EXPERIMENTAL STUDY ON DENSE OXYGEN-PERMEATING MEMBRANES FOR PARTIAL OXIDATION OF METHANE TO SYNGAS
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EXPERIMENTAL STUDY ON DENSE OXYGEN-PERMEATING MEMBRANES FOR PARTIAL OXIDATION OF METHANE TO SYNGAS
CIESC JournalIssue 8, (2001)
作者机构:
南京化工大学膜科学技术研究所
作者简介:
基金信息:
DOI:
CLC:
Online First:25 August 2001,
Published:25 August 2001
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XU Nanping, GU Xuehong, YANG Li, et al. EXPERIMENTAL STUDY ON DENSE OXYGEN-PERMEATING MEMBRANES FOR PARTIAL OXIDATION OF METHANE TO SYNGAS[J]. CIESC Journal, 2001, (8).
DOI:
XU Nanping, GU Xuehong, YANG Li, et al. EXPERIMENTAL STUDY ON DENSE OXYGEN-PERMEATING MEMBRANES FOR PARTIAL OXIDATION OF METHANE TO SYNGAS[J]. CIESC Journal, 2001, (8).DOI:
EXPERIMENTAL STUDY ON DENSE OXYGEN-PERMEATING MEMBRANES FOR PARTIAL OXIDATION OF METHANE TO SYNGAS
摘要
Abstract
In this paper
the pervoskite-related ZrO2-doped SrCo0.4 Fe0.6 O3-δ dense membrane reactors for methane partial oxidation to syngas are studied.Two membrane reactors with or without catalyst
which are running for a long time
are investigated.The results indicate that the membrane can continuously operate for over 300 hours in a reducing environment.Oxygen-permeation performance of membranes for three experimental processes including oxygen-permeation experiment are compared.The oxygen permeation flux increases in the order of oxygen-permeation experiment
blank membrane reaction experiment and membrane reaction experiment.The effects of feed conditions on experimental results in membrane reactor show that the feed concentration of methane influences the oxygen permeation flux of SCFZ membrane.The structures and compositions of membrane are also characterized by X-ray diffraction
scanning microscopy and energy dispersive spectroscopy.