VERIFICATION OF VAPOR-LIQUID EQUILIBRIUM DATA FOR SALT-CONTAINING SYSTEMS
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VERIFICATION OF VAPOR-LIQUID EQUILIBRIUM DATA FOR SALT-CONTAINING SYSTEMS
CIESC JournalIssue 8, (2002)
作者机构:
1. 河南大学化学系
2. 华东师范大学化学系
作者简介:
基金信息:
DOI:
CLC:
Online First:25 August 2002,
Published:25 August 2002
稿件说明:
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SUN Renyi, SUN Qian. VERIFICATION OF VAPOR-LIQUID EQUILIBRIUM DATA FOR SALT-CONTAINING SYSTEMS[J]. CIESC Journal, 2002, (8).
DOI:
SUN Renyi, SUN Qian. VERIFICATION OF VAPOR-LIQUID EQUILIBRIUM DATA FOR SALT-CONTAINING SYSTEMS[J]. CIESC Journal, 2002, (8).DOI:
VERIFICATION OF VAPOR-LIQUID EQUILIBRIUM DATA FOR SALT-CONTAINING SYSTEMS
摘要
Abstract
This paper regards the activity coefficient of salt in mixed solvents with constant composition as a function of vapor-liquid equilibrium data by means of ternary Gibbs-Duhem equation. A verification method including two independent criteria for vapor-liquid equilibrium data of salt containing system is proposed on the bases of thermodynamics and the Debye-Hückel electrolytical solution theory.A ccording to the criteria every experimental point can be verified by the calculation of its vapor-liquid equilibrium data.Not only is this method rigorous in the theory
but also very convenient in the application.Under the condition of fixing the ratio between two solvents it can be used for vapor-liquid equilibrium data verification of various salt-containing systems