Complexation adsorbent for ethylene-ethane separation:preparation and adsorption equilibrium
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Complexation adsorbent for ethylene-ethane separation:preparation and adsorption equilibrium
CIESC JournalIssue 8, (2006)
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Online First:25 August 2006,
Published:25 August 2006
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CHEN Le, LIU Xiaoqin, YAO Huqing. Complexation adsorbent for ethylene-ethane separation:preparation and adsorption equilibrium[J]. CIESC Journal, 2006, (8).
DOI:
CHEN Le, LIU Xiaoqin, YAO Huqing. Complexation adsorbent for ethylene-ethane separation:preparation and adsorption equilibrium[J]. CIESC Journal, 2006, (8).DOI:
Complexation adsorbent for ethylene-ethane separation:preparation and adsorption equilibrium
摘要
Abstract
The π-complexation adsorbent AgNO3/γ-Al2O3 was prepared from AgNO3 supported on γ-Al2O3 by the method of impregnation.The adsorbent is used for ethylene-ethane separation.The monolayer dispersion of AgNO3 on γ-Al2O3 was characterized with BET and XRD
and the maximum monolayer dispersion capacity of AgNO3 on γ-Al2O3 was calculated by XRD quantitative phase analysis.The adsorption equilibrium isotherms of ethylene and ethane on this adsorbent were measured at 38℃.The adsorption equilibrium data of ethylene and ethane could be properly fitted by the Langmuir-Freundlich model.The π-complexation adsorbent AgNO3/γ-Al2O3 had high equilibrium selectivity of ethylene
and the selective adsorption ratio of ethylene to ethane at 38℃ and 100 kPa was 10.1