal, 2010, (12).
DOI：

赵跃强. Computer aided solvent scanning for separation of diphenyl and 4-phenylacetophenone[J]. CIESC Journal, 2010, (12). DOI：

摘要

Abstract

The solvents for the separation of diphenyl and 4-phenylacetophenone were screened with computer according to the solid-liquid equilibrium equation based on UNIFAC.With the predicted separation factor values and selection principle for feasible solvents

the candidates of better solvents were determined as n-heptane

n-hexane

cyclohexane and diisopropyl ether.The solubility and separation factor of the two solid solutes in n-heptane

n-hexane

cyclohexane

diisopropyl ether and ethanol were measured by static equilibrium method.The average relative deviation between the calculated separation factor and experimental data is 16.73%

indicating that the solid-liquid equilibrium equation based on UNIFAC is suitable to select the separation solvent for solid solute mixtures with similar molecule stereoscopic structures.

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