DIRECT SYNTHESIS OF DIMETHYL ETHER FROM SYNGAS IN THREE-PAHASE AGITATED REACTORS
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DIRECT SYNTHESIS OF DIMETHYL ETHER FROM SYNGAS IN THREE-PAHASE AGITATED REACTORS
CIESC JournalIssue 1, (2002)
作者机构:
华东理工大学化学工程系
作者简介:
基金信息:
DOI:
CLC:
Online First:25 January 2002,
Published:25 January 2002
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LIU Dianhua, XU Jiang, ZHANG Haitao, et al. DIRECT SYNTHESIS OF DIMETHYL ETHER FROM SYNGAS IN THREE-PAHASE AGITATED REACTORS[J]. CIESC Journal, 2002, (1).
DOI:
LIU Dianhua, XU Jiang, ZHANG Haitao, et al. DIRECT SYNTHESIS OF DIMETHYL ETHER FROM SYNGAS IN THREE-PAHASE AGITATED REACTORS[J]. CIESC Journal, 2002, (1).DOI:
DIRECT SYNTHESIS OF DIMETHYL ETHER FROM SYNGAS IN THREE-PAHASE AGITATED REACTORS
摘要
Abstract
One-step synthesis of DME (dimethyl ether) from syngas on hybrid catalyst is studied.In the experiment
the effects of variables including composition of feed gas
temperature and pressure are studied under the condition as follows:the catalyst was composed of C302 methanol synthesis catalyst and CM-3-1 methanol dehydration catalyst (mixing ratio 1∶1).Liquid paraffin is used as inert solvent.The reaction temperature is in the range of 230-270℃ and the pressure is in the range of 3.0-5.0MPa.It turns out that with the temperature and pressure increasing the conversion of carbon
the selectivity and production rate of dimethyl ether increase
while the selectivity and production rate of methanol decrease.Furthermore
both the conversion of carbon and the selectivity of dimethyl ether are high for the syngas of appropriate CO 2.