铂电极上氟苯电化学降解机理及动力学

SONG Shuang; ZHOU Huamin; HE Zhiqiao; YING Haiping; CHEN Jianmeng

您当前的位置：

首页 >

文章列表页 >

铂电极上氟苯电化学降解机理及动力学

更新时间：2025-12-10

- 铂电极上氟苯电化学降解机理及动力学
- CIESC Journal Issue 10, (2006)
- 作者机构：
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Online First：25 October 2006，
  
  Published：25 October 2006
- 稿件说明：
移动端阅览
SONG Shuang, ZHOU Huamin, HE Zhiqiao, et al. 铂电极上氟苯电化学降解机理及动力学[J]. CIESC Journal, 2006, (10).
DOI：

SONG Shuang, ZHOU Huamin, HE Zhiqiao, et al. 铂电极上氟苯电化学降解机理及动力学[J]. CIESC Journal, 2006, (10). DOI：

摘要

Abstract

The degradation mechanism and kinetics of fluorobenzene (FB)was investigated on a platinum electrode.A graphite electrode was used as the counter electrode

and a Ag|AgCl(sat.KCl) electrode was used as the reference electrode.Degradation of FB was affected by several factors

such as pH

current density

FB initial concentration

temperature and NaF concentration.The intermediate products of FB degradation

including phenol

biphenylene

furan-2

5-dione and organic acids

were detected with high performance liquid chromatography (HPLC)

gas chromatography coupled with mass spectrometry (GC/MS) and ion chromatography (IC).The degradation mechanism with the formation of free radicals as reactive intermediates was proposed.The degradation of FB in aqueous solutions followed pseudo-second-order kinetics.

关键词

Keywords

references

Views

775

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Thermodynamic study of germanium-impurity competitive deposition in GeCl4-MxCly-H2 system

Effect of belt structure design on the vulcanization characteristics of all-steel radial tires

The impact of novel flow channel structure with sudden-expansion ratio on seawater-activated battery

Performance study of gas-liquid vortex separators under low cross-sectional gas velocity

Controlled synthesis of Bi2MoO6/MoO3 composite fibers via in-situ hydrothermal method and their high-efficiency photocatalytic hydrogen production performance

Related Author

No data

Related Institution

No data

⁰