LIQUID-LIQUID EQUILIBRIUM DETERMINATION AND CORRELATION OF CH3OH/H2O/H2O2/TMB/TOP QUINARY SYSTEM

MENG Xiangkun; WANG Chunyan; XU Xien

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LIQUID-LIQUID EQUILIBRIUM DETERMINATION AND CORRELATION OF CH₃OH/H₂O/H₂O₂/TMB/TOP QUINARY SYSTEM

更新时间：2025-12-10

- LIQUID-LIQUID EQUILIBRIUM DETERMINATION AND CORRELATION OF CH₃OH/H₂O/H₂O₂/TMB/TOP QUINARY SYSTEM
- CIESC Journal Issue 4, (2002)
- 作者机构：
  
  天津大学化工学院
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Online First：25 April 2002，
  
  Published：25 April 2002
- 稿件说明：
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MENG Xiangkun, WANG Chunyan, XU Xien. LIQUID-LIQUID EQUILIBRIUM DETERMINATION AND CORRELATION OF CH₃OH/H₂O/H₂O₂/TMB/TOP QUINARY SYSTEM[J]. CIESC Journal, 2002, (4).
DOI：

MENG Xiangkun, WANG Chunyan, XU Xien. LIQUID-LIQUID EQUILIBRIUM DETERMINATION AND CORRELATION OF CH₃OH/H₂O/H₂O₂/TMB/TOP QUINARY SYSTEM[J]. CIESC Journal, 2002, (4). DOI：

摘要

测定了常压、 4 0℃下甲醇 /H2 O/H2 O2 /1

5 -三甲苯 /磷酸三辛酯五元系液液平衡数据

分别用UNIQUAC模型和NRTL模型对实验数据进行了关联

取得了较满意的结果

Abstract

In this paper

the liquid-liquid equilibrium data of methanol/H 2O/H 2O 2/TMB/TOP are determined at 40℃ and at normal pressure.The experimental data are correlated with UNIQUAC and NRTL models

and the results are satisfactory.The relative mean deviation is less than 4%

and the relative maximal deviation is less than 8%.These parameters can be used to simulate the extraction process of the integrated process of epoxidation of propylene catalyzed by titanium silicalite (TS-1) and production of H 2O 2 by anthraquinone route.

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