Kinetics for extraction of boric acid from salt lake brine by 2-ethyl hexanol-toluene
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Kinetics for extraction of boric acid from salt lake brine by 2-ethyl hexanol-toluene
CIESC JournalIssue 12, (2010)
作者机构:
河北工业大学化工学院,天津,300130
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DOI:
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Online First:05 December 2010,
Published:05 December 2010
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吕建华. Kinetics for extraction of boric acid from salt lake brine by 2-ethyl hexanol-toluene[J]. CIESC Journal, 2010, (12).
DOI:
吕建华. Kinetics for extraction of boric acid from salt lake brine by 2-ethyl hexanol-toluene[J]. CIESC Journal, 2010, (12).DOI:
Kinetics for extraction of boric acid from salt lake brine by 2-ethyl hexanol-toluene
摘要
Abstract
The kinetics of extracting boric acid from salt lake brine were investigated on the conditions of different initial concentrations of boric acid and 2-ethyl hexanol
temperature and the interfacial area of two-phase.The method of rising drop technique was used in the experiment with 2-ethyl hexanol as the complexing agent and toluene as a diluent.The result shows that the extraction rate of boric acid increases with the increasing of the initial concentrations of boric acid in the aqueous phase and 2-ethyl hexanol in the organic phase
the interfacial area of two-phase.The extraction reaction between boric acid and 2-ethyl hexanol is the quick reaction
which occurred in the interfacial area of two-phase.The extraction process is the diffusion-controlled mode by the calculation of the apparent activation energy.The kinetics equation of extracting boric acid with 2-ethyl hexanol regressed from the experimental data with the linear least square method can be expressed at pH=1(aqueous phase) and 318.15 K
and the relative deviation of rate constant is 5.318%.